Deuterium content and site occupancy in iron sulfide at high pressure and temperature determined using in situ neutron diffraction measurements

Abeykoon, S.*; Howard, C.*; Dominijanni, S.*; Eberhard, L.*; Kurnosov, A.*; Frost, D. J.*; Boffa Ballaran, T.*; Terasaki, Hidenori*; Sakamaki, Tatsuya*; Suzuki, Akio*; et al.

Journal of Geophysical Research; Solid Earth, 128(9), p.e2023JB026710_1 - e2023JB026710_17, 2023/09

https://doi.org/10.1029/2023JB026710

Small amounts of iron sulphide minerals are found in most rocks from the Earth's mantle and as inclusions trapped in natural diamonds. Hydrogen may dissolve into iron sulphide minerals under high pressures and temperature, but is most likely lost once pressure and temperature are removed. In this study, we determined deuterium contents in iron sulphide, held under high pressure and temperature conditions, using neutron diffraction measurements with 6-ram multi-anvil press at PLANET, J-PARC. Deuterium contents in iron sulphide were measured at high-P, up to 11.4 GPa and high-T to 1300 K in in situ neutron diffraction experiments. The total deuterium content increases with both P and T. The results are used to estimate hydrogen contents of iron sulphide minerals in the deep continental lithospheric mantle, which are found to be in the range 1700-2700 ppm. This corresponds to approximately 2-3 ppm of hydrogen in the bulk mantle.

Unified mercury radioactivity monitoring system at J-PARC and its operation experiences

Harada, Masahide; Sekijima, Mitsuaki*; Morikawa, Noriyuki*; Masuda, Shiho; Kinoshita, Hidetaka; Sakai, Kenji; Kai, Tetsuya; Kasugai, Yoshimi; Muto, Giichi*; Suzuki, Akio*; et al.

JPS Conference Proceedings (Internet), 33, p.011099_1 - 011099_6, 2021/03

https://doi.org/10.7566/JPSCP.33.011099

In MLF at J-PARC, a unified mercury radioactivity monitor (UHAM) is installed to find an indication of failure of the mercury target and loop system by detecting radioactive materials leaked from the system with a -ray energy analysis with Germanium semi-conductor detectors (Ge detectors). It is composed of three units of sampling port and radiation monitors: (1) HAM for interstitial helium gas layer between the mercury vessel and surrounding water shroud of the mercury target, (2) CAM for atmosphere in the hot cell where the target loop is operated and (3) VAM for helium gas in the helium vessel where the target vessel is installed. Once any leakages of radioactive materials are detected, an alarm signal is issued immediately to the accelerator control system to stop beam operation. Software and hardware have been upgraded yearly. For example, two Ge detectors are used for HAM for redundancy, NaI Scintillation detectors are also used as supplemental for the Ge detector to keep availability of the system for high counting rate event. In April 2015, the UHAM activated when a small water coolant leakage from the water shroud of the mercury target occurred. VAM detected an abnormal increase of the counting rate in the helium vessel. It was also indicated that the measured radioactive nuclides were generated from the activation of the coolant (water) in the water shroud and not from the mercury.

Technical estimation for mass production of highly-concentrated Tc solution from Mo to be obtained by () reaction; A Preliminary study using inactive Re instead of Tc

Tanase, Masakazu*; Fujisaki, Saburo*; Ota, Akio*; Shiina, Takayuki*; Yamabayashi, Hisamichi*; Takeuchi, Nobuhiro*; Tsuchiya, Kunihiko; Kimura, Akihiro; Suzuki, Yoshitaka; Ishida, Takuya; et al.

Radioisotopes, 65(5), p.237 - 245, 2016/05

https://doi.org/10.3769/radioisotopes.65.237

no abstracts in English

Annual report on the effluent control of low level liquid waste in Nuclear Fuel Cycle Engineering Laboratories FY2014

Watanabe, Hitoshi; Nakano, Masanao; Fujita, Hiroki; Kono, Takahiko; Inoue, Kazumi; Yoshii, Hideki*; Otani, Kazunori*; Hiyama, Yoshinori*; Kikuchi, Masaaki*; Sakauchi, Nobuyuki*; et al.

JAEA-Review 2015-030, 115 Pages, 2015/12

JAEA-Review-2015-030.pdf:25.28MB

Based on the regulations (the safety regulation of Tokai reprocessing plant, the safety regulation of nuclear fuel material usage facilities, the radiation safety rule, the regulation about prevention from radiation hazards due to radioisotopes, which are related with the nuclear regulatory acts, the local agreement concerning with safety and environment conservation around nuclear facilities, the water pollution control law, and bylaw of Ibaraki prefecture), the effluent control of liquid waste discharged from the Nuclear Fuel Cycle Engineering Laboratories of Japan Atomic Energy Agency has been performed. This report describes the effluent control results of the liquid waste in the fiscal year 2014. In this period, the concentrations and the quantities of the radioactivity in liquid waste discharged from the reprocessing plant, the plutonium fuel fabrication facilities, and the other nuclear fuel material usage facilities were much lower than the limits authorized by the above regulations.

Annual report on the effluent control of low level liquid waste in Nuclear Fuel Cycle Engineering Laboratories FY2012

Sumiya, Shuichi; Watanabe, Hitoshi; Miyagawa, Naoto; Nakano, Masanao; Fujita, Hiroki; Kono, Takahiko; Inoue, Kazumi; Yoshii, Hideki; Otani, Kazunori*; Hiyama, Yoshinori*; et al.

JAEA-Review 2013-041, 115 Pages, 2014/01

JAEA-Review-2013-041.pdf:19.01MB

Based on the regulations (the safety regulation of Tokai reprocessing plant, the safety regulation of nuclear fuel material usage facilities, the radiation safety rule, the regulation about prevention from radiation hazards due to radioisotopes, which are related with the nuclear regulatory acts, and the local agreement concerning with safety and environment conservation around nuclear facilities, the water pollution control law, and bylaw of Ibaraki prefecture), this report describes the effluent control results of liquid waste discharged from the JAEA's Nuclear Fuel Cycle Engineering Laboratories in the fiscal year 2012, from 1st April 2012 to 31st March 2013. In this period, the concentrations and the quantities of the radioactivity in liquid waste discharged from the reprocessing plant, the plutonium fuel fabrication facilities, and the other facilities were much lower than the authorized limits of the above regulations.

High-magnetic-field X-ray absorption and magnetic circular dichroism spectroscopy in the mixed-valent compound YbAgCu

Nakamura, Toshiyuki*; Matsuda, Yasuhiro*; Her, J.-L.*; Kindo, Koichi*; Michimura, Shinji*; Inami, Toshiya; Mizumaki, Masaichiro*; Kawamura, Naomi*; Suzuki, Motohiro*; Chen, B.*; et al.

Journal of the Physical Society of Japan, 81(11), p.114702_1 - 114702_11, 2012/11

https://doi.org/10.1143/JPSJ.81.114702

The X-ray absorption and magnetic circular dichroism (MCD) spectra at the Yb L edge were measured in the mixed-valent heavy fermion compound YbAgCu at high magnetic fields and low temperatures. The magnetic-field-temperature (H-T) phase boundary determined by the valence state is in very good agreement with that determined by the magnetization. It is clearly found that the metamagnetism of this compound is due to the field induced valence transition. A distinctive positive peak of the XMCD spectra appears in the vicinity of the white line of the absorption due to Yb state, while no feature is observed in the XMCD spectra corresponding to the Yb state. A small negative XMCD peak was observed at a lower energy and was attributed to the quadrupole trasition from theoretical calcuration, which explains its peculicar magnetic field dependence.

Density of high-Ti basalt magma at high pressure and origin of heterogeneities in the lunar mantle

Sakamaki, Tatsuya*; Otani, Eiji*; Urakawa, Satoru*; Suzuki, Akio*; Katayama, Yoshinori; Zhao, D.*

Earth and Planetary Science Letters, 299(3-4), p.285 - 289, 2010/11

https://doi.org/10.1016/j.epsl.2010.09.007

The density of the Apollo 14 black glass melt, which has the highest TiO content of pristine mare glasses, was measured to 4.8 GPa and 2100 K using an X-ray absorption method. A fit of the pressure-density-temperature data to the high-temperature Birch-Murnaghan equation of state yielded the isothermal bulk modulus, its pressure derivative, and the temperature derivative of the bulk modulus. Implication for heterogeneities in the lunar mantle is discussed.

Designing PLANET; Neutron beamline for high-pressure material science at J-PARC

Arima, Hiroshi*; Hattori, Takanori; Komatsu, Kazuki*; Abe, Jun; Utsumi, Wataru; Kagi, Hiroyuki*; Suzuki, Akio*; Suzuya, Kentaro; Kamiyama, Takashi*; Arai, Masatoshi; et al.

Journal of Physics; Conference Series, 215(1), p.012025_1 - 012025_6, 2010/03

https://doi.org/10.1088/1742-6596/215/1/012025

The powder diffractometer dedicated to high-pressure experiments (PLANET) is now being constructed on BL11 at the spallation neutron source of J-PARC. PLANET aims to study structures of hydrogen-bearing materials including dense hydrous minerals of the Earth's deep interior, magmas and light element liquids. The instrument will realize diffraction and radiography experiments for powder and liquid/glass samples at high pressures up to 20 GPa and 2000 K. It covers spacing from 0.2 to 4.1 at 90 bank within the first frame. The design and performance of PLANET have been evaluated using Monte Carlo simulations.

Measurement of hydrous peridotite magma density at high pressure using the X-ray absorption method

Sakamaki, Tatsuya*; Otani, Eiji*; Urakawa, Satoru*; Suzuki, Akio*; Katayama, Yoshinori

Earth and Planetary Science Letters, 287(3-4), p.293 - 297, 2009/10

https://doi.org/10.1016/j.epsl.2009.07.030

The density of hydrous peridotite magma containing 5wt.% HO was measured at pressures and temperatures up to 4.3 GPa and 2073 K, respectively, using the X-ray absorption method. A fit of pressure-density-temperature data to the high-temperature Birch-Murnagan equation of state yields isothermal bulk modulus GPa, its pressure derivative and the temperature derivative of the bulk modulus GPa/K at 1773K. The small bulk modulus of the hydrous peridotite magma compared with that of the dry peridotite magma reflects the effect of water, which is more compressible than the silicate melt.

Overview of national centralized tokamak program; Mission, design and strategy to contribute ITER and DEMO

Ninomiya, Hiromasa; Akiba, Masato; Fujii, Tsuneyuki; Fujita, Takaaki; Fujiwara, Masami*; Hamamatsu, Kiyotaka; Hayashi, Nobuhiko; Hosogane, Nobuyuki; Ikeda, Yoshitaka; Inoue, Nobuyuki; et al.

Journal of the Korean Physical Society, 49, p.S428 - S432, 2006/12

To contribute DEMO and ITER, the design to modify the present JT-60U into superconducting coil machine, named National Centralized Tokamak (NCT), is being progressed under nationwide collaborations in Japan. Mission, design and strategy of this NCT program is summarized.