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addition on water durability of FeO-FeO
-PO
glassesKitamura, Naoto*; Nomura, Akira*; Saito, Akira*; Kobayashi, Hidekazu; Amamoto, Ippei; Takebe, Hiromichi*
Journal of the Ceramic Society of Japan, 126(11), p.948 - 951, 2018/11
Times Cited Count：6 Percentile：23.20(Materials Science, Ceramics)We studied compositional dependence of water durability of Zr(IV) containing FeO-FeO-PO glasses systems, which can apply to immobilize nuclear waste of Zr isotope. Stabilized film with interference fringe on the surface improves better water durability after immersion tests for BaO and ZrO coexisting glasses without fracture. On the other hand, microcrystalline ZrPO
was detected in the glass matrix when more than 1 mol% of ZrO incorporated. The effect of impregnated ZrPO crystal on the structure was discussed based on the phosphate structure analyzed by Raman spectra. Formation of Q
and Q
units, which contribute to water durability in the glass, are due to preferential precipitation of ZrPO crystal.
Amamoto, Ippei; Kobayashi, Hidekazu; Kitamura, Naoto*; Takebe, Hiromichi*; Mitamura, Naoki*; Tsuzuki, Tatsuya*; Fukayama, Daigen*; Nagano, Yuichi*; Jantzen, T.*; Hack, K.*
Journal of Nuclear Science and Technology, 53(10), p.1467 - 1475, 2016/10
Times Cited Count：5 Percentile：39.52(Nuclear Science & Technology)The iron phosphate glass (IPG) medium is known to be a high-efficiency glass medium, therefore we try to evaluate its applicability to immobilize sludge bearing radioactive nuclides arising from treatment of contaminated water at the stricken Fukushima Daiichi Nuclear Power Plant. For this study, many physical and chemical properties of target materials are necessary to evaluate the behaviours of IPG medium and its waste forms. Inevitably, it will entail the need for many and varied types of experiments to be carried out under high temperature. It is therefore rational to apply appropriate theoretical analysis first so as to reduce the number of experimental run. For this reason, some necessary thermodynamic values for theoretical analysis were estimated by CALPHAD approach followed by making up the calculated phase diagrams. By comparison with experimental results, they were found to be reliable for evaluating the behaviours of IPG medium and its waste forms.
Kobayashi, Hidekazu; Amamoto, Ippei; Yokozawa, Takuma; Yamashita, Teruo; Nagai, Takayuki; Kitamura, Naoto*; Takebe, Hiromichi*; Mitamura, Naoki*; Tsuzuki, Tatsuya*
Proceedings of 15th International Conference on Environmental Remediation and Radioactive Waste Management (ICEM 2013) (CD-ROM), 6 Pages, 2013/09
no abstracts in English
as the dominant sludge constituent generated from the treatment of water used for cooling the stricken power reactorsAmamoto, Ippei; Kobayashi, Hidekazu; Yokozawa, Takuma; Yamashita, Teruo; Nagai, Takayuki; Kitamura, Naoto*; Takebe, Hiromichi*; Mitamura, Naoki*; Tsuzuki, Tatsuya*
Proceedings of 15th International Conference on Environmental Remediation and Radioactive Waste Management (ICEM 2013) (CD-ROM), 8 Pages, 2013/09
The great amount of water used for cooling the stricken power reactors at Fukushima Dai-ichi has resulted in accumulation of "remaining water". As the remaining water is subsequently contaminated by FPs, etc., it is necessary to decontaminate it in order to reduce the volume of liquid radioactive waste and to reuse it again for cooling the reactors. Various techniques are being applied to remove FP, etc. and to make stable waste forms. One of the methods using the iron phosphate glass as a medium is being developed to stabilize the strontium-bearing sludge whose main component is BaSO. From the results hitherto, the iron phosphate glass is regarded as a potential medium for the target sludge.
Hagiwara, Shigeru*; Sakamoto, Yoshiaki; Takebe, Shinichi; Ogawa, Hiromichi; Nakayama, Shinichi
JAERI-Review 2002-038, 107 Pages, 2002/12
JAERI-Review-2002-038.pdf:6.72MB
For the disposal of radioactive waste arising from radioactive utilization facilities and nuclear facilities, it is necessary to establish the disposal system in proportion to half-lives of radionuclides and radioactivity concentration in the waste. It is important to grasp the features of the earth scientific phenomena and geological structure of our country for the disposal system of radioactive waste. Then, for the porpose of the survey of the geological characteristics around the Japanese Islands whole neiborhood, the earth scientific phenomena at present, geological structure and geotectonic history were summarized on the basis of the existing literatures.
Sakamoto, Yoshiaki; Ishii, Tomoaki*; Inagawa, Satoshi*; Gunji, Yasuyoshi*; Takebe, Shinichi; Ogawa, Hiromichi; Sasaki, Tomozo*
Journal of Nuclear Science and Technology, 39(Suppl.3), p.481 - 484, 2002/11
Sorption behavior of 227Ac and 233Pa onto several kinds of soils has been studied with a sequential extraction technique, for safety assessment of shallow land disposal of uranium bearing waste. After a batch sorption experiment, the sorbed form of 227Ac and 233Pa onto the soils was fractionated into ion exchange form (extraction by KCl+CaCl2), association with Fe+Mn oxides (extraction by NH2OH-HCl and oxalic acid), association with organic materials (extraction by H2O2) and fixation into soil (residual). From the results of the sequential extraction, major part of 227Ac sorbed onto the soils was found in the fraction of the ion exchange form and the fixation into the soils. On the other hand, major part of 233Pa was found in the fraction of the association with Fe+Mn oxides and the fixation into the soils. These results suggest that the sorption behavior of 227Ac and 233Pa is related to the irreversible sorption reaction onto the soils.
Ishii, Tomoaki*; Inagawa, Satoshi*; Gunji, Yasuyoshi*; Sakamoto, Yoshiaki; Takebe, Shinichi; Ogawa, Hiromichi; Sasaki, Tomozo*
Genshiryoku Bakkuendo Kenkyu, 8(1), p.55 - 64, 2001/09
Distribution coefficients of Uranium series nuclide(Pb,Ra,Ac,Th,Pa and U) were obtained under aerated zone environment and aquifer environment, for the safety evaluation of shallow underground disposal of uranium bearing waste. The distribution coefficients of them on 4 kinds of soil such as the loam in the rain water as for aerated zone environment and on 3 kinds of soil and rock such as the sand in groundwater as for aquifer environment have been measured by batch method. The distribution coefficients in aerated zone environment were one or two orders in magnitude higher than that in aquifer environment, except Ac. And, there was approximately the linear correlation on the relationship between cation exchange capacity and specific surface area, which are representative physical property of the soil, and distribution coefficient of lead, radium and protactinium.
Sakamoto, Yoshiaki; Ishii, Tomoaki*; Inagawa, Satoshi*; Gunji, Yasuyoshi*; Takebe, Shinichi; Ogawa, Hiromichi; Sasaki, Tomozo*
Genshiryoku Bakkuendo Kenkyu, 8(1), p.65 - 76, 2001/09
In order to study adsorption behavior of U series radionuclides(Pb, Ra, Th, Ac, Pa and U) in aerated zone environment (loam-rein water system) and aquifer environment(sand-groundwater system) for safety assessment of U bearing waste), pH dependence of distribution coefficients of each element have been obtained. The pH dependence of distribution coefficients of U, Ac, Th, Ra and Pb was analyzed by model calculation of adsorption behavior based on chemical forms of each elements and soil surface characteristics, which are a cation exchange capacity and surface charge. From model calculation of adsorption behavior, the distribution coefficients' values and adsorption behavior of Pb, Ra, Th, Ac and U could be showed by a combination of cation exchange and surface-complexation adsorption model.
Chinju, H.*; Nagasaki, Shinya*; Tanaka, Satoru*; Sakamoto, Yoshiaki; Takebe, Shinichi; Ogawa, Hiromichi
Journal of Nuclear Science and Technology, 38(8), p.645 - 654, 2001/08
Times Cited Count：3 Percentile：26.45(Nuclear Science & Technology)no abstracts in English
Sakamoto, Yoshiaki; Takebe, Shinichi; Ogawa, Hiromichi; Muraoka, Susumu; Ishii, Tomoaki*; Inagawa, Satoshi*; Gunji, Yasuyoshi*
Materials Research Society Symposium Proceedings, Vol.663, p.1207 - 1214, 2001/00
no abstracts in English
Hagiwara, Shigeru*; Sakamoto, Yoshiaki; Takebe, Shinichi; Okuda, Katsuzo*; Ogawa, Hiromichi
JAERI-Research 2000-039, 119 Pages, 2000/09
JAERI-Research-2000-039.pdf:5.04MB
no abstracts in English
Okuda, Katsuzo*; Takebe, Shinichi; Sakamoto, Yoshiaki; Hagiwara, Shigeru*; Ogawa, Hiromichi
JAERI-Review 99-023, p.100 - 0, 1999/10
JAERI-Review-99-023.pdf:4.63MB
no abstracts in English
Np and 
Am in sedimentary geological formationTanaka, Tadao; Takebe, Shinichi; Ogawa, Hiromichi; Muraoka, Susumu
JAERI-Research 98-018, 20 Pages, 1998/03
JAERI-Research-98-018.pdf:0.94MB
no abstracts in English
; Yamamoto, Tadatoshi; ; Takebe, Shinichi; Ogawa, Hiromichi; Tanaka, Tadao; Mukai, Masayuki; Komiya, Tomokazu; S.Li*; Z.Wang*; et al.
JAERI-Research 94-009, 44 Pages, 1994/07
JAERI-Research-94-009.pdf:1.69MB
no abstracts in English
Ogawa, Hiromichi; Takebe, Shinichi;
JAERI-Research 94-002, 12 Pages, 1994/07
JAERI-Research-94-002.pdf:0.61MB
no abstracts in English
Ogawa, Hiromichi; Takebe, Shinichi; Yamamoto, Tadatoshi
Journal of Nuclear Science and Technology, 28(3), p.248 - 254, 1991/03
no abstracts in English
Yamamoto, Tadatoshi; Takebe, Shinichi; Ogawa, Hiromichi; Tanaka, Tadao; Mukai, Masayuki; Komiya, Tomokazu; ;
JAERI-M 89-189, 18 Pages, 1989/11
no abstracts in English
Yamamoto, Tadatoshi; Takebe, Shinichi; Ogawa, Hiromichi; Tanaka, Tadao; Mukai, Masayuki; Komiya, Tomokazu; ;
JAERI-M 89-144, 23 Pages, 1989/10
no abstracts in English
-containing iron phosphate glassFujisawa, Masaharu*; Takebe, Hiromichi*; Kobayashi, Hidekazu; Amamoto, Ippei
no journal, ,
High level radioactive waste contains a relatively large amount of MoO. Mo is known to be a difficult element to incorporate in nuclear waste glass such as borosilicate glasses. On the other hand, phosphate glasses is able to contain MoO over a wide and continuous compositional range. In this study, the effect of MoO addition on properties of iron phosphate glass is studied. The glass transition temperature was evaluated. The immersion tests were performed according to MCC-2 test method due to evaluate the water durability. The additional effects of MoO are discussed in terms of glass structure.
Amamoto, Ippei; Kobayashi, Hidekazu; Yokozawa, Takuma; Yamashita, Teruo; Nagai, Takayuki; Suzuki, Yoshikazu*; Takebe, Hiromichi*; Mitamura, Naoki*; Tsuzuki, Tatsuya*
no journal, ,
no abstracts in English
