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Nagai, Takayuki; Okamoto, Yoshihiro; Yamagishi, Hirona*; Ota, Toshiaki*; Kojima, Kazuo*; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*
JAEA-Research 2021-010, 62 Pages, 2022/01
The local structure of glass-forming elements and waste elements in borosilicate glasses varies with its chemical composition. In this study, borosilicate glass frit and simulated waste glass samples were prepared and the local structure and chemical state regarding boron(B), oxygen(O), silicon(Si) and waste elements of iron(Fe), cesium(Cs) were estimated by using XAFS measurement in soft X-ray region. Following results were obtained by XAFS measurements of prepared glass frit and simulated waste glass samples: (1) The effect of NaO concentration on B-O coordination structure is greater than that of the waste elements concentration. (2) The height of pre-edge by O K-edge spectrum depends on the concentration of first transition elements such as Fe in glass samples. Following results were obtained by XAFS measurements of simulated waste glass samples after immersion test to investigate the long chemical stability. (1) A new compound was formed on the sample surface after the immersion test, and changes in the surface state were confirmed by Raman spectroscopy. (2) Cs on the sample surface after immersion test dissolves into the leaching solution. The Si K-edge XANES spectra of borosilicate glass frits and simulated waste glass samples included lanthanides oxide were measured, and following was confirmed. (1) As the NaO concentration increases in borosilicate glass frit, the K-edge peak of Si shifts to the low energy side. (2) The peak height of the K-edge of Si differs depending on the kind of lanthanide.
Nagai, Takayuki; Okamoto, Yoshihiro; Yamagishi, Hirona*; Ota, Toshiaki*; Kojima, Kazuo*; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*
JAEA-Research 2020-009, 48 Pages, 2020/09
The local structure of glass-forming elements and waste elements in waste glass varies with its chemical composition. In this study, borosilicate glass frit and simulated waste glass samples were prepared and the local structure and chemical state regarding boron (B), oxygen (O), and waste elements of cerium (Ce), cesium (Cs) were estimated by using XAFS measurement in soft X-ray region. Following results were obtained by XAFS measurements of prepared glass frit and simulated waste glass samples: (1) The existence ratio of four coordinate sp structure (BO) tends to increase with increasing NaO content in glass samples. (2) The height of a pre-edge which appears by K-edge XANES spectrum of O is so high that the Fe content in glass samples. Following results were obtained by XAFS measurements of simulated waste glass samples after immersion test to investigate long chemical stability. (1) The existence ratio of four coordinate sp structure (BO) increases by immersion test. (2) Ce which exists in the surface layer is oxidized by immersion test, and much of Cs in surface layer is lost after leach testing. Even if the glass frit form (fiber cartridge or beads) and manufacturing method were changed and a glass sample of the similar chemical composition was prepared, these observed Raman spectra of samples were different.
Shimizu, Takeshi*; Wang, H.*; Matsumura, Daiju; Mitsuhara, Kei*; Ota, Toshiaki*; Yoshikawa, Hirofumi*
ChemSusChem, 13(9), p.2256 - 2263, 2020/05
Times Cited Count:24 Percentile:77.17(Chemistry, Multidisciplinary)Nagai, Takayuki; Sasage, Kenichi; Okamoto, Yoshihiro; Shiwaku, Hideaki; Yamagishi, Hirona*; Ota, Toshiaki*; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*; Takahashi, Tomoe*; et al.
JAEA-Research 2019-003, 94 Pages, 2019/09
The local structures of glass-forming elements and waste elements would change by the chemical composition of waste glass including those elements. In this study, simulated waste glass samples were prepared from borosilicate glass frit including phosphorus (P) or vanadium (V), and we investigated local structures of boron, sodium, and waste elements in these P glass and V glass samples by using synchrotron XAFS measurements in soft and hard X ray region.
Nagai, Takayuki; Kobayashi, Hidekazu; Shimamura, Keisuke; Oyama, Koichi; Sasage, Kenichi; Okamoto, Yoshihiro; Shiwaku, Hideaki; Yamanaka, Keisuke*; Ota, Toshiaki*
JAEA-Research 2018-005, 72 Pages, 2018/09
Addition of radioactive waste to a borosilicate glass frit affects the local structures of glass-forming elements and waste elements in a waste glass produced in a vitrification process. In this study, simulated waste glass samples were prepared from borosilicate glass frit including phosphorus pentaoxide, and we investigated local structures of sodium (Na), boron (B), and waste elements in these glass samples by using synchrotron XAFS measurements in soft and hard X ray region.
Shimizu, Takeshi*; Wang, H.*; Tanifuji, Naoki*; Matsumura, Daiju; Yoshimura, Masashi*; Nakanishi, Koji*; Ota, Toshiaki*; Yoshikawa, Hirofumi*
Chemistry Letters, 47(5), p.678 - 681, 2018/05
Times Cited Count:9 Percentile:33.87(Chemistry, Multidisciplinary)Okamoto, Yoshihiro; Nagai, Takayuki; Kaneko, Koji; Motokawa, Ryuhei; Haga, Yoshinori; Yamanaka, Keisuke*; Ota, Toshiaki*
2017-Nendo Seika Kokaigata Riyo Seika Hokokusho (Ritsumeikan Daigaku SR Senta), p.33 - 36, 2018/00
The high-level radioactive waste solution which generated from a spent nuclear fuel reprocessing process are mixed with a borosilicate glass frit in a vitrification process, and a chemical stable glass solidified body is produced. To understand local structure of light elements included in a glass solidified body, we carried out a B K-edge XANES measurement of raw glass frits and simulated radioactive waste glasses. As a result of this estimation of boron local structure in glass samples, it was found that the sp type boron (BO) percentage increases and the sp type (BO) percentage by increasing the sodium content in glass frits.
Nagai, Takayuki; Kobayashi, Hidekazu; Sasage, Kenichi; Ayame, Yasuo; Okamoto, Yoshihiro; Shiwaku, Hideaki; Yamanaka, Keisuke*; Ota, Toshiaki*
JAEA-Research 2017-005, 54 Pages, 2017/06
Addition of radioactive waste to a borosilicate frit affects the local structures of boron (B) and waste elements in a waste glass. Synchrotron XAFS measurement was applied to investigate the local structural changes by using simulated waste borosilicate glass samples. Following results were obtained by the B K-edge XAFS analysis. It was confirmed that B K-edge XAFS analysis enables us to discriminate sp type boron (BO) from sp type boron (BO). Addition of waste elements to a glass frit increases the percentage of BO and decreases that of BO. By decreasing the SiO/AlO ratio or increasing the (SiO+BO)/AlO ratio in the glass composition, the BO percentage increases and the BO percentage decreases. Addition of PO decreases the BO percentage and increases the BO percentage. Following results were obtained from XAFS measurement of the waste elements. Cerium (Ce) valence is more reduced with the increase of the BO content. Addition of PO has a tendency to reduce the Ce valence and to enhance deposition of Zr oxide. Deposition of ruthenium compounds separated from glass phase can not be improved by changing the BO content. This study was performed as a part of the project, "Improvement of vitrification process of high-level radioactive liquid wastes" on the foundation business of the Agency for Natural Resources and Energy.
*; Shoji, Teruaki; Mori, Masahiro; Odajima, Kazuo; Otsuka, Hideo; Suzuki, Norio; Hasegawa, Mitsuru*; *; Sugihara, Masayoshi; Uesugi, Yoshihiko; et al.
JAERI-M 87-192, 21 Pages, 1987/10
no abstracts in English
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JAERI-M 87-042, 11 Pages, 1987/03
no abstracts in English
; ; ; ; ; ; *; ; ; ; et al.
Physical Review Letters, 58(21), p.2220 - 2223, 1987/00
Times Cited Count:26 Percentile:79.55(Physics, Multidisciplinary)no abstracts in English
; ; ; Sengoku, Seio; ; ; ; ; *; ; et al.
JAERI-M 86-109, 16 Pages, 1986/07
no abstracts in English
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JAERI-M 9544, 174 Pages, 1981/07
no abstracts in English
Yamanaka, Keisuke*; Nagai, Takayuki; Ota, Toshiaki*
no journal, ,
For understanding the fundamental knowledge in the vitrification process of radioactive waste, the local structure of boron of simulated waste glass was investigated by using the XAFS measurement in BL-11 of Ritsumeikan University SR Center.
Nagai, Takayuki; Okamoto, Yoshihiro; Yamanaka, Keisuke*; Ota, Toshiaki*
no journal, ,
no abstracts in English
Nagai, Takayuki; Kobayashi, Hidekazu; Okamoto, Yoshihiro; Yamanaka, Keisuke*; Ota, Toshiaki*
no journal, ,
no abstracts in English
Nagai, Takayuki; Okamoto, Yoshihiro; Yamagishi, Hirona*; Ota, Toshiaki*
no journal, ,
no abstracts in English
Nagai, Takayuki; Okamoto, Yoshihiro; Kaneko, Koji; Motokawa, Ryuhei; Haga, Yoshinori; Yamagishi, Hirona*; Yamanaka, Keisuke*; Ota, Toshiaki*
no journal, ,
no abstracts in English