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田川 雅人*; 岸田 和博*; 横田 久美子*; 松本 康司*; 吉越 章隆; 寺岡 有殿; Zhang, J.*; Minton, T. K.*
Protection of Materials and Structures from the Space Environment; Astrophysics and Space Science Proceedings, Vol.32, p.547 - 555, 2012/08
Volatile products were measured from two types of diamond-like carbon films under the hyperthermal atomic oxygen (AO) beam bombardment. It was clearly observed that CO and CO were formed at the conventional hydrogenated DLC surface by hyperthermal AO beam exposure. Desorption rates of CO and CO are constant with AO fluence which reflects the constant erosion rate of the hydrogenated DLC. In contrast, Si-doped DLC shows decrease in amount of CO and CO with increasing AO fluence. Oxidation of Si atoms at the DLC surface was detected by X-ray photoelectron spectroscopy. This is the evidence that SiO film formed at the DLC surface could prevent AO reaction with C atoms in DLC which leads to loss of DLC. Since a self-healing capability can be expected on Si-doped DLC, metal doping is a promising technology for space application of DLC.
田川 雅人*; 横田 久美子*; 岸田 和博*; 古山 雄一*; 戸出 真由美; 吉越 章隆; 寺岡 有殿; Minton, T. K.*
no journal, ,
本研究ではDLC膜中にSiをドープすることにより、DLC薄膜が原子状酸素曝露を受けた際にSi酸化保護皮膜を形成する可能性について、放射光光電子分光法、及び、ラザフォード後方散乱法による表面分析と反応生成物直接観察を行うことで検証を行った。原子状酸素照射前後における放射光光電子スペクトルから、室温での照射にもかかわらず、酸化膜の形成が確認され、反応生成物の脱離も抑えられることがわかった。