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Onutai, S.; Sato, Junya; Osugi, Takeshi
Journal of Solid State Chemistry, 319, p.123808_1 - 123808_10, 2023/03
Times Cited Count：0 Percentile：0.05(Chemistry, Inorganic & Nuclear)Onutai, S.; Osugi, Takeshi; Sone, Tomoyuki
Materials, 16(3), p.985_1 - 985_14, 2023/02
Times Cited Count：0 Percentile：0.02(Chemistry, Physical)Nakashio, Nobuyuki*; Osugi, Takeshi; Kurosawa, Shigenobu; Ishikawa, Joji; Hemmi, Ko; Iketani, Shotaro; Yokobori, Tomohiko
JAEA-Technology 2022-016, 47 Pages, 2022/08
JAEA-Technology-2022-016.pdf:2.23MB
The Nuclear Science Research Institute (NSRI) of the Japan Atomic Energy Agency (JAEA) started operation of the Advanced Volume Reduction Facilities (AVWF) for production of waste packages for disposal of low-level radioactive solid wastes (LLW). To clarify the operating conditions for homogenization of non-metallic LLW, preliminary tests were carried out using the plasma melting furnace of the non-metal melting unit. The fluidity of molten waste influences homogenization conditions of solidified products. It was clarified that the viscosity, which is determined by the chemical composition and the melting temperature, influence the fluidity of molten waste greatly through previous literature review and the small-scale melting tests. In the preliminary tests, the simulated waste with a cold tracer loaded in 200 L drums were melted. Using the waste chemical components (basicity, iron oxide concentration) as an experimental parameter, the homogeneity of the chemical components of the solidified product was investigated and the homogenization conditions of melting tests were examined. The retention ratio of the tracer in the molten bath was also confirmed. The viscosity of the molten wastes was measured and the correlation with homogeneity was examined. In addition, the technical requirements that should be concerned in advance for future actual operation were discussed.
Okamoto, Yoshihiro; Osugi, Takeshi; Shiwaku, Hideaki; Akabori, Mitsuo*
Insights Concerning the Fukushima Daiichi Nuclear Accident, Vol.4; Endeavors by Scientists, p.285 - 294, 2021/10
The transfer behavior of cesium adsorbed on some clay minerals in aqueous solution was investigated by X-ray absorption fine structure (XAFS) analysis of the Cs K-edge. The sample was prepared by mixing Cs-adsorbed mineral with a different pure clay mineral in water. The XAFS results of the dried mixture powder were compared with those obtained before mixing. It was recognized from the XAFS analysis for three kinds of clay minerals illite, kaolinite and vermiculite, that cesium was transferred from kaolinite to illite and vermiculite, and from illite to vermiculite. It can be concluded that cesium is transferred to and accumulated in vermiculite.
Kozai, Naofumi; Sato, Junya; Osugi, Takeshi; Shimoyama, Iwao; Sekine, Yurina; Sakamoto, Fuminori; Onuki, Toshihiko
Journal of Hazardous Materials, 416, p.125965_1 - 125965_9, 2021/08
Times Cited Count：14 Percentile：86.26(Engineering, Environmental)Irisawa, Keita; Kudo, Isamu*; Taniguchi, Takumi; Namiki, Masahiro*; Osugi, Takeshi; Nakazawa, Osamu
QST-M-16; QST Takasaki Annual Report 2017, P. 63, 2019/03
no abstracts in English
Abe, Tomohisa; Shimazaki, Takejiro; Osugi, Takeshi; Nakazawa, Osamu; Yamada, Naoto*; Yuri, Yosuke*; Sato, Takahiro*
QST-M-16; QST Takasaki Annual Report 2017, P. 140, 2019/03
no abstracts in English
Garcia-Lodeiro, I.*; Lebon, R.*; Machoney, D.*; Zhang, B.*; Irisawa, Keita; Taniguchi, Takumi; Namiki, Masahiro*; Osugi, Takeshi; Meguro, Yoshihiro; Kinoshita, Hajime*
Proceedings of 3rd International Symposium on Cement-based Materials for Nuclear Wastes (NUWCEM 2018) (USB Flash Drive), 4 Pages, 2018/11
-ray during dehydrationIrisawa, Keita; Kudo, Isamu*; Taniguchi, Takumi; Namiki, Masahiro*; Osugi, Takeshi; Nakazawa, Osamu
QST-M-8; QST Takasaki Annual Report 2016, P. 63, 2018/03
A solidification technique with minimized water content is being developed using a phosphate cement for safe storage of secondary radioactive wastes in the Fukushima Daiichi Nuclear Power Plant. To understand the applicability of the solidification technique for the actual secondary wastes, phosphate cement during dehydration was irradiated by 
Co -ray. The G(H
) for the phosphate cement decreased with time during dehydration, and was not detected after 7 days. Moreover, the Co -ray irradiation during dehydration did not change the crystalline and amorphous phases of the phosphate cement.
Abe, Tomohisa; Shimazaki, Takejiro; Osugi, Takeshi; Yamada, Naoto*; Yuri, Yosuke*; Sato, Takahiro*
QST-M-8; QST Takasaki Annual Report 2016, P. 61, 2018/03
no abstracts in English
Okamoto, Yoshihiro; Osugi, Takeshi; Akabori, Mitsuo; Kobayashi, Toru; Shiwaku, Hideaki
Journal of Molecular Liquids, 232, p.285 - 289, 2017/04
Times Cited Count：3 Percentile：13.86(Chemistry, Physical)High energy XAFS measurement using cerium K-edge was performed to study the chemical state of cerium in high-temperature molten slag (SiO-CaO-FeO
-CeO). It was found from the change in the nearest Ce-O distance obtained from EXAFS analysis and the energetic shift of the white line peak observed in XANES analysis that oxidation state of cerium was tetravalent in the molten state and trivalent in solid state. The Debye-Waller factor of the nearest Ce-O pair in solid slag was very large even at room temperature, and the change in its value upon heating and melting was very small. This result suggests that cerium is highly disordered and stable in solid slag.
Irisawa, Keita; Taniguchi, Takumi; Namiki, Masahiro; Garc
a-Lodeiro, I.*; Osugi, Takeshi; Sakakibara, Tetsuro; Nakazawa, Osamu; Meguro, Yoshihiro; Kinoshita, Hajime*
Proceedings of 2017 International Congress on Advances in Nuclear Power Plants (ICAPP 2017) (CD-ROM), 6 Pages, 2017/04
A solidification technique with minimized water content is being developed using phosphate cements for the safe storage of secondary radioactive wastes in the Fukushima Daiichi Nuclear Power Plant. Conventional cement systems become solidified via hydration reactions, and need a certain water content. Phosphate cement systems, however, become solidified via an acid-base reaction, and so they only require water mainly for reasons of workability. A reduced water content of phosphate cement systems is beneficial for the immobilization of the radioactive wastes from mitigating the potential to generate hydrogen gas by the radiolysis of water by radioactive wastes. The current study investigated the water content and mineralogy of calcium aluminate cement (CAC) and phosphate-modified CAC (CAP) cured in open systems at 60, 90 and 120 
C and in a closed system at 20 C as a reference case. Water contents in both the CAC and the CAP were seen to decrease as curing progressed. For 
90 C, the CAP contained less water than CAC. Free water in CAC converted to structural water by heat treatment, but this was not the case for CAP. An orthophosphate hydrate salt, a precursor phase of hydroxyapatite, was found in CAP when cured at 20 and 60 C, and a mixture of the orthophosphate hydrate salt and hydroxyapatite, Ca
(PO
)
(OH), were formed in the CAP when cured at 90 C. Phosphate products in CAP cured at 120 C appears to consist of a different phosphate phase compared with the CAP cured at 20, 60 and 90 C.
Abe, Tomohisa; Shimazaki, Takejiro; Nakayama, Takuya; Osone, Osamu; Osugi, Takeshi; Nakazawa, Osamu; Yuri, Yosuke*; Yamada, Naoto*; Sato, Takahiro*
QST-M-2; QST Takasaki Annual Report 2015, P. 83, 2017/03
no abstracts in English
Nakashio, Nobuyuki; Osugi, Takeshi; Iseda, Hirokatsu; Tohei, Toshio; Sudo, Tomoyuki; Ishikawa, Joji; Mitsuda, Motoyuki; Yokobori, Tomohiko; Kozawa, Kazushige; Momma, Toshiyuki; et al.
Journal of Nuclear Science and Technology, 53(1), p.139 - 145, 2016/01
Times Cited Count：1 Percentile：11.75(Nuclear Science & Technology)no abstracts in English
Nakayama, Takuya; Kawato, Yoshimi; Osugi, Takeshi; Shimazaki, Takejiro; Hanada, Keiji; Suzuki, Shinji; Sakakibara, Tetsuro; Nakazawa, Osamu; Meguro, Yoshihiro
JAEA-Technology 2014-046, 56 Pages, 2015/03
JAEA-Technology-2014-046.pdf:7.61MB
The combustible and flame-retardant radioactive wastes generated as a result of the research activities in Japan Atomic Energy Agency (JAEA) are incinerating to reduce their volume. The incinerated ash is planned to be solidified using cement for disposal. Since the properties of ashes generated in each institute of JAEA are varied with the type of incinerator and the wastes to be incinerated, it is necessary to do fundamental solidification tests in each institute to decide operating conditions of the planning cement solidification facility. It is important to standardize evaluating methods of cement and solidified waste because some characters depend on measuring method. This user's guide have been prepared how to decide the cement solidifying conditions of ash to design the cement solidification facility in JAEA. Requirements on the regulations of solidified radioactive waste have been examined and seven technical criteria, e.g. compressive strength, fluidity, have been selected as characters to be evaluated. Some empirical notes about selection of cement, admixtures, procedure on making a test piece, evaluation of expanding, compressive strength, solubility have been described. The strategy of tests and tips for finding optimized solidification condition has been summarized. Finally the example of optimized conditions satisfied the requirements and some problems to be solved have been described.
Okamoto, Yoshihiro; Osugi, Takeshi; Shiwaku, Hideaki; Akabori, Mitsuo
Nihon Genshiryoku Gakkai Wabun Rombunshi, 13(3), p.113 - 118, 2014/09
Transfer behavior of cesium adsorbed on some clay minerals in aqueous solution was investigated by X-ray absorption fine structure (XAFS) analysis of Cs K-edge. The sample was prepared by mixing Cs-adsorbed mineral with another different kind of pure clay mineral in water. The XAFS results of the dried mixture powder were compared with those obtained before the mixing. It was recognized from the XAFS analysis for three kinds of clay minerals; Illite, Kaolinite and Vermiculite, that cesium was transferred from Kaolinite to Illite and vermiculite, and from Illite to Vermiculite. It can be concluded that cesium is transferred to and accumulated in Vermiculite.
Umeda, Takahide*; Okamoto, Mitsuo*; Arai, Ryo*; Sato, Yoshihiro*; Kosugi, Ryoji*; Harada, Shinsuke*; Okumura, Hajime*; Makino, Takahiro; Oshima, Takeshi
Materials Science Forum, 778-780, p.414 - 417, 2014/02
Times Cited Count：2 Percentile：74.69Interface defects of Metal-Oxide-Semiconductors (MOSFETs) fabricated on Carbone (C) face 4H-SiC were investigated by Electrically Detected Magnet Resistance (EDMR). Gate oxide of the MOSFETs was formed by either wet-oxidation and H annealing or dry-oxidation. The values of channel mobility for MOSFETS with wet gate oxide and dry gate oxide are less than 1 and 90 cm
/Vs, respectively. By EDMR measurement under low temperature (less than 20 K), EDMR signals related to C were detected. The peak height of the signals increased with increasing -ray doses, and the channel mobility decreased. From this result, it is assumed that hydrogen atoms passivating C dangling bonds are released by -rays and the channel mobility decreases with increasing the C related defects.
Sukenaga, Sohei*; Osugi, Takeshi; Inatomi, Yosuke*; Saito, Noritaka*; Nakashima, Kunihiko*
Journal of MMIJ, 129(5), p.203 - 207, 2013/05
Viscosity changes of RO-SiO-FexO (R = Ca, Sr, Ba) melts due to changes in the oxidation states of the iron ions by systematically varying the oxygen partial pressure were measured at 1773 K. The initial compositions of the samples were 30RO-60SiO-10FeO(mol%), and the ratio of Fe
toFe
in the RO-SiO-FexO melts increased with increasing oxygen partial pressure in all samples. Meanwhile, the viscosity of all the RO-SiO-FexO melts decreased with increasing Fe to total-Fe ratio (Fe/t-Fe). The data indicate that the increase in the amount of Fe ions, which behave as network modifiers, would result in depolymerization of the silicate anions. In addition, the viscosity of the melts increased in the order of alkaline-earth cationic radius (Ba 
Sr Ca) when the Fe/t-Fe values of the melts were comparable. This would be due to the change in the coordination structure of Fe in the melts.
Osugi, Takeshi; Sukenaga, Sohei*; Inatomi, Yosuke*; Gonda, Yoshiyuki*; Saito, Noritaka*; Nakashima, Kunihiko*
ISIJ International, 53(2), p.185 - 190, 2013/02
Times Cited Count：16 Percentile：64.36(Metallurgy & Metallurgical Engineering)Understanding the changes in viscosity due to the different oxidation states of iron ions is important for simulating phenomena related to molten slags and also for understanding the structure of iron-oxidecontainingsilicate melts. However, these viscosity changes are not well understood. Here, we show the viscosity changes of RO-SiO-FexO (R = Li, Na, or K) melts due to changes in the oxidation states of the iron ions by systematically varying the oxygen partial pressure using several Ar-based gases at 1773 K. Not only the oxidation state of the iron ions but also the coordination structure of Fe may be important for understanding the viscosity.
interfacesUmeda, Takahide*; Kosugi, Ryoji*; Fukuda, Kenji*; Morishita, Norio*; Oshima, Takeshi; Ezaki, Kana*; Isoya, Junichi*
Materials Science Forum, 717-720, p.427 - 432, 2012/05
Times Cited Count：6 Percentile：94.36Metal-Oxide (SiO)-Semiconductor (MOS) structures fabricated on Silicon Carbide (SiC) were studied using Electrically Detected Magnetic Resonance technique (EDMR). The residual Carbons are expected to be near the interface between SiC and SiC-SiOSiO, which is different from Si-SiO interface. By the EDMR measurements at 50K, a defect center related to C dangling bonds which is called P
center and also a center related to C dangling bonds terminated by hydrogens or nitrogens (Ns) which is called P were observed. In addition, a center related to N donor which is called Nh exist near the interface from N-treatment samples. This suggests that carrier concentration increases near the interface due to the introduction of donors, and as a result, the channel conductance increases.
