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Journal Articles

Using CO$$_{2}$$ Reactions to Achieve Mass-spectrometric Discrimination in Simultaneous Plutonium-isotope Speciation with Inductively Coupled Plasma-Tandem Mass Spectrometry

Matsueda, Makoto; Kawakami, Tomohiko*; Koarai, Kazuma; Terashima, Motoki; Fujiwara, Kenso; Iijima, Kazuki; Furukawa, Makoto*; Takagai, Yoshitaka*

Chemistry Letters, 51(7), p.678 - 682, 2022/07

 Times Cited Count:6 Percentile:58.73(Chemistry, Multidisciplinary)

New methodology for a simultaneous isotope speciation of various Pu isotopes without complicated isobaric interferences is developed by using inductively coupled plasma-mass spectrometry (ICP-MS). In analyzing ICP tandem MS (ICP-MS/MS), CO$$_{2}$$ gas reactions in a dynamic reaction cell (DRC) almost eliminated the background noise intensity produced by isobaric interference from isotopes originating from actinides such as Am, Cm, and U at the locations (m/z) of significant Pu isotopes ($$^{239}$$Pu, $$^{240}$$Pu, $$^{241}$$Pu, $$^{242}$$Pu, $$^{244}$$Pu).

Journal Articles

Operational characteristics of the J-PARC cryogenic hydrogen system for a spallation neutron source

Tatsumoto, Hideki; Otsu, Kiichi; Aso, Tomokazu; Kawakami, Yoshihiko; Teshigawara, Makoto

AIP Conference Proceedings 1573, p.66 - 73, 2014/01

 Times Cited Count:6 Percentile:92.61(Thermodynamics)

The J-PARC cryogenic hydrogen system provides supercritical hydrogen provides to three moderators. A heater for the thermal compensation and a cryogenic accumulator are prepared to mitigate a pressure fluctuation. A feed temperature should be lower than 20 K and its fluctuation should be within 0.25 K to provide cold pulsed neutron beams of a higher neutronic performance. An ortho-para hydrogen convertor is installed to maintain the para-hydrogen concentration of more than 99.0%. In this study, it is confirmed that para-hydrogen always exists in the equilibrium concentration during the cool-down process. Propagation characteristics of temperature fluctuation caused by sudden heater power variations were studied. An allowable temperature fluctuation caused by the heater control approach is determined to be 1.05 K. It is found that the heater control would be applicable for the 1-MW proton beam operation by extrapolating from the experimental data for on-beam commissioning.

Journal Articles

Performance test of a centrifugal supercritical hydrogen pump

Tatsumoto, Hideki; Aso, Tomokazu; Otsu, Kiichi; Uehara, Toshiaki; Sakurayama, Hisashi; Kawakami, Yoshihiko; Kato, Takashi; Futakawa, Masatoshi; Yoshinaga, Seiichiro*

Proceedings of International Cryogenic Engineering Conference 23 (ICEC-23) and International Cryogenic Materials Conference 2010 (ICMC 2010), p.377 - 382, 2010/07

A dynamic gas bearing centrifugal pump that circulated supercritical hydrogen with a large flow rate of more than 0.16 kg/s was developed to minimize the hydrogen density change at the moderator. The two pumps were simultaneously operated in parallel for redundancy. The performance test results indicated that the dimensionless characteristics for the single and the parallel operations existed on an identical curve. An outstanding peak adiabatic efficiency exited at the flow coefficient of 0.046, independently of the revolution. It was verified that the developed hydrogen pump satisfied the design requirement.

Journal Articles

Production of a low-energy radioactive nuclear beam with high purity using JAERI-RMS

Ishiyama, Hironobu*; Ishikawa, Tomoko*; Hashimoto, Takashi; Watanabe, Yutaka*; Hirayama, Yoshikazu*; Imai, Nobuaki*; Miyatake, Hiroari; Tanaka, Masahiko*; Fuchi, Yoshihide*; Yoshikawa, Nobuharu*; et al.

Nuclear Instruments and Methods in Physics Research A, 560(2), p.366 - 372, 2006/05

 Times Cited Count:7 Percentile:47.41(Instruments & Instrumentation)

Thanks to the nature of inverse transfer-reactions, low-energy radioactive nuclear beams in light neutron-rich region were produced. The mass-separation and velocity-separation of the JAERI recoil mass-separator help to form high purity beams. The beams of $$^8$$Li, $$^{12}$$B, and $$^{16}$$N-RNBs are utilized to the experiments, so far, with those beam intensities and purities of 1.4$$times$$10$$^4$$ pps and 99$$%$$, 7.8$$times$$10$$^3$$ pps and 98$$%$$, and 4.7$$times$$10$$^3$$ pps and 98.5$$%$$, respectively.

Journal Articles

Safety issues in TRIAC facility

Nakanoya, Takamitsu; Abe, Shinichi; Matsuda, Makoto; Nishio, Katsuhisa; Hanashima, Susumu; Ichikawa, Shinichi; Tsukihashi, Yoshihiro; Takeuchi, Suehiro; Ishiyama, Hironobu*; Jeong, S.-C.*; et al.

Dai-17-Kai Tandemu Kasokuki Oyobi Sono Shuhen Gijutsu No Kenkyukai Hokokushu, p.123 - 126, 2004/00

no abstracts in English

JAEA Reports

Crack extension analysis under pressurized thermal shock loading by ADINA

Isozaki, Toshikuni; Shibata, Katsuyuki; *; *

JAERI-Research 96-039, 133 Pages, 1996/07

JAERI-Research-96-039.pdf:3.85MB

no abstracts in English

Journal Articles

Life estimation of cable insulating materials by long term radiation-thermal aging terts

Kusama, Yasuo; Kawakami, Waichiro; *; *; *

EIM-90-123, p.55 - 64, 1990/12

no abstracts in English

Journal Articles

Development of diagnostic methodology of degradation of electric wire and cables by a stress-strain response measurement

Yagi, Toshiaki; Morita, Yosuke; Kawakami, Waichiro; *; *; *; *

EIM-90-124, p.65 - 74, 1990/12

no abstracts in English

Journal Articles

Radiation resistance of thermoplastic polyurethane elastomer

Yagi, Toshiaki; Kawakami, Waichiro; *; *

EIM-89-114, p.1 - 9, 1989/12

no abstracts in English

Journal Articles

Effect of radiation oxidation on various properties of insulating materials

Kusama, Yasuo; Kawakami, Waichiro; *; *

EIM-89-116, p.21 - 29, 1989/12

no abstracts in English

JAEA Reports

None

Iwai, Makoto; Kurosu, Goro; Oka, Tsutomu; Asano, Tomohiro; Kawakami, Ryuji; Fukazawa, Tatsuo

PNC TN8420 86-001, 294 Pages, 1986/01

PNC-TN8420-86-001.pdf:7.36MB

None

JAEA Reports

Seismic Analysis of the JT-60,2; Dynamic Responce Analysis

; ; *; *

JAERI-M 8350, 39 Pages, 1979/07

JAERI-M-8350.pdf:1.1MB

no abstracts in English

JAEA Reports

Seismic Analysis of the JT-60, 1; Analysis Method and Eigenvalue Analysis

; ; *; *

JAERI-M 8155, 159 Pages, 1979/03

JAERI-M-8155.pdf:4.19MB

no abstracts in English

Oral presentation

Direct measurements of astrophysical nuclear reaction rates on light neutron-rich nuclei at TRIAC and JAEA-RMS

Miyatake, Hiroari; Ishiyama, Hironobu*; Watanabe, Yutaka*; Hirayama, Yoshikazu*; Imai, Nobuaki*; Tanaka, Masahiko*; Yoshikawa, Nobuharu*; Jeong, S.-C.*; Fuchi, Yoshihide*; Nomura, Toru*; et al.

no journal, , 

no abstracts in English

Oral presentation

A Systematic study of astrophysical nuclear reaction rates via $$^8$$Li

Miyatake, Hiroari; Ishiyama, Hironobu*; Watanabe, Yutaka*; Hirayama, Yoshikazu*; Imai, Nobuaki*; Tanaka, Masahiko*; Yoshikawa, Nobuharu*; Jeong, S.-C.*; Fuchi, Yoshihide*; Nomura, Toru*; et al.

no journal, , 

A systematic study of astrophysical reaction rates on light neutron-rich nuclei using low-energy radioactive nuclear beams (RNB) is in progress at the tandem facility of Japan Atomic Energy Agency (JAEA). Direct measurements of reaction rates of $$^8$$Li($$alpha$$, n)$$^{11}$$B, $$^{12}$$B($$alpha$$, n)$$^{15}$$N and, $$^8$$Li(d, p), (d, t), (d, $$alpha$$), (p, $$alpha$$) have been carried out. Measured excitation functions and obtained reaction rates will be presented. Possible r-process path via $$^8$$Li at each temperature during r-process and the influence of r-process abundance will be discussed.

Oral presentation

Development of a centrifugal hydrogen pump for the cryogenic hydrogen system in J-PARC

Aso, Tomokazu; Tatsumoto, Hideki; Otsu, Kiichi; Uehara, Toshiaki; Kawakami, Yoshihiko; Sakurayama, Hisashi; Futakawa, Masatoshi; Ushijima, Isamu*; Yoshinaga, Seiichiro*

no journal, , 

A centrifugal hydrogen pump that is a foil type self acting gas bearing had developed for the cryogenic hydrogen system in J-PARC, and the performance test was carried out in the system operation. The cryogenic hydrogen system plays a role in supplying supercritical hydrogen at a temperature of around 20 K and pressure of 1.5 MPa to three moderators and removing the nuclear heating of 3.8 kW at a proton beam of 1 MW from accelerators. In order to satisfy the neutronic performance, the temperature difference through the moderator should be reduced below 3 K. Therefore, cryogenic supercritical hydrogen should be circulated with the mass flow rate more than 160 g/s. We confirmed the characteristics of the pump satisfy the required performance.

Oral presentation

Late Holocene environmental changes in west Mongolia revealed by the lacustrine sediment analyses

Hayakawa, Tsubasa*; Katsuta, Nagayoshi*; Kokubu, Yoko; Hasebe, Noriko*; Murakami, Takuma; Miyata, Yoshiki*; Hasegawa, Hitoshi*; Nagao, Seiya*; Kawakami, Shinichi*

no journal, , 

no abstracts in English

Oral presentation

Using CO$$_{2}$$ reaction to achieve mass-spectrometric discrimination for Pu isotopic analysis with inductively coupled plasma-mass spectrometry

Matsueda, Makoto; Kawakami, Tomohiko*; Koarai, Kazuma; Terashima, Motoki; Fujiwara, Kenso; Iijima, Kazuki; Furukawa, Makoto*; Takagai, Yoshitaka*

no journal, , 

Inductively coupled plasma tandem mass spectrometry with CO$$_{2}$$ gas reactions in a dynamic reaction cell almost eliminated the background noise intensity produced by isobaric interference from isotopes originating from actinides such as Am, Cm, and U at the locations (m/z) of significant Pu isotopes ($$^{239}$$Pu, $$^{240}$$Pu, $$^{241}$$Pu, $$^{242}$$Pu, and $$^{244}$$Pu).

Oral presentation

Simultaneous determination of actinide-isotopes by online solid phase extraction-inductively coupled plasma-mass spectrometry

Matsueda, Makoto; Kawakami, Tomohiko*; Teruyama, Yuko*; Terashima, Motoki; Iijima, Kazuki; Furukawa, Makoto*; Takagai, Yoshitaka*

no journal, , 

Actinides have a significant radiotoxicity risk of internal exposure to human body due to their emission of high energy alpha particle. An analysis of the actinides is important for safe management of nuclear power plants and radioactive wastes. A traditional method using alpha spectrometry needs a time-consuming and complicated multi-step pretreatment process. Inductively coupled plasma-mass spectrometry (ICP-MS) can potentially realize rapid and simple analytical method by reducing the pretreatment process through combining various automatic chemical separation systems. Such a combination including a hyphenation of chemical instrument and pretreatment system can also be achieved to improve applicability of ICP-MS for simultaneous determination of actinides. In this study, we developed an automatic analytical system of online solid-phase extraction (SPE)-ICP-MS equipped with multi-separation steps of SPE for simultaneous determination of actinides (Th, U, Pu, and Am).

Oral presentation

Simultaneous determination of actinide isotopes by inductively coupled plasma-mass spectrometry incorporating cascade separation step

Matsueda, Makoto; Kawakami, Tomohiko*; Teruyama, Yuko*; Terashima, Motoki; Iijima, Kazuki; Furukawa, Makoto*; Takagai, Yoshitaka*

no journal, , 

Determination of actinides (e.g., Th, U, Np, Pu, Am, Cm) in contaminated water and nuclear waste is important for decommissioning the Fukushima Daiichi Nuclear Power Station. However, traditional radiochemical analysis needs a time-consuming process and large effort. ICP-MS has the potential of rapid determination by simultaneous detection of actinides, while many isobaric interferences prevent the quantification. In this study, we developed an automatic analysis method using ICP-MS incorporating cascade separation steps (solid phase separation and gas phase reaction in the dynamic reaction cell) to simultaneously determine actinides.

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