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Journal Articles

The Translational, rotational, and phonon dynamics of water in ZrO$$_{2}$$/water nanofluid

Yoshida, Koji*; Sanada, Yusuke*; Yamaguchi, Toshio*; Matsuura, Masato*; Tamatsukuri, Hiromu; Uchiyama, Hiroshi*

Journal of Molecular Liquids, 366, p.120218_1 - 120218_9, 2022/11

 Times Cited Count:1 Percentile:16.81(Chemistry, Physical)

Journal Articles

Structural changes in pH-responsive gelatin/hydroxypropyl methylcellulose phthalate blends aimed at drug-release systems

Nogami, Satoshi*; Kadota, Kazunori*; Uchiyama, Hiromasa*; Arima-Osonoi, Hiroshi*; Iwase, Hiroki*; Tominaga, Taiki*; Yamada, Takeshi*; Takata, Shinichi; Shibayama, Mitsuhiro*; Tozuka, Yuichi*

International Journal of Biological Macromolecules, 190, p.989 - 998, 2021/11

 Times Cited Count:6 Percentile:39.73(Biochemistry & Molecular Biology)

JAEA Reports

XAFS measurement of simulated waste glass samples (Borosilicate glass including vanadium)

Nagai, Takayuki; Kobayashi, Hidekazu; Sasage, Kenichi; Ayame, Yasuo; Okamoto, Yoshihiro; Shiwaku, Hideaki; Matsuura, Haruaki*; Uchiyama, Takafumi*; Okada, Yukiko*; Nezu, Atsushi*; et al.

JAEA-Research 2016-015, 52 Pages, 2016/11

JAEA-Research-2016-015.pdf:37.48MB

The local structure of waste elements in simulated waste glasses including V was estimated by using synchrotron XAFS measurement in this study. The results are as follows. (1) V has a high possibility which exists in the glass phase in the case of frit, and V can regard both samples as stable 4 coordination structure. (2) Zn, Ce, Nd, Zr, and Mo exist in the glass phase, and the difference is admitted by the percentage of Ce(III) and Ce(IV) by the composition. (3) Ru is separated from the glass phase as RuO$$_{2}$$ crystalline, both of metal and oxide exist in Rh, and Pd is separated out as metal. (4) It was confirmed that the regularity of the local structure of Zr and Mo in the molten glasses retreats as a result of the XAFS measurement at high temperature. (5) The XAFS measurement of molten glasses were performed at 1200$$^{circ}$$C, so it would be possible to acquire excellent data by improving the shapes of the sample cell.

Journal Articles

Effect of magnetism on lattice dynamics in SrFe$$_2$$As$$_2$$ using high-resolution inelastic X-ray scattering

Murai, Naoki*; Fukuda, Tatsuo; Kobayashi, Tatsuya*; Nakajima, Masamichi*; Uchiyama, Hiroshi*; Ishikawa, Daisuke*; Tsutsui, Satoshi*; Nakamura, Hiroki; Machida, Masahiko; Miyasaka, Shigeki*; et al.

Physical Review B, 93(2), p.020301_1 - 020301_5, 2016/01

 Times Cited Count:7 Percentile:34.12(Materials Science, Multidisciplinary)

Journal Articles

Precise measurement of acoustic phonons in PrFeAsO$$_{1-y}$$

Fukuda, Tatsuo; Baron, A. Q. R.*; Uchiyama, Hiroshi*; Nakamura, Hiroki; Ishikado, Motoyuki*; Machida, Masahiko; Shamoto, Shinichi

SPring-8/SACLA Riyo Kenkyu Seikashu (Internet), 3(2), p.290 - 293, 2015/07

Journal Articles

Production of criticality safety standard data with Monte-Carlo code MVP / nuclear data library JENDL-3.2 validated using ICSBE data

Tonoike, Kotaro; Suyama, Kenya; Okuno, Hiroshi; Miyoshi, Yoshinori; Uchiyama, Gunzo

Proceedings of 9th International Conference on Nuclear Criticality (ICNC 2011) (CD-ROM), 8 Pages, 2012/02

The 1st version of criticality safety handbook of Japan was published in 1988. A criticality safety analysis code system JACS was validated, and minimum critical mass and safety limit mass of various fissile materials were calculated. During more than two decades since then, new critical experimental data were taken in the Static Critical Experiment Facility (STACY), and more precise benchmark data of wider range of fissile materials were accumulated by the International Criticality Safety Benchmark Evaluation Project (ICSBEP). Computational capability has greatly grown, and new codes and nuclear data have been developed. The 2nd version of the handbook utilizes the results of validation of the criticality analysis method with a continuous energy Monte-Carlo code MVP and a nuclear data library JENDL-3.2 using the benchmark data chosen from the ICSBEP handbook. Results of the benchmark calculation were statistically studied, from which the safety limit value of multiplication factor was derived as 0.98. Based on the conclusion, minimum critical mass and safety limit mass were calculated. Future plan of research activities on the criticality safety in JAEA will be also overviewed.

Journal Articles

Soft and isotropic phonons in PrFeAsO$$_{1-y}$$

Fukuda, Tatsuo; Baron, A. Q. R.*; Nakamura, Hiroki; Shamoto, Shinichi; Ishikado, Motoyuki; Machida, Masahiko; Uchiyama, Hiroshi*; Iyo, Akira*; Kito, Hijiri*; Mizuki, Junichiro; et al.

Physical Review B, 84(6), p.064504_1 - 064504_13, 2011/08

 Times Cited Count:9 Percentile:39.35(Materials Science, Multidisciplinary)

Journal Articles

Irradiation history of Itokawa regolith material deduced from noble gases in the Hayabusa samples

Nagao, Keisuke*; Okazaki, Ryuji*; Nakamura, Tomoki*; Miura, Yayoi*; Osawa, Takahito; Bajo, Kenichi*; Matsuda, Shintaro*; Ebihara, Mitsuru*; Ireland, T.*; Kitajima, Fumio*; et al.

Science, 333(6046), p.1128 - 1131, 2011/08

 Times Cited Count:130 Percentile:95.22(Multidisciplinary Sciences)

A steroid surface materials record regolith processes and a history of cosmic-ray irradiation. Noble gas isotopes in three rocky grains from Itokawa have been determined. High concentrations of solar He, Ne, and Ar, as high as those in lunar soils, are released at variable temperatures from each sample. The isotopic compositions are essentially identical to those of solar wind but distinguishable in He relative abundance. These noble gas characteristics can be explained by repeated implantation and preferential loss of solar He by removal of weathered He-rich rim on the grain surface through friction among regolith grains on Itokawa. Residence time of regolith materials on Itokawa is alculated to be shorter than 10 Myr, suggesting that regolith materials of small asteroids would escape easily to space.

Journal Articles

Phonon spectra of PrFeAsO$$_{1-y}$$ via inelastic X-ray scattering

Fukuda, Tatsuo; Baron, A. Q. R.*; Nakamura, Hiroki; Shamoto, Shinichi; Ishikado, Motoyuki; Machida, Masahiko; Uchiyama, Hiroshi*; Iyo, Akira*; Kito, Hijiri*; Mizuki, Junichiro; et al.

Journal of the Physical Society of Japan, 80(Suppl.B), p.SB015_1 - SB015_4, 2011/01

 Times Cited Count:1 Percentile:11.35(Physics, Multidisciplinary)

We have investigated phonons of PrFeAsO$$_{1-y}$$ using high-resolution inelastic X-ray scattering and $$ab-initio$$ calculations. Extensive measurements show that there are some changes in phonon spectra with temperature and/or doping. However, we compare our data with several calculations and find that the experimentally observed changes are much smaller than differences between the experiment. data and the calculations. Agreement is improved if magnetism is included in the calculations. However, still in disagreement even in the parent sample below T$$_N$$. We consider several modifications of the $$ab-initio$$ calculations. The best agreement is obtained from modifying the nonmagnetic calculation. by softening only the in-plane nearest-neighbor Fe-As force constant. Fluctuating magnetism may be a partial explanation for the failure of the calculations, but seems incomplete in the face of the similarity of the measured phonon response in all the systems investigated including those known to have static magnetism.

Journal Articles

Recent progress in the energy recovery linac project in Japan

Sakanaka, Shogo*; Akemoto, Mitsuo*; Aoto, Tomohiro*; Arakawa, Dai*; Asaoka, Seiji*; Enomoto, Atsushi*; Fukuda, Shigeki*; Furukawa, Kazuro*; Furuya, Takaaki*; Haga, Kaiichi*; et al.

Proceedings of 1st International Particle Accelerator Conference (IPAC '10) (Internet), p.2338 - 2340, 2010/05

Future synchrotron light source using a 5-GeV energy recovery linac (ERL) is under proposal by our Japanese collaboration team, and we are conducting R&D efforts for that. We are developing high-brightness DC photocathode guns, two types of cryomodules for both injector and main superconducting (SC) linacs, and 1.3 GHz high CW-power RF sources. We are also constructing the Compact ERL (cERL) for demonstrating the recirculation of low-emittance, high-current beams using above-mentioned critical technologies.

JAEA Reports

Second version of data collection part of nuclear criticality safety handbook (Contract research)

Okuno, Hiroshi; Suyama, Kenya; Tonoike, Kotaro; Yamane, Yuichi; Yamamoto, Toshihiro; Miyoshi, Yoshinori; Uchiyama, Gunzo

JAEA-Data/Code 2009-010, 175 Pages, 2009/08

JAEA-Data-Code-2009-010.pdf:13.1MB
JAEA-Data-Code-2009-010(errata).pdf:0.11MB

The report revised the Data Collection part of Nuclear Criticality Safety Handbook, which was published in 1988. This second version provided criticality data on homogeneous U-H$$_{2}$$O and UF$$_{6}$$-HF, which were not cited in the previous version, and increased those data on the medium-enriched uranium fuels. Calculations were performed mainly with the Continuous-Energy Monte Carlo Criticality Calculation Code, MVP, and the Japanese Evaluated Nuclear Data Library, JENDL-3 Revision 2, JENDL-3.2, both of which were developed at the late Japan Atomic Energy Research Institute (JAERI). Data on atomic number densities of actinide metal and oxide were additionally supplied, and nuclide compositions of irradiated fuels were improved from the first version. One million histories of neutrons were followed in benchmark calculations of critical experiments and in calculations of single-unit criticality data, i.e., critical mass, volume, dimensions, etc., to attain almost ten times higher precision than the first version.

Journal Articles

Design of a 500kV electron gun for ERL light source at KEK

Yamamoto, Masahiro*; Honda, Yosuke*; Miyajima, Tsukasa*; Uchiyama, Takashi*; Kobayashi, Masanori*; Muto, Toshiya*; Matsuba, Shunya*; Sakanaka, Shogo*; Sato, Kotaro*; Saito, Yoshio*; et al.

Proceedings of 6th Annual Meeting of Particle Accelerator Society of Japan (CD-ROM), p.860 - 862, 2009/08

A newly 500 kV electron gun (2nd - 500 kV gun) for an ERL light source is designed at KEK. A new concept and state of-the-art technologies of vacuum system, ceramic insulators, high voltage power supply, photocathode and preparation system will be employed. The details are described in this report.

Journal Articles

Fluctuation of the neutron multiplication factor induced by an oscillation of the fuel solution system

Sato, Shohei; Okuno, Hiroshi; Uchiyama, Gunzo

Journal of Nuclear Science and Technology, 46(3), p.268 - 277, 2009/03

 Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)

This paper intends to figure out reactivity of the fuel solution system with a free surface. To fulfill this intension, criticality calculation with reflecting fluid calculation results have been carried out. For fluid calculation, the finite volume method and the VOF method are applied to track the free surface caused by an oscillation. For criticality calculation, we have applied the continuous energy Monte Carlo calculation method. As a result, three fluctuation types of $$k$$$$_{eff}$$ have been obtained depending on the oscillation frequency and the ratio of the solution height to the width of tank (H/L). If a sloshing motion is generated, $$k$$$$_{eff}$$fluctuates by a wide range and has a threshold, which can classify the fluctuation type of $$k$$$$_{eff}$$, despite the kind of the reflector. If H/L is above the threshold, ${it i.e.,}$ H/L=0.35, it fluctuates below the value of the static condition. The threshold value represented in this paper is smaller than that of the conventional one.

Journal Articles

Nuclear criticality safety evaluation of a mixture of MOX, UO$$_{2}$$ and additive in the most conservative concentration distribution

Okuno, Hiroshi; Sato, Shohei; Sakai, Tomohiro*; Uchiyama, Gunzo

Journal of Nuclear Science and Technology, 45(11), p.1108 - 1115, 2008/11

 Times Cited Count:2 Percentile:16.99(Nuclear Science & Technology)

For nuclear criticality safety evaluation of blenders at the mixed uranium-plutonium oxide (MOX) fuel plant, non-uniformity distributions of powders in three chemical components, i.e., MOX, uranium-dioxide (UO$$_{2}$$) and zinc-stearate, which is a fuel additive, should be taken into account. The model blender considered in this article contained a mixture of 33 wt% PuO$$_{2}$$-enriched MOX, depleted UO$$_{2}$$ and zinc-stearate in a shape of an upside-down truncated cone, which was surrounded by 30 cm-thick polyethylene. For a limitation of the number of calculation cases, the fissile plutonium mass of the mixture was fixed to 98 kg, and the total concentration of MOX and UO$$_{2}$$ was fixed to 4.0 g/cm$$^{3}$$. The most conservative fuel distribution in the aspect of nuclear criticality safety under these constraints was calculated with a two-dimensional optimum fuel distribution code OPT-TWO, so that the importance distribution of MOX and that of zinc-stearate should be individually flattened by conserving the mass of each component. The OPT-TWO calculation was followed by criticality calculation performed with the MCNP code to obtain the neutron multiplication factor of the fuel in the optimum fuel distribution. The most conservative fuel distribution obtained in this research was typically depicted as a shell of zinc-stearate embedded into the central MOX region surrounded by the peripheral UO$$_{2}$$ region. An increase in the neutron multiplication factor was found 25% at most; non-uniformity of plutonium enrichment concentration and that of zinc-stearate concentration contributed to it in almost equal and independent ways.

Journal Articles

Lattice dynamics of LaFeAsO$$_{1-x}$$F$$_x$$ and PrFeAsO$$_{1-y}$$ via inelastic X-ray scattering and first-principles calculation

Fukuda, Tatsuo; Baron, A. Q. R.*; Shamoto, Shinichi; Ishikado, Motoyuki; Nakamura, Hiroki; Machida, Masahiko; Uchiyama, Hiroshi*; Tsutsui, Satoshi*; Iyo, Akira*; Kito, Hijiri*; et al.

Journal of the Physical Society of Japan, 77(10), p.103715_1 - 103715_4, 2008/10

 Times Cited Count:42 Percentile:83.23(Physics, Multidisciplinary)

The lattice dynamics of LaFeAsO$$_{1-x}$$F$$_x$$ ($$x$$=0, 0.1) and PrFeAsO$$_{1-y}$$ ($$ysim$$0.1) are investigated using inelastic X-ray scattering. Measurements of powder samples provide an approximation to the phonon DOS, while dispersion is measured from a single crystal of PrFeAsO$$_{1-y}$$. A model that agrees reasonably well with all of the data at room temperature is built from results of ab-initio calculations by reducing the strength of the Fe-As bond by 30%.

Journal Articles

Progress in R&D efforts on the energy recovery linac in Japan

Sakanaka, Shogo*; Ago, Tomonori*; Enomoto, Atsushi*; Fukuda, Shigeki*; Furukawa, Kazuro*; Furuya, Takaaki*; Haga, Kaiichi*; Harada, Kentaro*; Hiramatsu, Shigenori*; Honda, Toru*; et al.

Proceedings of 11th European Particle Accelerator Conference (EPAC '08) (CD-ROM), p.205 - 207, 2008/06

Future synchrotron light sources based on the energy-recovery linacs (ERLs) are expected to be capable of producing super-brilliant and/or ultra-short pulses of synchrotron radiation. Our Japanese collaboration team is making efforts for realizing an ERL-based hard X-ray source. We report recent progress in our R&D efforts.

Journal Articles

Current status of spent fuel isotopic composition database SFCOMPO and related technical development by JAEA

Suyama, Kenya; Okuno, Hiroshi; Uchiyama, Gunzo

Need for Post Irradiation Experiments to Validate Fuel Depletion Calculation Methodologies, p.151 - 156, 2006/12

In the field of criticality safety evaluation of spent fuels, Japan Atomic Energy Agency (former Japan Atomic Energy Research Institute, JAERI) has carried out continuous research and development. The effort includes obtaining isotopic composition data of spent nuclear fuels by the post irradiation examinations (PIE) for spent fuels irradiated in light water reactors and developing burnup calculation code system SWAT and new libraries for ORIGEN2 code adopting latest nuclear data libraries. JAERI had developed isotopic composition database SFCOMPO. This report describes current status of SFCOMPO and a result of technical developments of burnup credit in JAEA, i.e. re-evaluation of burnup values of PIE data taken at JAERI.

Journal Articles

Current status and potential needs of burn-up credit in Japan

Suyama, Kenya; Okuno, Hiroshi; Uchiyama, Gunzo; Yamamoto, Toru*

Need for Post Irradiation Experiments to Validate Fuel Depletion Calculation Methodologies, p.31 - 34, 2006/12

In Japan, burnup credit (BUC) has already been introduced into the criticality safety evaluation of Spent Nuclear Fuel (SNF) receiving pools and dissolver at Rokkasho Reprocessing Plant (RRP). BUC in other fuel cycle facilities including SNF transport is not considered. This is because the pressure of accumulation of SNF in Japan is decreased for a while since (1) the operation of spent fuel storage pools in RRP and (2) proposal of construction of an interim storage facility using dry-type metal casks by Recyclable-Fuel Storage Company (RFS) in Aomori. However, potential demands for adoption of BUC and improvement of related techniques have been still high. The technical development related to BUC is in progress continuously in the field of burnup analysis as post irradiation examinations (PIE) and reactor physics experiments. This concludes that BUC is an attractive concept and further adoption in spent fuel management process is expected in Japan.

Journal Articles

Energy spectra of electrons induced by MeV atom clusters

Kudo, Hiroshi*; Iwasaki, Wataru*; Uchiyama, Rumi*; Tomita, Shigeo*; Shima, Kunihiro*; Sasa, Kimikazu*; Ishii, Satoshi*; Narumi, Kazumasa; Naramoto, Hiroshi; Saito, Yuichi; et al.

Japanese Journal of Applied Physics, Part 2, 45(22), p.L565 - L568, 2006/06

 Times Cited Count:14 Percentile:47.16(Physics, Applied)

The first observation of the energy distribution of electrons emitted from solids bombarded by MeV atom clusters is reported. In the backward direction, using graphite and Si bombarded by C$$_{n}$$$$^{+}$$ and Al$$_{n}$$$$^{+}$$ (n $$leq$$ 8), an appreciable suppression of electron emission has been observed at electron energies lower than $$sim$$10 eV. Electron yield per atom decreases with increasing n, and becomes less than 50% at n $$geq$$ 3, relative to the case of n = 1. The experimental results cannot be explained in terms of projectile stopping cross sections nor by the clearing-the-way effect. It is probable that the suppressed electron emission is a result of the suppression of the transport or surface transmission of the produced low-energy electrons, rather than of the suppression of ionization.

JAEA Reports

Report of investigation on malfunction of reserved shutdown system in HTTR

Hamamoto, Shimpei; Iigaki, Kazuhiko; Shimizu, Atsushi; Sawahata, Hiroaki; Kondo, Makoto; Oyama, Sunao; Kawano, Shuichi; Kobayashi, Shoichi; Kawamoto, Taiki; Suzuki, Hisashi; et al.

JAEA-Technology 2006-030, 58 Pages, 2006/03

JAEA-Technology-2006-030.pdf:10.69MB

During normal operation of High Temperature engineering Test Reactor (HTTR) in Japan Atomic Energy Agency (JAEA), the reactivity is controlled by the Control Rods (CRs) system which consists of 32 CRs (16 pairs) and 16 Control Rod Drive Mechanisms (CRDMs). The CR system is located in stand-pipes accompanied by the Reserved Shutdown System (RSS). In the unlikely event that the CRs fail to be inserted, the RSS is provided to insert B$$_{4}$$C/C pellets into the core. The RSS shall be designed so that the reactor should be held subcriticality from any operation condition by dropping in the pellets. The RSS consists of B$$_{4}$$C/C pellets, hoppers which contain the pellets, electric plug, driving mechanisms, guide tubes and so on. In accidents when the CRs cannot be inserted, an electric plug is pulled out by a motor and the absorber pellets fall into the core by gravity. A trouble, malfunction of one RSS out of sixteen, occurred during a series of the pre-start up checks of HTTR on February 21, 2005. We investigated the cause of the RSS trouble and took countermeasures to prevent the issue. As the result of investigation, the cause of the trouble was attributed to the following reason: In the motor inside, The Oil of grease of the multiplying gear flowed down from a gap of the oil seal which has been deformed and was mixed with abrasion powder of brake disk. Therefore the adhesive mixture prevented a motor from rotating.

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