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論文

Enhanced strength and ductility in an additively manufactured Al10SiMg alloy at cryogenic temperatures

Naeem, M.*; Rehman, A. U.*; Romero Resendiz, L.*; Salamci, E.*; Aydin, H.*; Ansari, P.*; Harjo, S.; Gong, W.; Wang, X.-L.*; 他3名*

Communications Materials (Internet), 6, p.65_1 - 65_13, 2025/04

The need for lightweight materials with mechanical integrity at ultralow temperatures drives the development of advanced alloys for cryogenic use. Additive manufacturing via laser powder bed fusion (LPBF) offers a scalable way to create alloys with tailored properties. Here, we show that LPBF-processed Al10SiMg exhibits a high ultimate tensile strength (395 MPa) and uniform elongation (25%) at 15 K. These enhancements stem from grain refinement, increased geometrically necessary dislocations, and stress partitioning between the Al matrix and the stiffer Si phase, aiding strain accommodation. ${it In-situ}$ neutron diffraction reveals that the Si phase, with its higher yield strength, bears most of the load, while the Al matrix undergoes continuous strain hardening, extending deformation capacity. These results highlight Al10SiMg's promise for cryogenic applications such as hydrogen storage, aerospace, and quantum computing hardware.

論文

Unusual low-temperature ductility increase mediated by dislocations alone

Naeem, M.*; Ma, Y.*; Tian, J.*; Kong, H.*; Romero-Resendiz, L.*; Fan, Z.*; Jiang, F.*; Gong, W.; Harjo, S.; Wu, Z.*; et al.

Materials Science & Engineering A, 924, p.147819_1 - 147819_10, 2025/02

 被引用回数:0 パーセンタイル:0.00(Nanoscience & Nanotechnology)

Face-centered cubic (fcc) medium-/high-entropy alloys (M/HEAs) typically enhance strength and ductility at cryogenic temperatures via stacking faults, twinning, or martensitic transformation. However, in-situ neutron diffraction on VCoNi MEA at 15 K reveals that strain hardening is driven solely by rapid dislocation accumulation, without these mechanisms. This results in increased yield strength, strain hardening, and fracture strain. The behavior, explained by the Orowan equation, challenges conventional views on cryogenic strengthening in fcc M/HEAs and highlights the role of dislocation-mediated plasticity at low temperatures.

論文

Strong low-energy rattling modes enabled liquid-like ultralow thermal conductivity in a well-ordered solid

Liu, P.-F.*; Li, X.*; Li, J.*; Zhu, J.*; Tong, Z.*; 古府 麻衣子*; 楡井 真実; Xu, J.*; Yin, W.*; Wang, F.*; et al.

National Science Review, 11(12), p.nwae216_1 - nwae216_10, 2024/12

 被引用回数:12 パーセンタイル:91.22(Multidisciplinary Sciences)

Crystalline solids exhibiting inherently low lattice thermal conductivity ($$kappa_{rm L}$$) are of great importance in applications such as thermoelectrics and thermal barrier coatings. However, $$kappa_{rm L}$$ cannot be arbitrarily low and is limited by the minimum thermal conductivity related to phonon dispersions. In this work, we report the liquid-like thermal transport in a well-ordered crystalline CsAg$$_5$$Te$$_3$$, which exhibits an extremely low $$kappa_{rm L}$$ value of $$sim$$ 0.18 Wm$$^{-1}$$K$$^{-1}$$. On the basis of first-principles calculations and inelastic neutron scattering measurements, we find that there are lots of low-lying optical phonon modes at $$sim$$ 3.1 meV hosting the avoided-crossing behavior with acoustic phonons. These strongly localized modes are accompanied by weakly bound rattling Ag atoms with thermally induced large amplitudes of vibrations. Using the two-channel model, we demonstrate that coupling of the particle-like phonon modes and the heat-carrying wave-like phonons is essential for understanding the low $$kappa_{rm L}$$, which is heavily deviated from the $$1/T$$ temperature dependence of the standard Peierls theory. In addition, our analysis indicates that the soft structural framework with liquid-like motions of the fluctuating Ag atoms is the underlying cause that leads to the suppression of the heat conduction in CsAg$$_5$$Te$$_3$$. These factors synergistically account for the ultralow $$kappa_{rm L}$$ value. Our results demonstrate that the liquid-like heat transfer could indeed exist in a well-ordered crystal.

論文

Application of neutron characterization techniques to metallic structural materials

Wang, Y.*; Gong, W.; Su, Y. H.; Li, B.*

Acta Metallurgica Sinica, 60(8), p.1001 - 1016, 2024/08

 被引用回数:1 パーセンタイル:41.92(Metallurgy & Metallurgical Engineering)

The correlation between the atomic structure, microstructure, and macroscopic properties of structural materials remains a core issue in materials research. In recent years, substantial progress has been achieved in constructing accelerator-based neutron sources and related experimental techniques, offering a robust platform for an in-depth understanding of the aforementioned correlation under real-time and in situ conditions. This article reviews the latest advancements in the application of major neutron characterization techniques, including neutron diffraction, Bragg-edge imaging, small-angle neutron scattering, pair distribution function analysis, and quasi-elastic/inelastic neutron scattering, in structural materials. Furthermore, it particularly highlights the origins and evolution of internal stresses during the phase transformations of steels, deformation mechanisms in light metals such as magnesium alloys, and microstructure and residual stress analyses using Bragg-edge imaging. Finally, a brief outlook on future development trends is provided.

論文

Progress of material characterization techniques based on neutron Bragg-edge transmission imaging

Wang, Y. W.*; 徐 平光; Su, Y. H.; Ma, Y. L.*; Wang, H. H.*

Physics Examination and Testing, 42(4), p.32 - 41, 2024/08

With the rapid technological development of large spallation neutron source facilities, the neutron beam flux obtained has been greatly improved and neutron imaging techniques have been further developed. Due to the limitation of neutron beam flux, conventional neutron imaging techniques require neutron beams with a wide wavelength range to obtain relatively high neutron beam flux conditions. Recently, spallation neutron sources using large proton accelerators have made it possible to obtain high-flux pulsed neutron beams. Energy (wavelength) resolved neutron imaging technique based on the Bragg edge effect (neutron Bragg edge transmission imaging technique) is expected to have a wide range of applications because of its high energy resolution, high spatial resolution, and ability to detect crystallographic information. The basic principle of this technique is briefly introduced. Several applications in the evaluation of residual strain, phase composition, dislocation density, and oriented structure are also reviewed to play an active role in promoting the wider applications of related technique.

論文

Dual nanoprecipitation and nanoscale chemical heterogeneity in a secondary hardening steel for ultrahigh strength and large uniform elongation

Wang, S.*; Wang, J.*; Zhang, S.*; Wei, D.*; Chen, Y.*; Rong, X.*; Gong, W.; Harjo, S.; Liu, X.*; Jiao, Z.*; et al.

Journal of Materials Science & Technology, 185, p.245 - 258, 2024/06

 被引用回数:15 パーセンタイル:97.90(Materials Science, Multidisciplinary)

Nanoprecipitates and nanoscale retained austenite (RA) with suitable stability play crucial roles in determining the yield strength (YS) and ductility of ultrahigh strength steels (UHSSs). However, owing to the kinetics incompatibility between nanoprecipitation and austenite reversion, it is highly challenging to simultaneously introduce high-density nanoprecipitates and optimized RA in UHSSs. In this work, through the combination of austenite reversion treatment (ART) and subsequent flash austenitizing (FA), nanoscale chemical heterogeneity was successfully introduced into a low-cost UHSS prior to the aging process. This chemical heterogeneity involved the enrichment of Mn and Ni in the austenite phase. The resulting UHSS exhibited dual-nanoprecipitation of Ni(Al,Mn) and (Mo,Cr)$$_{2}$$ C and nanoscale austenite stabilized via Mn and Ni enrichment. The hard martensitic matrix strengthened by high-density dual-nanoprecipitates constrains the plastic deformation of soft RA with a relatively low fraction, and the presence of relatively stable nanoscale RA with adequate Mn and Ni enrichment leads to a marginal loss in YS but keeps a persistent transformation-induced plasticity (TRIP) effect. As a result, the newly-developed UHSS exhibits an ultrahigh YS of 1.7 GPa, an ultimate tensile strength (UTS) of 1.8 GPa, a large uniform elongation (UE) of 8.5 percent, and a total elongation (TE) of 13 percent. The strategy of presetting chemical heterogeneity to introduce proper metastable phases before aging can be extended to other UHSSs and precipitation-hardened alloys.

論文

Onset of collectivity for argon isotopes close to $$N=32$$

Linh, B. D.*; Corsi, A.*; Gillibert, A.*; Obertelli, A.*; Doornenbal, P.*; Barbieri, C.*; Duguet, T.*; G$'o$mez-Ramos, M.*; Holt, J. D.*; Hu, B. S.*; et al.

Physical Review C, 109(3), p.034312_1 - 034312_15, 2024/03

 被引用回数:2 パーセンタイル:58.81(Physics, Nuclear)

理化学研究所RIビームファクトリーにて中性子過剰核$$^{50}$$Arビームからの1中性子ノックアウト反応実験を行い、$$^{49}$$Arのエネルギー準位および分光学的因子を導出した。特に、第一励起状態の$$1/2^-$$への分光学的因子が大きいことから、始状態の$$^{50}$$Arの基底状態において中性子が$$p_{1/2}$$軌道を多く占めていることがわかった。これは、中性子数32がよい魔法数として知られる$$^{52}$$Caとは異なった性質であり、カルシウムからアルゴンへと陽子が2個減ることで閉殻構造が大きく崩れることが明らかになった。

論文

Microscopic origin of the spin-reorientation transition in the kagome topological magnet TbMn$$_{6}$$Sn$$_{6}$$

Huang, Z.*; Wang, W.*; Ye, H.*; Bao, S.*; Shangguan, Y.*; Liao, J.*; Cao, S.*; 梶本 亮一; 池内 和彦*; Deng, G.*; et al.

Physical Review B, 109(1), p.014434_1 - 014434_9, 2024/01

 被引用回数:2 パーセンタイル:62.71(Materials Science, Multidisciplinary)

TbMn$$_{6}$$Sn$$_{6}$$ is a correlated topological magnet with a Mn-based kagome lattice, in which a Chern gap opens at the Dirac point at low temperatures. The magnetic moment direction of the ferrimagnetic order changes from in the kagome plane to the out-of-plane upon cooling, which is essential for generating the Chern gap, but the underlying mechanism for the spin reorientation remains elusive. Here, we investigate the spin-reorientation transition in TbMn$$_{6}$$Sn$$_{6}$$ using neutron scattering. We provide direct evidence for the spin-reorientation transition and unveil the coexistence of two Tb modes at 200 K. To account for these results, we put forward a model based on SU(N) spin-wave theory, in which there is a temperature evolution of the ground state Tb $$4f$$ orbitals, driven by the crystalline electric field, single-ion anisotropy, and exchange interactions between Tb and Mn ions. Our findings shed light on the complex magnetism of TbMn$$_{6}$$Sn$$_{6}$$, despite its relatively simple ground state magnetic structure, and provide insights into the mechanisms for tuning magnetic topological materials.

論文

Cryogenic impact fracture behavior of a high-Mn austenitic steel using electron backscatter diffraction and neutron Bragg-edge transmission imaging

Wang, Y. W.*; Wang, H. H.*; Su, Y. H.; 徐 平光; 篠原 武尚

Materials Science & Engineering A, 887, p.145768_1 - 145768_13, 2023/11

 被引用回数:7 パーセンタイル:67.79(Nanoscience & Nanotechnology)

A unique impact fracture behavior is found in a high-Mn austenitic steel (24Mn-4Cr-0.4C-0.3Cu) in this work. The steel exhibits concurrent twinning-induced plasticity (TWIP) effect and the transformation-induced plasticity (TRIP) effect. By analyzing the load-deflection curves recorded during Charpy impact testing, the resistance to crack initiation and propagation is quantified from the absorbed energy. The high-Mn steel demonstrates good resistance to crack initiation at 273 K and 77 K. However, as the temperature decreases from 273 K to 77 K, there is an accelerated transition from stable crack growth to unstable crack growth during impact, resulting in the deterioration of resistance to crack propagation. The plastic deformation of the impact-tested samples, especially in the region close to the crack-path profile was quantitatively analyzed using neutron Bragg-edge transmission (BET) imaging. The deformation zones, divided by using the width of the 200 Bragg edge, exhibit good agreement with the impact absorbed energy characteristics obtained from dynamic load-deflection curves. Moreover, the unstable growth transition point was roughly determined on the impact-tested sample. Then, the electron backscatter diffraction (EBSD) technique is employed to examine the deformation microstructure along the crack-path in the impact-tested samples. The results revealed the dual roles of TRIP effect in impact toughness of the high-Mn steel. On one hand, the TRIP effect plays a positive role in improving resistance to crack initiation and propagation. On the other hand, the excessive accumulation of brittle $$varepsilon$$/$$alpha$$'-martensite caused by the enhanced TRIP effect at 77 K leads to quasi-cleavage fracture, thereby playing a negative role. Finally, we discussed the prominent toughening mechanisms associated with the TWIP and TRIP effects, which greatly impact the impact fracture behavior.

論文

Development of scalable deconvolution methods for determining secondary target neutron yields from dual-thick-target cosmic-ray ion accelerator experiments

Ratliff, H.; McGirl, N. A.*; Beach, M. R.*; Castellanos, L. A.*; Clowdsley, M. S.*; Heilbronn, L. H.*; LaTessa, C.*; Norbury, J. W.*; Rusek, A.*; Sivertz, M.*; et al.

Nuclear Instruments and Methods in Physics Research B, 544, p.165121_1 - 165121_15, 2023/11

 被引用回数:0 パーセンタイル:0.00(Instruments & Instrumentation)

Experiments emulating the deep-space radiation environment within an enclosed spacecraft were conducted at the NASA Space Radiation Laboratory; this was achieved by bombarding various combinations of two consecutive thick targets with Galactic Cosmic Ray-like particle beams. While all secondary particles generated in the first of these two targets could be characterized using time-of-flight techniques, characterization of the neutrons produced in the second target, emulating the "back wall" of a spacecraft, required the development and implementation of deconvolution techniques. This work covers this methodology, its validation, and the systematic results present within this benchmark dataset of neutron yields from the secondary target.

論文

PANDORA Project for the study of photonuclear reactions below $$A=60$$

民井 淳*; Pellegri, L.*; S$"o$derstr$"o$m, P.-A.*; Allard, D.*; Goriely, S.*; 稲倉 恒法*; Khan, E.*; 木戸 英治*; 木村 真明*; Litvinova, E.*; et al.

European Physical Journal A, 59(9), p.208_1 - 208_21, 2023/09

 被引用回数:7 パーセンタイル:76.15(Physics, Nuclear)

光核反応は原子核構造の観点からも応用の観点からも重要であるにも関わらず、その反応断面積は未だに不定性が大きい。近年、超高エネルギー宇宙線の起源を探るために、鉄よりも軽い原子核の光核反応断面積を正確に知る必要が指摘されている。この状況を打破するため、原子核物理の実験、理論、宇宙物理の共同研究となるPANDORAプロジェクトが始まった。本論文はその計画の概要をまとめたものである。原子核実験ではRCNP、iThembaによる仮想光子実験とELI-NPによる実光子実験などが計画されている。原子核理論では、乱雑位相近似計算、相対論的平均場理論、反対称化分子動力学、大規模殻模型計算などが計画されている。これらで得られた信頼性の高い光核反応データベースと宇宙線伝搬コードを組み合わせ、超高エネルギー宇宙線の起源の解明に挑む。

論文

A One-third magnetization plateau phase as evidence for the Kitaev interaction in a honeycomb-lattice antiferromagnet

Shangguan, Y.*; Bao, S.*; Dong, Z.-Y.*; Xi, N.*; Gao, Y.-P.*; Ma, Z.*; Wang, W.*; Qi, Z.*; Zhang, S.*; Huang, Z.*; et al.

Nature Physics, 19(12), p.1883 - 1889, 2023/09

 被引用回数:19 パーセンタイル:94.19(Physics, Multidisciplinary)

The magnetization of a quantum magnet can be pinned at a fraction of its saturated value by collective effects. One example of such a plateau phase is found in spin-1/2 triangular-lattice antiferromagnets. They feature strong geometrical frustration and the plateau phase therein is often interpreted as arising from an order-by-disorder mechanism driven by quantum fluctuations. Here we observe a one-third magnetization plateau under an applied magnetic field in the spin-1 antiferromagnet Na$$_{3}$$Ni$$_{2}$$BiO$$_{6}$$ with a honeycomb lattice, which, with conventional magnetic interactions, would not be geometrically frustrated. Based on our elastic neutron scattering measurements, we propose the spin structure of the plateau phase to be an unusual partial spin-flop ferrimagnetic order. Our theoretical calculations indicate that bond-anisotropic Kitaev interactions are the source of frustration that produces the plateau. These results suggest that Kitaev interactions provide a different route to frustration and phases driven by quantum fluctuations in high-spin magnets.

論文

Double-differential primary target neutron yields from dual-thick-target proton and heavy ion accelerator experiments

Ratliff, H.; McGirl, N. A.*; Beach, M. R.*; Castellanos, L. A.*; Clowdsley, M. S.*; Heilbronn, L. H.*; LaTessa, C.*; Norbury, J. W.*; Rusek, A.*; Sivertz, M.*; et al.

Nuclear Instruments and Methods in Physics Research B, 542, p.87 - 94, 2023/09

 被引用回数:1 パーセンタイル:26.66(Instruments & Instrumentation)

Experiments at the NASA Space Radiation Laboratory were performed to develop a benchmark dataset relevant to space radiation shielding scenarios by bombarding aluminum and polyethylene targets with galactic cosmic ray-like ion beams. Unique to this experiment, a dual-target configuration was used to emulate an enclosed environment in space in which the radiation environment must be characterized. Neutrons produced by interactions in both thick targets were detected and characterized; this paper discusses the neutrons produced in the most upstream of the two thick targets, detailing the role of source ion and target configuration on neutron yield.

論文

First observation of $$^{28}$$O

近藤 洋介*; Achouri, N. L.*; Al Falou, H.*; Atar, L.*; Aumann, T.*; 馬場 秀忠*; Boretzky, K.*; Caesar, C.*; Calvet, D.*; Chae, H.*; et al.

Nature, 620(7976), p.965 - 970, 2023/08

 被引用回数:27 パーセンタイル:94.86(Multidisciplinary Sciences)

非常に中性子が過剰な原子核$$^{28}$$Oは、陽子、中性子ともに魔法数であることから古くからその性質に興味が持たれていたが、酸素の最後の束縛核$$^{24}$$Oよりも中性子が4個も多いため、これまで観測されてこなかった。この論文では、理化学研究所RIBFにて$$^{29}$$Fからの1陽子ノックアウト反応によって$$^{28}$$Oを生成し、そこから放出される中性子を測定することによって初めてその観測に成功した。核構造の観点からは、$$^{28}$$Oでは二重閉殻が保たれているか興味が持たれていたが、実験で得られた分光学的因子が殻模型計算で予言されて程度の大きいことから、閉殻構造をもたない可能性が高いことがわかった。

論文

Level structures of $$^{56,58}$$Ca cast doubt on a doubly magic $$^{60}$$Ca

Chen, S.*; Browne, F.*; Doornenbal, P.*; Lee, J.*; Obertelli, A.*; 角田 佑介*; 大塚 孝治*; 茶園 亮樹*; Hagen, G.*; Holt, J. D.*; et al.

Physics Letters B, 843, p.138025_1 - 138025_7, 2023/08

 被引用回数:9 パーセンタイル:85.35(Astronomy & Astrophysics)

$$^{57,59}$$Scからの1陽子ノックアウト反応を用いて、$$^{56}$$Caと$$^{58}$$Caのガンマ崩壊を観測した。$$^{56}$$Caでは1456(12)keVの$$gamma$$線遷移が、$$^{58}$$Caでは1115(34)keVの遷移が観測された。どちらの遷移も暫定的に$$2^{+}_{1} rightarrow 0^{+}_{gs}$$と割り当てられた。有効核子間相互作用をわずかに修正した広い模型空間での殻模型計算では、$$2^{+}_{1}$$準位エネルギー、2中性子分離エネルギー、反応断面積が実験とよく一致し、N=34閉殻の上に新しい殻が形成されていることを裏付けた。その構成要素である$$0_{f5/2}$$$$0_{g9/2}$$軌道はほぼ縮退しており、これは$$^{60}$$Caが二重魔法核である可能性を排除し、Ca同位体のドリップラインを$$^{70}$$Caあるいはそれ以上にまで広げる可能性がある。

論文

Intruder configurations in $$^{29}$$Ne at the transition into the island of inversion; Detailed structure study of $$^{28}$$Ne

Wang, H.*; 安田 昌弘*; 近藤 洋介*; 中村 隆司*; Tostevin, J. A.*; 緒方 一介*; 大塚 孝治*; Poves, A.*; 清水 則孝*; 吉田 数貴; et al.

Physics Letters B, 843, p.138038_1 - 138038_9, 2023/08

 被引用回数:4 パーセンタイル:69.46(Astronomy & Astrophysics)

$$^{29}$$Neからの1中性子除去反応を用いて、$$^{28}$$Neの詳細な$$gamma$$線分光を行った。平行運動量分布の解析に基づき、$$^{28}$$Neの準位構造とスピンパリティを決定し、初めて負のパリティ状態を同定した。測定された断面積と運動量分布から、N=20とN=28のシェルギャップの消失の証拠となる有意なintruder p-wave強度が明らかになった。束縛状態については、弱いf-waveの可能性のある強度が観測された。いくつかの有効相互作用を用いた大規模殻模型計算では、実験的に観測された大きなp-wave強度と小さなf-wave強度は再現されず、Ne同位体に沿った反転の島への遷移の完全な理論的記述への挑戦が続いていることを示している。

論文

High-density nanoprecipitates and phase reversion via maraging enable ultrastrong yet strain-hardenable medium-entropy alloy

Kwon, H.*; Sathiyamoorthi, P.*; Gangaraju, M. K.*; Zargaran, A.*; Wang, J.*; Heo, Y.-U.*; Harjo, S.; Gong, W.; Lee, B.-J.*; Kim, H. S.*

Acta Materialia, 248, p.118810_1 - 118810_12, 2023/04

 被引用回数:48 パーセンタイル:99.21(Materials Science, Multidisciplinary)

Maraging steels, known for ultrahigh strength and good fracture toughness, derive their superior properties from lath martensite structure with high-density nanoprecipitates. In this work, we designed a novel Fe-based medium-entropy alloy with a chemical composition of Fe$$_{60}$$Co$$_{25}$$Ni$$_{10}$$Mo$$_5$$ in atomic% by utilizing the characteristics of the maraging steels. By a single-step aging of only 10 min at 650 $$^{circ}$$C, the alloy showed microstructures consisting of a very high number density of (Fe, Co, Ni)$$_7$$Mo$$_6$$-type nanoprecipitates in lath martensite structure and reverted FCC phase, which led to ultrahigh yield strength higher than 2 GPa. This work demonstrates a novel direction to produce strong and ductile materials by expanding the horizons of material design with the aid of high-entropy concept and overcoming the limits of conventional materials.

論文

Pressure-modulated magnetism and negative thermal expansion in the Ho$$_2$$Fe$$_{17}$$ intermetallic compound

Cao, Y.*; Zhou, H.*; Khmelevskyi, S.*; Lin, K.*; Avdeev, M.*; Wang, C.-W.*; Wang, B.*; Hu, F.*; 加藤 健一*; 服部 高典; et al.

Chemistry of Materials, 35(8), p.3249 - 3255, 2023/04

 被引用回数:2 パーセンタイル:21.90(Chemistry, Physical)

静水圧や化学圧力は、結晶構造を変化させる効率的な刺激であり、材料科学において電気的、磁気的特性のチューニングによく利用されている。しかし、化学圧力は定量化が困難であり、これら両者の定量的な対応関係はまだよくわかっていない。本研究では、負の熱膨張(NTE)を持つ永久磁石の候補である金属間化合物を調べた。放射光X線その場観察により、AlをドープしたHo$$_2$$Fe$$_{17}$$に負の化学圧力があることを明らかにし、単位セル体積の温度・圧力依存性を用いそれを定量的に評価した。また、磁化測定と中性子回折測定を組み合わせることで、磁気秩序に対する化学圧力と静水圧の違いを比較した。興味深いことに、圧力はNTEの抑制と増強を制御するために使用することができた。電子状態計算から、圧力がFermiレベル(EF)に対する主要バンドの上部に影響を与えたことを示しており、これは磁気安定性に影響を与え、それが磁気とNTEを調節する上で重要な役割を果たしていることがわかった。本研究は、圧力の影響を理解し、それを利用して機能性材料の特性を制御する良い例を示している。

論文

A Colossal barocaloric effect induced by the creation of a high-pressure phase

Jiang, X.*; 服部 高典; Xu, X.*; Li, M.*; Yu, C.*; Yu, D.*; Mole, R.*; 矢野 真一郎*; Chen, J.*; He, L.*; et al.

Materials Horizons, 10(3), p.977 - 982, 2023/03

 被引用回数:26 パーセンタイル:93.43(Chemistry, Multidisciplinary)

現在の蒸気圧縮式冷凍機に代わる環境に優しい冷凍機として、バロカロリック効果に基づく固体冷凍機が世界的に注目されている。一般に、バロカロリック効果が発現する相はいずれも常圧でも存在する。ここでは、それらの物質と違って、KPF$$_{6}$$が高圧の菱面体晶相を生成することにより、巨大なバロカロリック効果を示すことを実証した。相図は、圧力依存の熱量測定、ラマン散乱測定、中性子回折測定に基づいて構築されたものである。本研究は、巨大バロカロリー効果に、高圧相の生成という新たな手法をもたらすと期待される。

論文

Tensile overload-induced texture effects on the fatigue resistance of a CoCrFeMnNi high-entropy alloy

Lam, T.-N.*; Chin, H.-H.*; Zhang, X.*; Feng, R.*; Wang, H.*; Chiang, C.-Y.*; Lee, S. Y.*; 川崎 卓郎; Harjo, S.; Liaw, P. K.*; et al.

Acta Materialia, 245, p.118585_1 - 118585_9, 2023/02

 被引用回数:24 パーセンタイル:88.92(Materials Science, Multidisciplinary)

The present study investigates the crystallographic-texture effects on the improved fatigue resistance in the CoCrFeMnNi high-entropy alloys (HEAs) with the full-size geometry of the ASTM Standards E647-99. We exploited X-ray nano-diffraction mapping to characterize the crystal-deformation levels ahead of the crack tip after stress unloading under both constant- and tensile overloaded-fatigue conditions. The crack-tip blunting-induced much higher deformation level was concentrated surrounding the crack-tip which delays the fatigue-crack growth immediately after a tensile overload. The predominant deformation texture orientation in the Paris regime was investigated, using electron backscatter diffraction and orientation distribution function analyses. The twinning formation-driven shear deformation gave rise to the development of the Goss-type texture within the plastic deformation regime under a tensile-overloaded-fatigue condition, which was attributed to enhance the crack deflection and thus the tensile induced crack-growth-retardation period in the CoCrFeMnNi HEA.

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