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論文

Quantum dynamics of hydrogen in the iron-based superconductor LaFeAsO$$_{0.9}$$D$$_{0.1}$$ measured with inelastic neutron spectroscopy

山浦 淳一*; 平賀 晴弘*; 飯村 壮史*; 村場 善行*; Bang, J.*; 池内 和彦*; 中村 充孝; 稲村 泰弘; 本田 孝志*; 平石 雅俊*; et al.

Physical Review B, 99(22), p.220505_1 - 220505_6, 2019/06

鉄系超伝導体LaFeAsO$$_{0.9}$$D$$_{0.1}$$の非弾性中性子散乱実験により、超伝導転移温度26K以下において、5-15meVのエネルギー領域に新しい励起が生じることを見出した。なお、この励起は母物質であるLaFeAsO$$_{0.9}$$F$$_{0.1}$$では現れない。14.5meVと11.1meVに現れる強い励起は水素の量子ラットリングまたはバンド運動に起因し、格子間サイトが2個以上のポテンシャル極小点を有する場合にのみ出現するものと結論付けた。

論文

Gapless magnetic excitation in a heavily electron-doped antiferromagnetic phase of LaFeAsO$$_{0.5}$$D$$_{0.5}$$

玉造 博夢*; 平賀 晴弘*; 池内 和彦*; 飯村 壮史*; 村場 善行*; 中村 充孝; 佐賀山 基*; 山浦 淳一*; 村上 洋一*; 倉本 義夫*; et al.

Physical Review B, 98(17), p.174415_1 - 174415_6, 2018/11

 被引用回数:1 パーセンタイル:100(Materials Science, Multidisciplinary)

中性子非弾性散乱実験によりLaFeAsO$$_{0.5}$$D$$_{0.5}$$の第二反強磁性母相におけるギャップレス磁気励起の研究を行った。実験の結果、他の鉄系超伝導の母物質とは異なり、LaFeAsO$$_{0.5}$$D$$_{0.5}$$では磁気励起ギャップが4Kもの非常に低い温度においてもなお観測されないことを見出した。このギャップレス励起はab面内の擬等方性に起因するものと理解され、バンド計算による先行研究の結果と一致する。さらに、この相での磁気励起強度はノンドープのLaFeAsOに比べてはるかに強いこと、及び、常磁性相においてもなおLaFeAsO$$_{0.5}$$D$$_{0.5}$$の磁気励起が存在することを見出した本研究の実験結果は、本系において電子ドープが局在性を増強すると主張する最近の研究結果を強く支持する。

論文

Observation of momentum-resolved charge fluctuations proximate to the charge-order phase using resonant inelastic X-ray scattering

吉田 雅洋*; 石井 賢司; 中 惇*; 石原 純夫*; Jarrige, I.*; 池内 和彦*; 村上 洋一*; 工藤 一貴*; 小池 洋二*; 永田 知子*; et al.

Scientific Reports (Internet), 6, p.23611_1 - 23611_8, 2016/03

 パーセンタイル:100(Multidisciplinary Sciences)

In strongly correlated electron systems, enhanced fluctuations in the proximity of the ordered states of electronic degrees of freedom often induce anomalous electronic properties such as unconventional superconductivity. While spin fluctuations in the energy-momentum space have been studied widely using inelastic neutron scattering, other degrees of freedom, i.e., charge and orbital, have hardly been explored thus far. Here, we use resonant inelastic X-ray scattering to observe charge fluctuations proximate to the charge-order phase in transition metal oxides. In the two-leg ladder of Sr$$_{14-x}$$Ca$$_x$$Cu$$_{24}$$O$$_{41}$$, charge fluctuations are enhanced at the propagation vector of the charge order ($$mathbf{q}_mathrm{CO}$$) when the order is melted by raising the temperature or by doping holes. In contrast, charge fluctuations are observed not only at $$mathbf{q}_mathrm{CO}$$ but also at other momenta in a geometrically frustrated triangular bilayer lattice of LuFe$$_2$$O$$_4$$. The observed charge fluctuations have a high energy ($$sim$$ 1 eV), suggesting that the Coulomb repulsion between electrons plays an important role in the formation of the charge order.

論文

Magnetic and electronic properties of (LaMnO$$_3$$)$$_5$$(SrMnO$$_3$$)$$_5$$ superlattice revealed by resonant soft X-ray scattering

久保田 正人; 山田 浩之*; 中尾 裕則*; 岡本 淳*; 山崎 裕一*; 澤 彰仁*; 村上 洋一*

Japanese Journal of Applied Physics, 53(5S1), p.05FH07_1 - 05FH07_5, 2014/05

 被引用回数:2 パーセンタイル:85.43(Physics, Applied)

We have investigated the magnetic and electronic properties of (LaMnO$$_3$$)$$_5$$(SrMnO$$_3$$)$$_5$$ superlattice fabricated on a lattice-matched La$$_{0.3}$$Sr$$_{0.7}$$Al$$_{0.65}$$Ta$$_{0.35}$$O$$_{3}$$ substrate by resonant soft X-ray scattering. The temperature- and $mbox{boldmath $Q$}$-dependences of the energy spectra were measured around the Mn $$L_{2,3}$$-absorption edges. We successfully observed not only a signal that reflects the valence modulation of Mn ion, but also a magnetic signal reflecting ferromagnetism. Compared with the calculated models, we concluded that the ferromagnetism mainly originates from the magnetic moments at the Mn sites sandwiched by LaO layers.

論文

Antiferromagnetic order of the Co$$^{2+}$$ high-spin state with a large orbital angular momentum in La$$_{1.5}$$Ca$$_{0.5}$$CoO$$_{4}$$

岡本 淳*; 中尾 裕則*; 山崎 裕一*; 和達 大樹*; 田中 新*; 久保田 正人; 堀金 和正*; 村上 洋一*; 山田 和芳*

Journal of the Physical Society of Japan, 83(4), p.044705_1 - 044705_6, 2014/04

 被引用回数:7 パーセンタイル:38.92(Physics, Multidisciplinary)

The antiferromagnetic insulator La$$_{1.5}$$Ca$$_{0.5}$$CoO$$_{4}$$ has been investigated by Co L$$_{2,3}$$-edge and O K-edge X-rayabsorption spectroscopy (XAS) measurements and Co L$$_{2,3}$$-edge resonant soft X-ray magnetic scattering (RXMS)measurement to determine the Co electronic structures associated with magnetic ordering. Co L$$_{2,3}$$-edge linear-dichroicXAS shows that Co$$^{2+}$$ takes a high-spin (HS) state and Co$$^{3+}$$ takes a low-spin (LS) state. Using Co L$$_{2,3}$$-edge RXMS, wedirectly determined that an antiferromagnetic order is formed with a HS state of Co$$^{2+}$$ ions. Moreover, the spin andorbital angular momenta of the Co$$^{2+}$$ HS state are quantitatively estimated to be 1.1$$pm$$0.1 and 1.0$$pm$$0.1, respectively,and to align parallel in the ab plane by utilizing the cluster model calculation. The large orbital angular momentum of the Co$$^{2+}$$ HS state originates from the small $$D_{4h}$$-symmetry crystal field splitting of $$t_{2g}$$ levels, which is comparable with the spin-orbit coupling constant of the Co 3$$d$$ orbital.

論文

Bipartite magnetic parent phases in the iron oxypnictide superconductor

平石 雅俊*; 飯村 壮史*; 小嶋 健児*; 山浦 淳一*; 平賀 晴弘*; 池田 一貴*; Miao, P.*; 石川 喜久*; 鳥居 周輝*; 宮崎 正範*; et al.

Nature Physics, 10(4), p.300 - 303, 2014/04

 被引用回数:62 パーセンタイル:3.79(Physics, Multidisciplinary)

High-temperature (high-$$T_{rm c}$$) superconductivity appears as a consequence of the carrier-doping of an undoped parent compound exhibiting antiferromagnetic order; thereby, ground-state properties of the parent compound are closely relevant to the superconducting state. On the basis of the concept, a spin-fluctuation has been addressed as an origin of pairing of the superconducting electrons in cuprates. Whereas, there is growing interest in the pairing mechanism such as an unconventional spin-fluctuation or an advanced orbital-fluctuation due to the characteristic multi-orbital system in iron-pnictides. Here, we report the discovery of an antiferromagnetic order as well as a unique structural transition in electron-overdoped LaFeAsO$$_{1-x}$$H$$_x$$ ($$x sim 0.5$$), whereby another parent phase was uncovered, albeit heavily doped. The unprecedented two-dome superconducting phases observed in this material can be interpreted as a consequence of the carrier-doping starting from the original at $$x sim 0$$ and advanced at $$x sim 0.5$$ parent phases toward the intermediate region. The bipartite parent phases with distinct physical properties in the second magnetic phase provide us with an interesting example to illustrate the intimate interplay among the magnetic interaction, structural change and orbital degree of freedom in iron-pnictides.

論文

Spin state of Co$$^{3+} $$ in LaCo$$_{1-x}$$ Rh$$_{x}$$O$$_{3}$$ investigated by structural phenomena

浅井 晋一郎*; 岡崎 竜二*; 寺崎 一郎*; 安井 幸夫*; 小林 航*; 中尾 朗子*; 小林 賢介*; 熊井 玲児*; 中尾 裕則*; 村上 洋一*; et al.

Journal of the Physical Society of Japan, 82(11), p.114606_1 - 114606_6, 2013/11

 被引用回数:6 パーセンタイル:46.59(Physics, Multidisciplinary)

LaCo$$_{1-x}$$ Rh$$_{x}$$O$$_{3}$$について中性子および放射光X線回折実験を行い、Co$$^{3+}$$イオンのスピン状態と結晶構造との関連を調べた。10KにおけるLaCo$$_{0.8}$$Rh$$_{0.2}$$O$$_{3}$$では、Co(Rh)O$$_{6}$$八面体のCo(Rh)-O間距離は理論値と一致し、格子体積は温度低下によって減少した。また、この格子体積の減少に伴って高スピン状態の比率は減少した。これらの結果から、Co$$^{3+}$$イオンのスピン状態は高スピン状態と低スピン状態が混在したものであり、高スピン状態は、Rh$$^{3+}$$イオンの置換によって生じたピン止め効果に加え熱励起によって発現することがわかった。

論文

Instrumental upgrades of the RIXS spectrometer at BL11XU at SPring-8

石井 賢司; Jarrige, I.*; 吉田 雅洋*; 池内 和彦*; 稲見 俊哉; 村上 洋一*; 水木 純一郎

Journal of Electron Spectroscopy and Related Phenomena, 188, p.127 - 132, 2013/06

 被引用回数:8 パーセンタイル:41.65(Spectroscopy)

Two recent instrumental upgrades of the inelastic X-ray scattering spectrometer installed at BL11XU at SPring-8 are reported. The first one is a multianalyzer system, where we can simultaneously use three crystal analyzers aligned perpendicularly to the scattering plane. In a test measurement of polycrystalline $$alpha$$-PtO$$_2$$, the inelastic spectra obtained with each respective analyzer showed a completely identical lineshape, and a slight difference ($$le$$ 10%) in intensity. The system enhances the experimental efficiency, and allows for simultaneous scan at three momenta for a single-crystal sample. The second development is a polarization analyzer for the scattered photons. A pyrolytic graphite (PG) crystal is placed in front of the detector and serves as a polarization-analyzer crystal, using the (006) reflection for the Cu $$K$$-edge. We succeeded to observe clear polarization dependence in the $$d$$-$$d$$ excitations of KCuF$$_3$$.

論文

Emergent phenomena in perovskite-type manganites

田口 康二郎*; 酒井 英明*; 奥山 大輔*; 石渡 晋太郎*; 藤岡 淳*; 福田 竜生; 橋爪 大輔*; 賀川 史敬*; 高橋 陽太郎*; 島野 亮*; et al.

Physica B; Condensed Matter, 407(11), p.1685 - 1688, 2012/06

 被引用回数:3 パーセンタイル:79.94(Physics, Condensed Matter)

Perovskite-type manganites exhibit various interesting phenomena arising from complex interplay among spin, charge, orbital, and lattice degrees of freedom. As the respective examples, perovskite-type YMnO$$_3$$ and Sr$$_{1-x}$$Ba$$_x$$MnO$$_3$$ are discussed. In the YMnO$$_3$$, the ferroelectric lattice distortion associated with the $$E$$-type spin order is observed for the first time. Displacement-type ferroelectricity with off-center magnetic ions is discovered for Sr$$_{0.5}$$Ba$$_{0.5}$$MnO$$_3$$, which shows both large polarization value and strong coupling between ferroelectricity and magnetism.

論文

Magnetic phase diagrams of YVO$$_{3}$$ and TbVO$$_{3}$$ under high pressure

備前 大輔*; 中尾 裕則*; 岩佐 和晃*; 村上 洋一*; 長壁 豊隆; 藤岡 淳*; 安江 俊夫*; 宮坂 茂樹*; 十倉 好紀*

Journal of the Physical Society of Japan, 81(2), p.024715_1 - 024715_6, 2012/02

 被引用回数:4 パーセンタイル:59.95(Physics, Multidisciplinary)

低温高圧力下の中性子回折実験により、RVO$$_{3}$$(R=Y, Tb)の磁気相図を明らかにした。TbVO$$_{3}$$では、その基底状態が加圧によって${it C}$-タイプのスピン秩序(${it C}$-SO)から${it G}$-タイプのスピン秩序(${it G}$-SO)へと変化することが明らかとなった。これまでに基底状態の軌道秩序は、加圧により${it G}$-タイプの軌道秩序(${it G}$-OO)から${it C}$-タイプの軌道秩序(${it C}$-OO)へと変化することが明らかになっていたが、これと完全に対応している。一方、YVO$$_{3}$$の基底状態は、常圧から今回の最高圧力値6.2GPaまで、${it G}$-SOと${it C}$-OOが同時に存在し、非秩序相-[${it G}$-SO, ${it C}$-OO]相間の相転移が、ペロブスカイト型の遷移元素酸化物RMO$$_{3}$$において初めて観測された。両物質において[${it G}$-SO, ${it C}$-OO]相が加圧とともに安定化していくが、これは共有結合効果と超交換相互作用が重要な役割を果たしていると考えられる。

論文

Polarization-analyzed resonant inelastic X-ray scattering of the orbital excitations in KCuF$$_3$$

石井 賢司; 石原 純夫*; 村上 洋一*; 池内 和彦*; 葛下 かおり*; 稲見 俊哉; 大和田 謙二; 吉田 雅洋; Jarrige, I.; 多々見 央*; et al.

Physical Review B, 83(24), p.241101_1 - 241101_4, 2011/06

 被引用回数:18 パーセンタイル:30.21(Materials Science, Multidisciplinary)

We report a Cu $$K$$-edge resonant inelastic X-ray scattering (RIXS) study of orbital excitations in KCuF$$_3$$. By performing the polarization analysis of the scattered photons, we disclose that the excitation between the $$e_g$$ orbitals and the excitations from $$t_{2g}$$ to $$e_g$$ exhibit distinct polarization dependence. The polarization dependence of the respective excitations is interpreted based on a phenomenological consideration of the symmetry of the RIXS process that yields a necessary condition for observing the excitations. In addition, we show that the orbital excitations are dispersionless within our experimental resolution.

論文

Temperature dependence of the electronic structure of Sr$$_{14}$$Cu$$_{24}$$O$$_{41}$$ studied by resonant inelastic X-ray scattering

吉田 雅洋; 石井 賢司; 池内 和彦*; Jarrige, I.; 村上 洋一*; 水木 純一郎; 筒井 健二; 遠山 貴己*; 前川 禎通*; 工藤 一貴*; et al.

Physica C, 470(Suppl.1), p.S145 - S146, 2010/12

 被引用回数:4 パーセンタイル:73.14(Physics, Applied)

Sr$$_{14-x}$$Ca$$_x$$Cu$$_{24}$$O$$_{41}$$ (SCCO), which is composed of two-leg ladders and edge-sharing chains, is the first superconducting cuprate without CuO$$_2$$ planes. By substituting Ca for Sr, holes are transferred from the chains to the ladders. It was recently shown that charge ordering (CO) along the leg direction in the ladder occurs at $$x=0$$ and the periodicity is five times the unit length along the c axis. In order to investigate the electronic excitations associated with the CO, we carried out resonant inelastic X-ray scattering (RIXS) experiments for SCCO ($$x=0,6$$). Cu-$$K$$ RIXS can directly probe the momentum-dependent electronic excitations related to the Cu site, which are resonantly enhanced by tuning the incident photon energy to the Cu $$K$$-edge. We measured the q dependence of the intraband excitations, which is associated with the dynamics of doped holes in the Zhang-Rice singlet band. The intensity is enhanced at the momentum $${bf q}=(q_{rm rung},q_{rm leg})=(0,2pi/5)$$ corresponding to the periodicity of the CO in $$x=0$$, while the temperature dependence of the enhancement is different for $$x=0$$ and $$x=6$$. We discuss the relationship between our experimental results and the occurrence of the CO.

論文

X-ray photon correlation spectroscopy study in valence fluctuation compound Eu$$_{3}$$S$$_{4}$$

中尾 裕則*; 大和田 謙二; 下村 晋*; 落合 明*; 並河 一道*; 水木 純一郎; 三村 秀和*; 山内 和人*; 村上 洋一*

AIP Conference Proceedings 1234, p.935 - 938, 2010/06

 被引用回数:2 パーセンタイル:24.85

X-ray photon correlation spectroscopy (XPCS) is a powerful tool to perform direct measurements of the dynamics of fluctuations in condensed matter systems at atomic resolution. Here we have investigated spatial and time correlations of domains in the valence fluctuated phase in a typical valence fluctuation compound Eu$$_{3}$$S$$_{4}$$ near the charge ordering temperature ($$T_{CO}$$). The spatial correlation was observed at the fundamental reflection (4 4 4) using coherent diffraction techniques, which indicated that the domain size is longer than 200 nm near $$T_{CO}$$. The time correlation of the domain was measured by the XPCS technique, and we found that the slow fluctuation of the order of 10 second exists only near $$T_{CO}$$.

論文

Resonant magnetic X-ray diffraction study on the successive metamagnetic transitions of TbB$$_4$$ up to 30T

稲見 俊哉; 大和田 謙二; 松田 康弘*; Ouyang, Z. W.*; 野尻 浩之*; 松村 武*; 奥山 大輔*; 村上 洋一*

Journal of Physics; Conference Series, 211, p.012010_1 - 012010_6, 2010/02

 被引用回数:3 パーセンタイル:17.09

Quite recently, successive metamagnetic transitions between 16T and 28T were reported on the rare-earth tetraboride TbB$$_4$$. Considerable attentions have been attracted on this peculiar bahavior. Recently, X-ray diffraction experiments under pulsed high magnetic field have been developed at several places. In order to examine the magnetic structures at high magnetic fields, we applied this technique to TbB$$_4$$. Small magnetic X-ray scattering cross section was overcome by utilizing resonance enhancement. The obtained field, polarization, and scattering angle dependence of magnetic reflections indicates that magnetic moments perpendicular to the magnetic field exist in the high-field plateau phases. This result is inconsistent with normalfractional magnetization plateau phases that posses only magnetic moments parallel or antiparallel to the field. In order to resolve this discrepancy, we propose magnetic structures that consist of Ising spins and XY spins.

論文

Resonant magnetic X-ray diffraction study on successive metamagnetic transitions in TbB$$_4$$

稲見 俊哉; 大和田 謙二; 松田 康弘*; Ouyang, Z. W.*; 野尻 浩之*; 松村 武*; 奥山 大輔*; 村上 洋一*

Journal of the Physical Society of Japan, 78(3), p.033707_1 - 033707_4, 2009/03

 被引用回数:15 パーセンタイル:30.11(Physics, Multidisciplinary)

Resonant magnetic X-ray diffraction experiments on the Shastry-Sutherland lattice TbB$$_4$$ were carried out under pulsed magnetic fields up to 30 T at 8 K. TbB$$_4$$ exhibits a multi-step magnetization process above 16 T below about 20 K when magnetic fields are applied along the $$c$$-axis. We examined the intensity of the 010 magnetic reflection as a function of magnetic field and found that the magnetization plateau phases are accompanied by large XY components of magnetic moments. We propose novel magnetic structures which consist of XY spins and Ising spins for the plateau phases. We also propose that energy level-crossing and its inherent degeneracy give rise to the successive met magnetic transitions in TbB$$_4$$.

論文

Momentum-resolved charge excitations in high-$$T$$$$_{rm c}$$ cuprates studied by resonant inelastic X-ray scattering

石井 賢司; Hoesch, M.*; 稲見 俊哉; 葛下 かおり*; 大和田 謙二; 坪田 雅己; 村上 洋一; 水木 純一郎; 遠藤 康夫; 筒井 健二*; et al.

Journal of Physics and Chemistry of Solids, 69(12), p.3118 - 3124, 2008/12

 被引用回数:3 パーセンタイル:78.44(Chemistry, Multidisciplinary)

Resonant inelastic X-ray scattering (RIXS) in the hard X-ray regime is a new spectroscopic technique to measure electronic excitations utilizing brilliant synchrotron radiation. It has the great advantage that the momentum dependence can be measured unlike conventional optical methods. As inelastic neutron scattering gives spin or lattice dynamics, inelastic X-ray scattering can be a tool to measure charge dynamics in solids through the coupling of photon to the charge of the electron. Here, I would like to present our RIXS studies on high-$$T_c$$ cuprates and related materials which were performed in close collaboration with theorists. In doped Mott insulators, an interband excitation across the Mott gap and an intraband excitation below the gap are observed in the low energy region of RIXS spectra. Momentum and carrier-doping dependence of the excitations will be discussed.

論文

Structural phase transition in the spin gap system YbAl$$_3$$C$$_3$$

松村 武*; 稲見 俊哉; 小坂 昌史*; 加藤 慶顕*; 犬飼 敬希*; 落合 明*; 中尾 裕則*; 村上 洋一*; 片野 進*; 鈴木 博之*

Journal of the Physical Society of Japan, 77(10), p.103601_1 - 103601_4, 2008/10

 被引用回数:7 パーセンタイル:48.33(Physics, Multidisciplinary)

The unresolved phase transition at 80K in YbAl$$_3$$C$$_3$$ has been studied by X-ray diffraction. It has been confirmed that the transition is a structural one with atomic displacement. Superlattice reflections that appear below 80K show that the crystal structure changes from hexagonal to orthorhombic. From the reflection conditions, we conclude that the space group in the low temperature phase is Pbca, where all the atoms occupy the general 8c site. By fitting the observed intensities, we present two possible models of atomic displacement. The displacement results in the deformation of the triangular lattice of Yb spins, which is considered to be responsible for the formation of a spin-singlet ground state at low temperatures.

論文

High-magnetic-field X-ray absorption spectroscopy of field-induced valence transition in EuNi$$_2$$(Si$$_{1-x}$$Ge$$_x$$)$$_2$$

松田 康弘*; 稲見 俊哉; 大和田 謙二; 村田 悠人*; 野尻 浩之*; 村上 洋一*; 光田 暁弘*; 和田 裕文*; 宮崎 寛*; 原田 勲*

Journal of the Physical Society of Japan, 77(5), p.054713_1 - 054713_7, 2008/05

 被引用回数:23 パーセンタイル:22.98(Physics, Multidisciplinary)

EuNi$$_2$$(Si$$_{1-x}$$Ge$$_x$$)$$_2$$の磁場誘起価数転移を低温でX線吸収実験から研究した。Euの価数の磁場依存性を初めて直接的に観測したものである。40T以上の磁場において価数の低下を観測した。Euの価数はゼロ磁場の2.75から40Tで2.33になった。この結果を理論モデルで解析した。量子力学的混成に重要な、混成パラメータVとエネルギー差$$Delta$$$$E$$を求めた。

論文

NaV$$_{2}$$O$$_{5}$$の逐次電荷不均化による悪魔の花; 悪魔の花を咲かせるIsingスピンの詳細と競合する相互作用の理解

大和田 謙二; 藤井 保彦; 村岡 次郎*; 中尾 裕則*; 村上 洋一*; 野田 幸男*; 大隅 寛幸*; 池田 直*; 菖蒲 敬久; 礒部 正彦*; et al.

放射光, 21(2), p.87 - 96, 2008/03

常圧下で電荷不均化を示すNaV$$_{2}$$O$$_{5}$$の温度圧力相図上で「悪魔の花」が観測された。われわれは、X線構造解析的手法と電荷配列に敏感な共鳴X線回折法の相補利用により、低圧側と高圧側に現われる二つの基底状態の構造の関係を電荷配列も含めて明らかにした。その結果、二つの等価な電荷配列パターンがNaV$$_{2}$$O$$_{5}$$におけるIsingスピンに対応し、それに付随する原子変位はIsingスピンに線型に結合したものであることがわかった。このことからNaV$$_{2}$$O$$_{5}$$において、逐次電荷不均化による悪魔の花が実現されていると結論した。またわれわれは、競合する相互作用の起源がIsing spin-phonon結合によるものであると推測した。

論文

Structural relations between two ground states of NaV$$_{2}$$O$$_{5}$$ under high pressure; A Synchrotron X-ray diffraction study

大和田 謙二; 藤井 保彦; 村岡 次郎*; 中尾 裕則*; 村上 洋一; 野田 幸男*; 大隅 寛幸*; 池田 直*; 菖蒲 敬久; 礒部 正彦*; et al.

Physical Review B, 76(9), p.094113_1 - 094113_10, 2007/09

 被引用回数:7 パーセンタイル:60.08(Materials Science, Multidisciplinary)

ANNNI(Axial Next Nearest Neighbor Ising)物質,NaV$$_{2}$$O$$_{5}$$の基底状態C$$_{1/4}$$,C$$_{0}$$相の構造的関係をX線回折で調べた。C$$_{0}$$相の構造はC$$_{1/4}$$相の4層(AAA'A')の一つ(AもしくはA')で説明できることがわかった。ただし、原子変位は27%にまで押さえられる。一方、電荷秩序は完全に起きている。このことは電荷格子結合定数が圧力によって変わっていることを示しており、悪魔の相図を生み出す競合する相互作用比の変化の起源を考えるうえで興味深い。

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