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水素脆化を適正に評価できる水素添加法とは; 低合金鋼のTDS解析

Optimum hydrogen charging techniques for the evaluation of hydrogen embrittlement; TDS analysis of low alloy steel

海老原 健一   ; 岩本 隆*; 三輪 則暁*; 山田 紘樹*; 岡村 司*; 漆原 亘*; 大村 朋彦*

Ebihara, Kenichi; Iwamoto, Takashi*; Miwa, Noriaki*; Yamada, Hiroki*; Okamura, Tsukasa*; Urushihara, Wataru*; Omura, Tomohiko*

応力腐食割れの1つの原因である水素脆化の機構の理解に資するために参加した日本鉄鋼協会の「水素脆化研究の基盤構築」研究会では、鉄鋼の水素脆化評価に適切な水素添加方法を探るため、異なる鋼種の試料に異なる方法で水素を添加し、昇温脱離分析で得られる水素熱脱離曲線及び添加水素量について評価した。本発表は、その研究会での成果に関する一連の最終報告の一部である。発表では、ISIJ International誌に掲載が決定している論文の内容を中心に、低合金鋼の水素熱脱離曲線の数値シミュレーションによる考察について講演する。特に、熱脱離曲線を形成する脱離水素を捕獲する鋼材中の欠陥の種類に対する考察、及び実験によるその同定方法について、より詳細に解説する。

In order to explore the properly hydrogen-charging method for the estimation of hydrogen embrittlement of steels, in the workshop of Fundamental construction for hydrogen embrittlement supported by the Iron and Steel Institute of Japan of which I took part for understanding the mechanism of hydrogen embrittlement which is one cause of stress corrosion cracking, the thermal desorption spectrum of hydrogen and the amount of charged hydrogen were estimated among various kinds of steels charged with hydrogen by various methods. The presentation is a part of a series of the final report about the results obtained in the workshop. In the presentation, I talk about the numerical estimation of the desorption spectrum of low alloy steel mainly on the basis of the paper which is going to be published in the ISIJ International. Particularly, the kind of defects in the steel that capture hydrogen forming the spectrum and the experimental method for identifying the defects are explained in details.

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