検索対象:     
報告書番号:
※ 半角英数字
 年 ~ 
 年

Structure and dynamics of poly(vinyl alcohol) gels in mixtures of dimethyl sulfoxide and water

ジメチルスルホキシドと水混合系におけるポリビニルアルコールゲルの構造とダイナミクス

金谷 利治*; 高橋 伸明; 竹下 宏樹*; 大倉 正敏*; 西田 幸次*; 梶 慶輔*

Kanaya, Toshiji*; Takahashi, Nobuaki; Takeshita, Hiroki*; Okura, Masatoshi*; Nishida, Koji*; Kaji, Keisuke*

We review our structure studies on poly(vinyl alcohol) (PVA) gels formed in mixtures of dimethyl sulfoxide (DMSO) and water using various scattering methods including wide-, small- and ultra small-angle neutron scattering and light scattering. These studies revealed the hierarchic structure of PVA gels formed in DMSO/water (60/40 v/v) in a very wide spatial scale from 1 ${AA}$ to several micron: the crosslinking points are crystallites with radius of $$sim$$70 ${AA}$, the distance between the neighboring crystallites is 180-200 ${AA}$, and the bicontinuous structure due to liquid-liquid phase separation is in mm scale. We also review our dynamic studies on three kinds of PVA gels in nm scale using neutron spin echo technique to separate the concentration fluctuations observed by small-angle neutron scattering into the static and dynamics contributions.

Access

:

- Accesses

InCites™

:

パーセンタイル:62.08

分野:Polymer Science

Altmetrics

:

[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.