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Urakawa, Satoru*; Inoue, Toru*; Hattori, Takanori; Sano, Asami; Kohara, Shinji*; Wakabayashi, Daisuke*; Sato, Tomoko*; Funamori, Nobumasa*; Funakoshi, Kenichi*
Minerals (Internet), 10(1), p.84_1 - 84_13, 2020/01
Times Cited Count:9 Percentile:62.38(Geochemistry & Geophysics)The structure of hydrous amorphous SiO is fundamental to investigate the effects of water on the physicochemical properties of oxide glasses and magma. The hydrous SiO glass with 13 wt.% DO was synthesized under high-pressure and high-temperature conditions and its structure was investigated by small angle X-ray scattering, X-ray diffraction, and neutron diffraction experiments at pressures of up to 10 GPa and room temperature. This hydrous glass is separated into a SiO rich major phase and a DO rich minor phase. Medium-range order of the hydrous glass shrinks compared to the anhydrous SiO glass due to disruption of SiO linkage by formation of Si-OD deuterioxyl, while the pressure response is similar. Most of DO molecules are in the small domains and hardly penetrate into SiO major phase.
*; *; *
JNC TJ8400 2000-018, 79 Pages, 2000/02
As a basic research for geological disposal of high-level radioactive wastes, diffusion behavior of radionuclides and corrosion behavior of overpack materials in clay buffer materials (bentonite) were studied. In the study on the diffusion behavior of radionuclides, basal spacing and water content were determined for water saturated, compacted Na-montmorillonite that is major clay mineral of bentonite. The apparent diffusion coefficients of Na, Sr, Cs and Cl ions and their activation energies were also determined at different dry densities of montmorillonite. For all kinds of ions, the activation energies were found to increase as the dry density increased. These findings suggest that the diffusion mechanism of ions in compacted montmorillonite changed with increasing dry density. As a reasonable explanation for the changes in the activation energy, we proposed a multiprocess diffusion model, in which predominant diffusion process is considered to change from pore water diffusion to interlayer diffusion via surface diffusion when the dry density increases. The Na-montmorillonite is expected to alter by the ion exchange with Ca ions, which could be introduced from groundwater and/or cementitious materials in a repository. The apparent diffusion coefficients of Na and Cs ions and their activation energies were studied for Na/Ca montmorillonite mixtures in order to know the effect of this kind of alteration on the diffusion behavior of ions. It was found that the alteration of montmorillonite affected diffusion coefficients and the activation energies for both kinds of cations. These effects cannot be explained only by the pore water diffusion. The multiprocess diffusion model proposed in this study is suggested as the most reasonable explanation for the effects. The oxidation behavior of pyrite in bentonite during drying process was studied for understanding corrosion behavior of overpack materials in bentonite. There ...
*
JNC TJ8400 2000-017, 74 Pages, 2000/02
The report concerns the improvement of the method measuring thermal conductivity of buffer materials using a thermistor probe and the measurement of thermal conductivity of compacted bentonites and mixtures of bentonite and silica sand using the proposed method measuring thermophysical properties. The method measuring thermal conductivity is improved in accuracy and the apparatus is improved so as to measure easily with more short time. The calculated values of the conventional correlations predicting thermal conductivity of bentonite and mixture were compared with the exising and present data of thermal conductivity of bentonites and mixtures. The correlation proposed by Sakashita and Kumada can predict the best fitted values with the data of the bentonites and Fricke and Bruggeman correlations are fitted with the data for the mixtures with practical accuracy.
Sumita, Junya; Sawa, Kazuhiro; Mogi, Haruyoshi; ; Kitami, Takayuki; Akutsu, Yoichi; *; *; *
JAERI-Research 99-054, p.41 - 0, 1999/09
no abstracts in English
Imai, Hisashi*; Nishida, Kaoru*; *; Amemiya, Kiyoshi*; Lin, Weiren*
PNC TJ1449 98-004, 231 Pages, 1998/02
None
*; *; *; Iida, Takao*; *; *
PNC TJ1545 93-005, 36 Pages, 1993/03
no abstracts in English
*
PNC TJ1545 92-005, 51 Pages, 1992/03
no abstracts in English
Taisei Corporation*; Shimizu Corporation*; Obayashi Corporation*; Kajima Corporation*
PNC TJ1449 91-005, 256 Pages, 1991/01
None
; *; ;
Radioact.Waste Manage.Nucl.Fuel Cycle, 7(3), p.303 - 316, 1986/00
no abstracts in English
; Katakai, Akio; ;
Sep.Sci.Technol., 21(3), p.299 - 313, 1986/00
Times Cited Count:72 Percentile:95.24(Chemistry, Multidisciplinary)no abstracts in English
; Kaetsu, Isao
J.Membr.Sci., 17, p.71 - 77, 1984/00
Times Cited Count:2 Percentile:44.78(Engineering, Chemical)no abstracts in English
;
JAERI-M 8706, 20 Pages, 1980/02
no abstracts in English
*; Machi, Sueo;
JAERI-M 6329, 22 Pages, 1975/12
no abstracts in English
Suzuki, Seiya; Nakayoshi, Akira; Okamura, Nobuo; Watanabe, Masayuki; Koizumi, Kenji
no journal, ,
no abstracts in English
Ishii, Katsunori; Segawa, Tomoomi; Kawaguchi, Koichi
no journal, ,
The Japan Atomic Energy Agency is developing a simplified mixed oxide (MOX) fuel fabrication process. In this process, a wet granulator improves the flowability of MOX raw powder for the pelletizing process 1, 2). Following this granulation step, the formed granules have moisture content of approximately 10 wt.%. To adhere to the acceptance standards regarding moisture content for the fuel pellet fabrication step, drying the granules under the moisture content of 1 wt.% using a dryer is necessary. To maintain the granule shape during powder handling and shaker process of a pressing machine, the granules must be adjusted to enough crushing strength. However, the relation between dry conditions and granule crushing strength has not been reported. Therefore, to estimate the appropriate heating conditions of the dryer, we investigated the influence of varying heating conditions on moisture content and granule crushing strength.
Kumagai, Yuta; Koshizaka, Akiko*; Oka, Toshitaka; Kumagai, Jun*; Ikarugi, Riko; Kitatsuji, Yoshihiro
no journal, ,
We have launched a research project aiming development of an evaluation method for radiolytic H production from radioactive waste containing -emitting radionuclides. As a first step of the project, we set up an analysis system that can detect very low concentration of H anticipated in the waste analysis. The H production from radioactive wastes is generally very slow. Therefore, the analysis of the radiolytic H requires high sensitivity. We estimated the H production rate from a typical waste, and it gave the rate as low as 100 ppb per 24 hours. In order to detect such a low concentration of H, a semiconductor-type gas sensor was employed in our analysis system. We have tested our system with standard H gas and the result indicated that the lower limit of our system was around 40 ppb.