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Suzuki, Hakuto*; Zhao, G.*; Okamoto, Jun*; Sakamoto, Shoya*; Chen, Z.-Y.*; Nonaka, Yosuke*; Shibata, Goro; Zhao, K.*; Chen, B.*; Wu, W.-B.*; et al.
Journal of the Physical Society of Japan, 91(6), p.064710_1 - 064710_5, 2022/06
Times Cited Count:0 Percentile:0.00(Physics, Multidisciplinary)Lam, T.-N.*; Chou, Y.-S.*; Chang, Y.-J.*; Sui, T.-R.*; Yeh, A.-C.*; Harjo, S.; Lee, S. Y.*; Jain, J.*; Lai, B.-H.*; Huang, E.-W.*
Crystals (Internet), 9(8), p.420_1 - 420_8, 2019/08
Times Cited Count:9 Percentile:62.18(Crystallography)Chang, Y. L.*; Sasaki, Takehiko*; Ribas-Ario, J.*; Machida, Masahiko; Shiga, Motoyuki
Journal of Physical Chemistry B, 123(7), p.1662 - 1671, 2019/02
Times Cited Count:4 Percentile:9.19(Chemistry, Physical)Dehydration of biomass-derived polyalcohols has recently drawn attention in green chemistry as a prototype of selective reactions controllable in hot water or hot carbonated water, without any use of organic solvents or metal catalysts. Here, we report a free-energy analysis based on first-principles metadynamics and blue-moon ensemble simulations to understand the mechanism of competing intramolecular dehydration reactions of 1,2,5-pentanetriol in hot acidic water. The simulations consistently predict that the most dominant mechanism is the proton-assisted S2 process, where the protonation of the hydroxyl group by water and the C-O bond breaking and formation occur in a single step. The detailed mechanism found from the simulations shows how the reaction paths are selective in hot water and why the reaction rates are accelerated in acidic environments, thus giving a clear explanation of experimental findings for a broad class of competing dehydration processes of polyalcohols.
Tang, C.*; Song, Q.*; Chang, C.-Z.*; Xu, Y.*; Onuma, Yuichi; Matsuo, Mamoru*; Liu, Y.*; Yuan, W.*; Yao, Y.*; Moodera, J. S.*; et al.
Science Advances (Internet), 4(6), p.eaas8660_1 - eaas8660_6, 2018/06
Times Cited Count:34 Percentile:83.82(Multidisciplinary Sciences)Chang, Y.-Y.*; Tanida, Kiyoshi; Belle Collaboration*; 170 of others*
Physical Review Letters, 115(22), p.221803_1 - 221803_8, 2015/11
Times Cited Count:11 Percentile:58.77(Physics, Multidisciplinary)Jeong, S. H.*; Chang, D. H.*; Kim, T. S.*; In, S. R.*; Lee, K. W.*; Jin, J. T.*; Chang, D. S.*; Oh, B. H.*; Bae, Y. S.*; Kim, J. S.*; et al.
Review of Scientific Instruments, 83(2), p.02B102_1 - 02B102_3, 2012/02
Times Cited Count:26 Percentile:69.99(Instruments & Instrumentation)The first NB (neutral beam) injection system of the KSTAR tokamak was partially completed in 2010 with only 1/3 of its full design capability, and NB heating experiments were carried out during the 2010 KSTAR operation campaign. The ion source is composed of a JAEA bucket plasma generator and a KAERI large multi-aperture accelerator assembly. Before the beam injection experiments, characteristics of the ion source were investigated. A minimum beam divergence angle was 0.8 . The ion species ratio was D
:D
:D
=75:20:5. The arc efficiency is more than 1.0 A/kW. In the 2010 KSTAR campaign, the deuterium NB power of 0.7-1.5 MW was successfully injected into the KSTAR plasma with the beam energy of 70-90 keV. L-H transitions were observed within a wide range of beam powers relative to a threshold value. In every deuterium NB injection, a burst of D-D neutrons was recorded, and increases in the ion temperature and the plasma stored energy were found.
Watanabe, Kazuhiro; Dairaku, Masayuki; Tobari, Hiroyuki; Kashiwagi, Mieko; Inoue, Takashi; Hanada, Masaya; Jeong, S. H.*; Chang, D. H.*; Kim, T. S.*; Kim, B. R.*; et al.
Review of Scientific Instruments, 82(6), p.063507_1 - 063507_6, 2011/06
Times Cited Count:16 Percentile:57.46(Instruments & Instrumentation)A long pulse plasma generator for neutral beam injectors has been developed. The plasma generator was designed to produce 65 A at 120 keV from a beam extraction area of 12 cm 46 cm. A type of the plasma generator is a multi-cusp plasma generator with SmCo permanent magnets. A long pulse test of the plasma generator was performed at the KSTAR NBI test stand in Korea under the Japan - Korea Fusion collaboration. It was successfully demonstrated of the long pulse operation of the plasma generator for 200 s at an arc discharge power of 70 kW which can produce 65 A beams. Plasma spatial uniformity at the beam extraction area was confirmed to be smaller than
8% of the deviation from an averaged ion saturation current density. A high arc efficiency of 0.9-1.1 A/kW was obtained at the beam extraction with 73 keV, 41 A for 5 sec. From these experimental studies, a performance of this plasma generator for long pulse ion sources was confirmed.
Chang, L.-J.; Schweika, W.*; Kao, Y.-J.*; Chou, Y. Z.*; Peron, J.*; Br
ckel, T.*; Yang, H. C.*; Chen, Y. Y.*; Gardner, J. S.*
Physical Review B, 83(14), p.144413_1 - 144413_7, 2011/04
Times Cited Count:9 Percentile:37.70(Materials Science, Multidisciplinary)Park, J.-H.*; Wakahara, Akihiro*; Okada, Hiroshi*; Furukawa, Yuzo*; Kim, Y.-T.*; Chang, H.-J.*; Song, J.*; Shin, S.*; Lee, J.-H.*; Sato, Shinichiro; et al.
Japanese Journal of Applied Physics, 49(3), p.032401_1 - 032401_5, 2010/03
Times Cited Count:1 Percentile:5.30(Physics, Applied)Kishida, Norio*; Murata, Toru*; Asami, Tetsuo*; Kosako, Kazuaki*; Maki, Koichi*; Harada, Hideo*; Lee, Y.*; Chang, J.*; Chiba, Satoshi; Fukahori, Tokio
AIP Conference Proceedings 769, p.199 - 202, 2005/05
Nuclear data for photonuclear reactions are required in the field of shielding design of high-energy electron accelerators and high-energy -ray therapy. The JENDL Photonuclear Data File was prepared by a working group on nuclear data evaluations for photonuclear reactions in Japanese Nuclear Data Committee. From a survey of many literatures, it is difficult to construct the photonuclear data file by using only measured data, since there are not sufficient experimental data. We were therefore evaluating with theoretical calculations based on statistical nuclear reaction models. The photonuclear cross sections that are to be contained in the file are as follows: photoabsorption cross sections, yield cross sections and DDX for neutrons, protons, deuterons, tritons,
He-particles and alpha-particles, and isotope production cross sections. For the actinide nuclides, photofission cross sections are also included. The maximum energy of incident photons is 140 MeV and stored are the photonuclear data for 68 nuclides from
H to
Np.
Sukhovitskij, E.*; Chiba, Satoshi; Lee, J.*; Lee, Y.*; Chang, J.*; Maruyama, Toshiki; Iwamoto, Osamu
Journal of Nuclear Science and Technology, 39(8), p.816 - 826, 2002/08
Times Cited Count:13 Percentile:62.41(Nuclear Science & Technology)The soft-rotator model (SRM) and a coupled-channels method based on the oupling scheme based on the wave functions of the SRM were applied for a self-consistent analyses of the nuclear level structure, B(E2) and the nucleon interaction data of Fe. The model could describe the experimental collective levels of
Fe up to the excitation energy of 5.5 MeV successfully. Relativistic kinematics and global optical potential form, consistent with the shell model, dispersion relationship and Dirac phenomenology, were used in coupled-channels optical model approach to overcome problems left in our previous work. The available nucleon interaction experimental data up to 160 MeV and B(E2)
- transitions were described satisfactorily.
Hu, Q. H.*; Zhang, T.*; Shen, Y. Q.*; Tachi, Yukio; Fukatsu, Yuta; Borglin, S.*; Chang, C.*; Hampton, J.*
no journal, ,
Hanada, Masaya; Kojima, Atsushi; Akino, Noboru; Komata, Masao; Mogaki, Kazuhiko; Oh, B. H.*; Jeong, S. H.*; Chang, D. H.*; Lee, K. W.*; Bae, Y. S.*
no journal, ,
no abstracts in English