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Kimura, Akihiro; Tanimoto, Masataka; Ishida, Takuya; Tsuchiya, Kunihiko; Hasegawa, Yoshio*; Hishinuma, Yukio*; Suzuki, Masashi*
JAEA-Technology 2011-012, 17 Pages, 2011/06
PZC (Poly-Zirconium Compound) was developed as adsorbent of molybdenum for Mo-
Tc generator. However, PZC has some faults. So, new adsorbent based on titanium (PTC), was developed for getting rid of faults. This time,
Mo adsorption and
Tc elution tests with PZC and PTC were carried out. As a result, the
Mo adsorption performance of the PTC was lower than PZC, on the other hand,
Tc elution performance of the PTC was higher than PZC.
Matsuoka, Hiromitsu; Hashimoto, Kazuyuki; Hishinuma, Yukio*; Ishikawa, Koji*; Terunuma, Hitoshi*; Tatenuma, Katsuyoshi*; Uchida, Shoji*
Journal of Nuclear and Radiochemical Sciences, 6(3), p.189 - 191, 2005/12
Applicability of Mo adsorbent PZC(Poly Zirconium Compound) for W/
Re generator was investigated. Long term stability of adsorption of
W to the PZC column, elution of
Re from PZC column, desorption of
from PZC column, and labeling of Hydroxyethylidene Diphosphonic Acid(HEDP) and Mercaptoacetyltriglycine(MAG3) with
Re eluted from PZC column were tested. The PZC generator gave reproducible
Re elution yields with low
W parent breakthrough for a long period of time(about 5 months), that is the
W/
Re generator using PZC has a potential for practical use.
Wakai, Eiichi; Hishinuma, Akimichi; Miwa, Yukio; Ouchi, Asao*; Isozaki, Seiichi*; Takaki, Seiichi*; Abiko, Kenji*
Materials Transactions, JIM, 41(1), p.136 - 140, 2000/01
no abstracts in English
Miwa, Yukio; Jitsukawa, Shiro; Hishinuma, Akimichi
Journal of Nuclear Materials, 258-263(PT.A), p.457 - 461, 1998/00
Times Cited Count:15 Percentile:74.24(Materials Science, Multidisciplinary)no abstracts in English
Wakai, Eiichi; Hishinuma, Akimichi; Abe, Hiroaki; Miwa, Yukio; Takaki, Seiichi*; Abiko, Kenji*
Proc of Ultra-High-Purity Metallic-Base Materials (UHPM-98), p.35 - 45, 1998/00
no abstracts in English
Noda, Kenji; Oyama, Yukio; ; Maekawa, Hiroshi; Hishinuma, Akimichi
Journal of Nuclear Materials, 174, p.319 - 326, 1990/00
Times Cited Count:13 Percentile:75.87(Materials Science, Multidisciplinary)no abstracts in English
Yamaguchi, Daisuke; Koizumi, Satoshi; Hasegawa, Yoshio*; Hishinuma, Yukio*; Suzuki, Masashi*; Kodama, Hiroto*; Onuma, Masato*; Oba, Yojiro*
no journal, ,
The structure of nitrogen (N)-doped titanium dioxide (TiO), which exhibits an improved photo-catalytic property, was investigated by small-angle neutron (SANS) and X-ray scattering (SAXS) methods. The N-doped TiO
nanosheet showed a SANS profile, of which q-dependence is nearly identical to that of undoped TiO
nanosheet, however, of which intensity is three times as large as that of undoped TiO
nanosheet. As for the SAXS measurements, hardly any difference was observed between undoped TiO
nanosheet and N-doped one. For N-doped nanosheet, a core-shell structure where TiO
particles locate at the center and N atoms surround the surface of TiO
particles was deduced from the analysis of those obtained SANS and SAXS profiles by taking account of the difference in scattering contrast between neutron and X-ray for each component, i.e., Ti, O, and N atoms.
Niizeki, Tomotake*; Hishinuma, Yukio*; Suzuki, Masashi*; Hasegawa, Yoshio*; Nishikata, Kaori; Kimura, Akihiro; Ishida, Takuya; Tanimoto, Masataka; Tsuchiya, Kunihiko
no journal, ,
no abstracts in English
Yamaguchi, Daisuke; Noda, Yohei; Koizumi, Satoshi; Hasegawa, Yoshio*; Hishinuma, Yukio*; Suzuki, Masashi*; Kodama, Hiroto*; Onuma, Masato*; Oba, Yojiro*
no journal, ,
The structure of nitrogen (N)-doped titanium dioxide (TiO), which is a visible light photocatalyst, was investigated by small-angle neutron (SANS) and X-ray scattering (SAXS) methods. The bare TiO
was fabricated by sol-gel method and possessed a characteristic length of ca. 10 nm due to some regularity consisting of TiO
particles and pores. In the air, bare TiO
and N-doped TiO
specimens showed a similar scattering profiles each other for both of SANS and SAXS measurements. A slight increase of scattering intensity was observed for N-doped TiO
specimen only on the SANS profile. To confirm whether the slight difference in SANS profiles between bare TiO2
and N-doped TiO
specimens was due to the doped N atoms, both of bare TiO
and N-doped TiO
specimens were soaked in the mixture of H
O/D
O = 55/45 (w/w) mixture, of which scattering contrast for neutron is the same as TiO
, and measured by SANS. The resultant SANS profiles of soaked bare TiO
and N-doped TiO
specimens were distinctly different each other and the scattering from doped N atoms, which gives the information of their distribution was captured.
Yamaguchi, Daisuke; Noda, Yohei; Koizumi, Satoshi; Hasegawa, Yoshio*; Hishinuma, Yukio*; Suzuki, Masashi*; Kodama, Hiroto*; Onuma, Masato*; Oba, Yojiro*; Yuasa, Takeshi*; et al.
no journal, ,
Nowadays industrial materials tend to include a variety of additives and to be a composite of them to satisfy a high request for intelligent function and durability. Elucidation of such a multi-component and hierarchical structure is really a tough work but indispensable to learn the fundamentals of relation between the structure and property and to attain a reasonable improvement of those materials. Combined use of small-angle neutron scattering (SANS) and small-angle X-ray scattering (SAXS) often gives a good clue to decompose the total scattering of the organic/inorganic composite into the partial scattering from a particular component. Two examples will be demonstrated here for extracting the structural information from the composite specimen via this method; one is the distribution of the dopant nitrogen atoms in the porous photocatalyst and the other is the dispersion state of fillers in the rubber matrix.
Haraga, Tomoko; Hishinuma, Yukio*; Kaneta, Yui*; Ishimori, Kenichiro; Takahashi, Kuniaki
no journal, ,
no abstracts in English
Amamoto, Ippei; Yokozawa, Takuma; Kobayashi, Hidekazu; Taguchi, Tomitsugu; Hasegawa, Yoshio*; Hishinuma, Yukio*; Yamakawa, Atsushi*
no journal, ,
no abstracts in English
Yamaguchi, Daisuke; Hasegawa, Yoshio*; Hishinuma, Yukio*; Kodama, Hiroto*; Suzuki, Masashi*; Koizumi, Satoshi*; Noda, Yohei; Oba, Yojiro*
no journal, ,
Anion doped titanium dioxide (TiO), which is expected to exhibit an improved photo-catalytic property due to the effect of narrowing in the band gap, was investigated by small-angle neutron scattering (SANS). Among wide variety of photo-catalytic products, TiO
is one of the most promising and various improvements have been done. On the functional aspect it has been confirmed that for instance, nitrogen (N) doped TiO
can be activated not only by the photons of which wavelength is corresponding to ultraviolet but also by those of visible light and thereby an enhancement of the efficiency is attained. However, the difference in structure between bare TiO
and N-doped TiO
has not yet definitively clarified despite the considerable structural analyses by using X-ray probes. With profiting from an enhanced scattering length of N atoms to the neutron beam, an attempt to capture the distribution of N atoms in the N-doped TiO
by SANS is presented here.
Hasegawa, Yoshio*; Hishinuma, Yukio*; Amamoto, Ippei; Yokozawa, Takuma; Kobayashi, Hidekazu; Taguchi, Tomitsugu; Yamakawa, Atsushi*; Suzuki, Masashi*
no journal, ,
no abstracts in English
Yamaguchi, Daisuke; Hasegawa, Yoshio*; Hishinuma, Yukio*; Suzuki, Masashi*; Kodama, Hiroto*; Koizumi, Satoshi*; Noda, Yohei; Oba, Yojiro*
no journal, ,
Anion, e.g., nitrogen (N) doped titanium dioxide (TiO), being expected to exhibit an improved photo-catalytic property due to the effect of narrowing in the band gap, was investigated by small- (SANS) and wide-angle neutron scattering. Among wide variety of photo-catalytic products, TiO
is one of the most promising and various improvements have been done. However, the difference in structure between bare TiO
and N-doped TiO
has not yet definitively clarified despite the considerable structural analyses by X-ray diffraction or X-ray photoemission spectroscopy. With profiting from an enhanced scattering length of N atoms to the neutron beam, an attempt to capture the distribution of N atoms in N-doped TiO
by SANS was conducted. Specimens prepared with and without N-doping were compared. The traces of doped N species on the scattering profiles might be brought out from invisible differences with contrast variation method employing the soakage in tuned H
O/D
O mixture possessing nearly the same scattering length density as TiO
component.
Nakamura, Tatsuya; To, Kentaro; Tobe, Masahiro; Hishinuma, Yukio*; Hosoya, Takaaki; Sakasai, Kaoru
no journal, ,
no abstracts in English
Nakamura, Tatsuya; To, Kentaro; Kiyanagi, Ryoji; Ohara, Takashi; Hosoya, Takaaki; Tobe, Masahiro; Hishinuma, Yukio*; Ebine, Masumi; Sakasai, Kaoru
no journal, ,
New detector modules have been developed based on a Li:ZnS scintillator and wavelength-shifting fibers technology to upgrade the detectors for SENJU neuron diffractometer at J-PARC MLF. The detector upgrade plan includes (1) Thin-type add-in detectors, (2) High efficiency detectors to replace the original ones, (3) a large area detector for installation under the sample vacuum tank (Large area bottom detector), and (4) One detector-bank detectors. As for (1) and (2) the detector modules have been developed with a 1.5-fold improved detection efficiency with a 50-60% smaller detector depth. 4 add-in detectors and 6 replacement detectors have been manufactured and installed to the diffractometer. The large area bottom detector that has a four-fold larger neutron-sensitive area than the original detector, has also been developed. To increase the light collection efficiency a scintillation light is collected from the both ends of the wavelength-shifting fiber. The prototype detector exhibited an acceptable count uniformity 5
9% over the detector.
Watanabe, Masashi; Morimoto, Kyoichi; Kato, Masato; Konashi, Kenji*; Arita, Yuji*; Watanabe, Hiromichi*; Hishinuma, Yukio*
no journal, ,
no abstracts in English
Hashimoto, Kazuyuki; Hishinuma, Yukio*; Ishikawa, Koji*; Terunuma, Hitoshi*; Tatenuma, Katsuyoshi*; Uchida, Shoji*; Matsuoka, Hiromitsu
no journal, ,
Applicability of Mo adsorbent PZC(Poly Zirconium Compound) for W/
Re generator was investigated. Up to the present, long term stability of adsorption of
W to the PZC column, elution of
Re from PZC column, desorption of
W from PZC column, and labeling of Hydroxyethylidene Diphosphonic Acid (HEDP) and Mercaptoacetyltriglycine (MAG3) with
Re eluted from PZC column were tested and the results were compared with that of
Re eluted from alumina column.
Yamaguchi, Daisuke; Koizumi, Satoshi; Hasegawa, Yoshio*; Hishinuma, Yukio*; Suzuki, Masashi*; Kodama, Hiroto*; Onuma, Masato*; Oba, Yojiro*
no journal, ,
From the combined SANS and SAXS profiles, both of the neat and N-doped TiO catalyst was characterized to have a sheet-like shape with thickness of several tens to hundreds of nm and to be composed of sub-unit TiO
particles of several nm. On the SANS profile, the N-doped TiO
catalyst showed a q-dependence nearly identical to that of neat TiO
catalyst, however, of which intensity is three times as large as that of neat TiO
catalyst. On the other hand, by SAXS measurement, hardly any difference was observed between neat TiO
catalyst and N-doped one. The analysis of those obtained SANS and SAXS profiles suggests that the localization of doped N atoms at the surface of TiO
particles and hence TiO
-core/N-shell structure can be inferred for the N-doped TiO
material.