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$$gamma$$線照射下での中性塩化物水溶液中における炭素鋼の腐食挙動; 塩化物イオン濃度依存性

Corrosion behavior of carbon steel in neutral chloride aqueous solution under $$gamma$$-ray irradiation; Effect of chloride ion concentration

本岡 隆文; 米川 夏津夫; 上野 文義  

Motooka, Takafumi; Yonekawa, Kazuo; Ueno, Fumiyoshi

中性塩化物水溶液中での鉄鋼の腐食では、腐食速度が極大となる塩化物イオン濃度があることが知られているが、この事象に対して、放射線の影響を低線量率条件で検討した事例は少ない。そこで、低線量率の$$gamma$$線を用いた腐食試験により検討した。塩化物イオン濃度の異なる中性塩化物水溶液を用いた炭素鋼の腐食試験の結果、腐食速度が極大となる塩化物イオン濃度が存在した。腐食速度極大の発現は、塩化物イオン濃度増大に伴い、水溶液の導電率増大に起因する腐食速度が増大するためと、照射時の腐食加速因子である溶存酸素濃度及び過酸化水素生成量が低下するためと考えられる。

It is known that the corrosion of steel in neutral chloride solution has a chloride concentration at which the corrosion rate reaches a maximum. However, it is unknown that the effect of radiation at a low dose rate on this phenomenon. Therefore, we examined the effect of radiation at a low dose rate on corrosion of steel in neutral chloride solution by corrosion tests using various concentration of chloride neutral solutions. As the results, the corrosion rate becomes a maximum at a certain chloride concentration. It is consider that the increase in conductivity of solutions along with the chloride concentration increases and the decrease in concentrations of hydrogen peroxide and dissolved oxygen are key factors for the corrosion of steel in neutral chloride solution under a low dose rate condition.

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