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岡根 哲夫; 藤森 伸一; 間宮 一敏; 岡本 淳; 村松 康司; 藤森 淳; 鈴木 博之*; 松本 武彦*; 古林 孝夫*; 磯部 雅朗*; et al.
Journal of Magnetism and Magnetic Materials, 272-276(Suppl.), p.e297 - e298, 2004/05
被引用回数：5 パーセンタイル：28.90(Materials Science, Multidisciplinary)金属-絶縁体転移を示すスピネル・カルコゲナイドCuIrSの温度に依存した電子状態の変化を高分解能軟X線光電子分光により実験的に調べた。試料温度が転移温度以下になると、フェルミ準位近傍でギャップの形成が見られる一方、価電子帯全体の構造も高エネルギー側にシフトしていることが明らかになった。またIr 4
内殻準位の光電子スペクトルの形状は転移温度の上と下で非常に顕著な形状変化を示した。このことは金属-絶縁体転移に伴うIr 5
電子状態の変化に対応したものと考えられる。
久保園 芳博*; 三村 和江*; 高林 康裕*; 前田 裕宣*; 柏野 節夫*; 江村 修一*; 西畑 保雄; 宇留賀 朋哉*; 田中 庸裕*; 高橋 昌男*
Journal of Synchrotron Radiation, 6(Part3), p.564 - 566, 1999/05
擬一次元系ポリマーであるRbCの約50Kでの金属-絶縁体相転移の起源を明らかにするために、RbC安定相のRb-K吸収端でのXAFSが、14.6から210Kの温度範囲で測定された。XAFSによって決められたRbとCの原子間距離と平均自乗変位は50Kで異常を示さず、その金属-絶縁体相転移はSDW不安定性を起源としていることが示唆される。
Opletal, P.; 酒井 宏典; 芳賀 芳範; 三宅 厚志*; 徳永 将史*; 常盤 欣文; 山本 悦嗣; 神戸 振作; 徳永 陽
no journal, ,
UOX (X = S, Se, Te) crystallizes in tetragonal PbFCl-type structure (P4/nmm space group). Only polycrystalline samples are reported in literature. UOS, UOSe and UOTe were reported to be antiferromagnets with T
= 55, 100 and 160 K, respectively. Magnetic structure of UOS and UOSe were reported to have moment along the c-axis with Q = (0,0,1/2). UOS and UOSe were both reported to exhibit semiconducting behavior on polycrystalline samples. UOTe was theoretically predicted to have nontrivial topology. We have prepared first single crystals of UOX (X = S, Se, Te) and shown they exhibit semimetallic conductivity and UOS exhibits increase of T by almost 30 K in contrast to published literature. We will present the method of preparation of single crystals, results of magnetic, transport, thermal measurements, all effect and data obtained in high magnetic fields. We will discuss these results in connection to Weyl semimetals and results published in literature and anisotropy observed in electric resistivity.
Opletal, P.; 酒井 宏典; 芳賀 芳範; 三宅 厚志*; 徳永 将史*; 常盤 欣文; 山本 悦嗣; 神戸 振作; 徳永 陽
no journal, ,
UOX (X = S, Se, Te) crystallizes in tetragonal PbFCl-type structure (P4/nmm space group). Only polycrystalline samples are reported in literature. UOS, UOSe and UOTe were reported to be antiferromagnets with T
= 55, 100 and 160 K, respectively. Magnetic structure of UOS and UOSe were reported to have moment along the c-axis with Q = (0,0,1/2). UOS and UOSe were both reported to exhibit semiconducting behavior on polycrystalline samples. UOTe was theoretically predicted to have nontrivial topology. We have prepared first single crystals of UOX (X = S, Se, Te) and shown they exhibit semimetallic conductivity and UOS exhibits increase of T by almost 30 K in contrast to published literature. We will present the method of preparation of single crystals, results of magnetic, transport, thermal measurements, all effect and data obtained in high magnetic fields. We will discuss these results in connection to Weyl semimetals and results published in literature and anisotrpy observed in electric resistivity.
Opletal, P.; 酒井 宏典; 芳賀 芳範; 常盤 欣文; 山本 悦嗣; 神戸 振作; 徳永 陽
no journal, ,
Magnetic semimetals are currently focus of research due to possible electronic topological features. Topological features originate from nontrivial band characters. One of the most interesting state is Weyl fermion which originate from band splitting driven by spin-orbit interaction due to the inversion symmetry breaking or time-reversal symmetry breaking. The materials with these properties are called Weyl semimetals. Wey fermions are expected to be robust and have high mobility, which is important for practical application of topological matter. Uranium materials are interesting candidates for Weyl semimetals because of their strong spin-orbit interaction causing band inversion and/or strong electronic correlations, often observed as 5f magnetism. One of the possible candidates are UOX (X = S, Se, Te) compounds. We measured electric resistivity of UOX using Montgomery method. The resistivity along a-axis shows metallic/semi-metallic behavior in whole temperature region while resistivity in along the c-axis shows dramatic increase below T. We will discuss possible origin of this increase in relation to crystal and band structure.
