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Mass-resolved momentum imaging of three dichloroethylene isomers by femtosecond laser-induced coulomb explosion

フェムト秒レーザーを用いたクーロン爆発によるジクロロエチレンのモーメンタムイメージング

和田 資子*; 赤木 浩*; 熊田 高之   ; 板倉 隆二*; 若林 知成*

Wada, Yoriko*; Akagi, Hiroshi*; Kumada, Takayuki; Itakura, Ryuji*; Wakabayashi, Tomonari*

フェムト秒レーザーを用いたジクロロエチレン異性体のクーロン爆発実験をおこなったところ、異性体間で$$^{35}$$Cl$$^+$$とC$$^{2+}$$の異なる質量分解モーメンタムイメージングが得られた。

Coulomb explosion experiments using 60 fs laser pulses were conducted for structural characterization of three dichloroethylene isomers. Under laser intensity at 1.8 $$times$$ 10$$^{14}$$ W/cm$$^2$$, mass-resolved momentum imaging (MRMI) for selected fragment ions of $$^{35}$$Cl$$^+$$ and C$$^{2+}$$ revealed different patterns for the three isomers. The C$${2+}$$ ion fragmented from multiply charged trans-1,2-DCE was forced to leave perpendicularly to the direction of the laser polarization, due to recoil forces from adjacent cations. In contrast, the fast ions of C$${2+}$$ from cis-1,2-DCE exhibited an isotropic distribution, whereas the fast ions of C$${2+}$$ from 1,1-DCE recoiled along the laser polarization together with the slow C$${2+}$$ ions, and thereby distinction of the three isomers was demonstrated. Coulomb explosion occurs predominantly at specific orientation, which is useful for potential applications of MRMI analysis to molecular structure assays.

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