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Journal Articles

Local structure study of the iron-based systems of BaFe$$_2$$As$$_2$$ and LiFeAs by X-ray PDF and XAFS analyses

Li, S.*; Toyoda, Masayuki*; Kobayashi, Yoshiaki*; Ito, Masayuki*; Ikeuchi, Kazuhiko*; Yoneda, Yasuhiro; Otani, Akira*; Matsumura, Daiju; Asano, Shun*; Mizuki, Junichiro*; et al.

Physica C, 555, p.45 - 53, 2018/12

 Times Cited Count:1 Percentile:5.02(Physics, Applied)

${it T}$-dependence of local distortions in BaFe$$_2$$As$$_2$$ and LiFeAs by X-ray PDF and XAFS methods. Although PDF data exhibit anomaly at the structure transition temperature, EXAFS data exhibit no anomaly. Data supporting the local orthorhombicity at 300 K in the tetragonal phase for BaFe$$_2$$As$$_2$$. Arguments on the origins of the 4-fold symmetry breaking in the ground average structure of the tetragonal phase.

Journal Articles

Study of oxygen ion diffusion in (Ba$$_{0.5}$$Sr$$_{0.5}$$)(Co$$_{0.8}$$Fe$$_{0.2}$$)O$$_{2.33-delta}$$ through ${it in-situ}$ neutron diffractions at 300 and 720 K

Ito, Takanori*; Hirai, Takene*; Yamashita, Junichi*; Watanabe, Shoji*; Kawata, Etsuya*; Kitamura, Naoto*; Idemoto, Yasushi*; Igawa, Naoki

Physica B; Condensed Matter, 405(8), p.2091 - 2096, 2010/04

 Times Cited Count:15 Percentile:55.02(Physics, Condensed Matter)

We analyze the mechanism of oxygen ion diffusion in (Ba$$_{0.5}$$Sr$$_{0.5}$$)(Co$$_{0.8}$$Fe$$_{0.2}$$)O$$_{2.33-delta}$$ by using the Rietveld refinement, the maximum entropy method (MEM) analysis, and MEM-based pattern fitting (MPF) with ${it in-situ}$ neutron diffractions at 300 and 720 K. We speculate that when $$U$$$$_{rm aniso}$$ and neutron scattering density of O1(4${it c}$) site with a large number of vacancies metamorphose into that with anisotropy directed toward the O1(4${it c}$) and O2(8${it d}$) sites at 720 K, the oxygen ions diffuse along the paths between O1(4${it c}$) and O1(4${it c}$), and O1(4${it c}$) and O2(8${it d}$).

Journal Articles

Characterization of electrode/electrolyte interface for lithium batteries using ${it in situ}$ synchrotron X-ray reflectometry; A New experimental technique for LiCoO$$_{2}$$ model electrode

Hirayama, Masaaki*; Sonoyama, Noriyuki*; Abe, Takashi*; Minoura, Machiko*; Ito, Masumi*; Mori, Daisuke*; Yamada, Atsuo*; Kanno, Ryoji*; Terashima, Takahito*; Takano, Mikio*; et al.

Journal of Power Sources, 168(2), p.493 - 500, 2007/06

 Times Cited Count:89 Percentile:90.34(Chemistry, Physical)

A new experimental technique was developed for detecting structure changes at electrode/electrolyte interface of lithium cell using X-ray reflectometry and two-dimensional model electrodes with a restricted lattice-plane. The electrodes were constructed with an epitaxial film of LiCoO$$_{2}$$ synthesized by pulsed laser deposition method. The anisotropic properties were confirmed by electrochemical measurements. ${it Ex situ}$ X-ray reflectivity measurements indicated that the impurity layer existed on the as-grown LiCoO$$_{2}$$ was dissolved and a new SEI layer with lower density was formed after soaking into the electrolyte. ${it In situ}$ X-ray reflectivity measurements indicated that the surface roughness of the intercalation (1 1 0) plane increased with applying voltages, while no significant changes in surface morphology were observed for the intercalation non-active (0 0 3) plane during the pristine stage of the charge-discharge process.

Journal Articles

Coherent X-ray diffraction for domain observation

Owada, Kenji; Namikawa, Kazumichi; Mizuki, Junichiro; Shimomura, Susumu*; Nakao, Hironori*; Ito, Kazuki*; Matsushita, Mitsuyoshi*; Yoneda, Yasuhiro; Murakami, Yoichi*; Hirota, Kazuma*

Transactions of the Materials Research Society of Japan, 32(1), p.7 - 10, 2007/03

An X-ray speckle pattern well reflects a particle or domain alignment on the inside of materials. Detecting the alignment is important for understanding a function of the materials such as ferroelectric, piezoelectric materials, photonic crystals and so on. We have thus constructed the apparatus for coherent X-ray diffraction at BL22XU@SPring-8, high quality slits for obtaining the full coherent X-ray beam, high resolution X-ray CCD camera for obtaining the well-resolved speckle pattern, and so on. By using the devices, we have successfully observed the speckle pattern from Cu$$_{3}$$Au, the ferroelectric material PZN-9%PT (91%Pb(Zn$$_{1/3}$$Nb$$_{2/3}$$)O$$_{3}$$-9%PbTiO$$_{3}$$) and Sr-doped BaTiO$$_{3}$$. The 2DFFT image gives us a spatial autocorrelation function which includes the information of the arrangement of the domains in the crystal within micrometers scale.

Journal Articles

Characterization of electrode/electrolyte interface with X-ray reflectometry and epitaxial-film LiMn$$_{2}$$O$$_{4}$$ electrode

Hirayama, Masaaki*; Sonoyama, Noriyuki*; Ito, Masumi*; Minoura, Machiko*; Mori, Daisuke*; Yamada, Atsuo*; Tamura, Kazuhisa; Mizuki, Junichiro; Kanno, Ryoji*

Journal of the Electrochemical Society, 154(11), p.A1065 - A1072, 2007/00

 Times Cited Count:96 Percentile:95.4(Electrochemistry)

Structural changes at electrode/electrolyte interface of a lithium cell were studied by X-ray reflectometry and two-dimensional model electrodes with a restricted lattice plane of LiMn$$_{2}$$O$$_{4}$$. The ex situ reflectometry indicated that a thin impurity layer covered the lattice plane of the as-grown film. The impurity layer was dissolved and a solid-electrolyte-interface-like phase appeared after the electrode was soaked into the electrolyte. The in situ observation clarified that the surface reactivity depended on the lattice planes of the spinel; the defect layer at the (111) plane was stable during the electrochemical reaction, whereas a slight decrease in the film thickness was observed for the (110) plane. Our surface characterization of the intercalation electrode indicated that the surface structure changes during the pristine stage of the change-discharge processes and these changes are dependent on the lattice orientation of LiMn$$_{2}$$O$$_{4}$$.

Journal Articles

Anoxic dissolution processes of biotite; Implications for Fe behavior during Archean weathering

Murakami, Takashi*; Ito, Junichi*; Utsunomiya, Satoshi*; Kasama, Takeshi*; Kozai, Naofumi; Onuki, Toshihiko

Earth and Planetary Science Letters, 224(1-2), p.117 - 129, 2004/07

 Times Cited Count:33 Percentile:53.32(Geochemistry & Geophysics)

no abstracts in English

Journal Articles

Photoionization of Ne$$^{3+}$$ ions in the region of the 1${it s}$ $$rightarrow$$ 2${it p}$ autoionizing resonance

Oura, Masaki*; Yamaoka, Hitoshi*; Kawatsura, Kiyoshi*; Kimata, Junichi*; Hayaishi, T.*; Takahashi, Takehisa*; Koizumi, Tetsuo*; Sekioka, T.*; Terasawa, Michitaka*; Ito, Yo*; et al.

Physical Review A, 63(1), p.014704_1 - 014704_4, 2001/01

 Times Cited Count:15 Percentile:59.79(Optics)

no abstracts in English

JAEA Reports

None

Seno, Muneaki*; *; Ito, Kenji*; Ambo, Noriaki*; *

PNC TJ1561 98-002, 129 Pages, 1998/02

PNC-TJ1561-98-002.pdf:4.82MB

None

Journal Articles

Operation of the negative-ion based NBI for JT-60U

Kuriyama, Masaaki; Akino, Noboru; *; Ito, Takao; Inoue, Takashi; Usui, Katsutomi; Ebisawa, Noboru; Oshima, Katsumi*; Ohara, Yoshihiro; Ohara, Hiroshi; et al.

Fusion Engineering and Design, 39-40, p.115 - 121, 1998/00

 Times Cited Count:36 Percentile:91.63(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Development of negative-ion based NBI system for JT-60

Kuriyama, Masaaki; Aoyagi, Tetsuo; ; *; Ito, Takao; Inoue, Takashi; Usami, H*; Usui, Katsutomi; ; Oshima, Katsumi*; et al.

Nihon Genshiryoku Gakkai-Shi, 38(11), p.912 - 922, 1996/00

 Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)

no abstracts in English

JAEA Reports

Construction of tangential injection NBI system

Oga, Tokumichi; ; ; *; Ito, Takao; *; Kawai, Mikito; *; Komata, Masao; Kunieda, Shunsuke; et al.

JAERI-Tech 95-044, 147 Pages, 1995/09

JAERI-Tech-95-044.pdf:4.65MB

no abstracts in English

JAEA Reports

Absolute calibration of the neutron yield measurement on JT-60 Upgrade

Nishitani, Takeo; Takeuchi, Hiroshi; Barnes, C. W.*; Iguchi, Tetsuo*; Nagashima, Akira; Kondoh, Takashi; Sakasai, Akira; Itami, Kiyoshi; Tobita, Kenji; Nagashima, Keisuke; et al.

JAERI-M 91-176, 23 Pages, 1991/10

JAERI-M-91-176.pdf:1.08MB

no abstracts in English

JAEA Reports

Shielding Experiment of a Spent Fuel Transport Cask for a PWR Spent Fuel Assembly

; *; ; ; ; ; ; ; ; ; et al.

JAERI-M 82-201, 60 Pages, 1982/12

JAERI-M-82-201.pdf:1.99MB

no abstracts in English

Journal Articles

Construction of a waste treatment plant at the Japan Atomic Energy Research Institute; The plan, progress, and result

*; ; Ishihara, Takehiko; ; ; ; ; ; ; ; et al.

Dai-3-Kai Genshiryoku Shimpojiumu Hobunshu, 2, P. 40, 1959/00

no abstracts in English

Oral presentation

Verification of optical fiber current transformer with a sensor of flint glass in JT-60U

Nishiyama, Tomokazu; Yagyu, Junichi; Arai, Takashi; Kurosawa, Kiyoshi*; Ito, Akira*; Hayashi, Takao; Miya, Naoyuki; Miyo, Yasuhiko; Sasajima, Tadayuki; Kawamata, Yoichi

no journal, , 

no abstracts in English

Oral presentation

Study of hydrogen storage characteristics and structual changes of hydrogen materials by ion irradiation

Abe, Hiroshi; Uchida, Hirohisa*; Morimoto, Ryo*; Yoneda, Yasuhiro; Mizuki, Junichiro; Ito, Hisayoshi

no journal, , 

no abstracts in English

Oral presentation

Polarised neutron spectrometer, POLANO, at J-PARC attempts at understanding novel magnetism

Oyama, Kenji*; Yokoo, Tetsuya*; Ito, Shinichi*; Suzuki, Junichi*; Iwasa, Kazuaki*; Sato, Taku*; Kira, Hiroshi*; Sakaguchi, Yoshifumi*; Ino, Takashi*; Oku, Takayuki; et al.

no journal, , 

19 (Records 1-19 displayed on this page)
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