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hydridosilicate at high pressures; A Bridge to BaSiH
polyhydrideBeyer, D. C.*; Spektor, K.*; Vekilova, O. Y.*; Grins, J.*; Barros Brant Carvalho, P. H.*; Leinbach, L. J.*; Sannemo-Targama, M.*; Bhat, S.*; Baran, V.*; Etter, M.*; et al.
ACS Omega (Internet), 10(15), p.15029 - 15035, 2025/04
Times Cited Count：0 Percentile：0.00(Chemistry, Multidisciplinary)Hydridosilicates featuring SiH octahedral moieties represent a rather new class of compounds with potential properties relating to hydrogen storage and hydride ion conductivity. Here, we report on the new representative BaSiH obtained from reacting the Zintl phase hydride BaSiH
with H
fluid at pressures above 4 GPa and subsequent decompression to ambient pressure. It consists of complex SiH
ions, which are octahedrally coordinated by Ba
counterions. The arrangement of Ba and Si atoms deviates only slightly from an ideal fcc NaCl structure. IR and Raman spectroscopy showed SiH bending and stretching modes in the ranges 800-1200 and 1400-1800 cm
, respectively. BaSiH is thermally stable up to 95
C above which decomposition into BaH and Si takes place. DFT calculations indicated a direct band gap of 2.5 eV. The discovery of BaSiH consolidates the compound class of hydridosilicates, accessible from hydrogenations of silicides at gigapascal pressures (
10 GPa). The structural properties of BaSiH suggest that it presents an intermediate (or precursor) for further hydrogenation at considerably higher pressures to the predicted superconducting polyhydride BaSiH.
Licensing Application Group, Fuels and Materials Department
JAEA-Testing 2024-002, 20 Pages, 2024/08
JAEA-Testing-2024-002.pdf:1.46MB
The contamination accident occurred at Plutonium Fuel Research Facility (PFRF) in Japan Atomic Energy Agency (JAEA) Oarai Research and Development Institute on June 6, 2017. During the work of opening the fuel storage container and checking the properties of the contents, the plastic bag that double-packed the inner container burst. The scattering of the fuels contaminated the work room and exposed the worker. The cause of the plastic bag burst was that the enclosed epoxy resin was decomposed by 
-rays and the internal pressure increased due to the generated hydrogen gas. The 54 storage containers containing plutonium held at PFRF also at risk of increasing internal pressure. Therefore, an opening inspection was conducted to confirm the contents of the storage container in the hot cell. In addition, the contents of storage containers that may generate gas were stabilized. We are planning to transport the fuel storage containers out to another facility for the decommission of PFRF. The other 9 storage containers include oxide raw material powder: Pu + 
U in excess of 220 g. In order to decrease to less than 220 g (the limit of transport cask), the metal inner containers in the storage container were taken out and repacked in another storage container. This report describes advance measures such as permit application and the details of about storage container opening inspection and metal inner container repacking.
Ishitsuka, Etsuo; Nagasumi, Satoru; Hasegawa, Toshinari; Kawai, Hiromi*; Wakisaka, Shinji*; Nagase, Sota*; Nakamura, Kento*; Yaguchi, Hiroki*; Ishii, Toshiaki; Nakano, Yumi*; et al.
JAEA-Technology 2024-008, 23 Pages, 2024/07
JAEA-Technology-2024-008.pdf:1.69MB
Five people from three universities participated in the 2023 summer holiday practical training with the theme of "Technical development on HTTR". The participants practiced the analysis of HTTR core, the analysis of behavior on loss of forced cooling test, the analysis of Iodine deposition behavior in primary cooling system and the feasibility study of energy storage system for HTGRs. In the questionnaire after this training, there were impressions such as that it was useful as a work experience and some students found it useful for their own research. These impressions suggest that this training was generally evaluated as good.
Kawahara, Takahiro; Suda, Shoya; Fujikura, Toshiki; Masai, Seita; Omori, Kanako; Mori, Masakazu; Kurosawa, Tsuyoshi; Ishihara, Keisuke; Hoshi, Akiko; Yokobori, Tomohiko
JAEA-Technology 2023-020, 36 Pages, 2023/12
JAEA-Technology-2023-020.pdf:2.79MB
We have been storing drums containing radioactive waste (radioactive waste packages) at waste storage facilities. We have been managing radioactive waste packages along traditional safety regulations. However, over 40 years has passed from a part of them were brought in pit-type waste storage facility L. Most of them are carbon steel 200 L drums, and surface of them are corroded. For better safety management, we started to take drums out from the pit and inspect them in FY 2019. After each inspection, we repair them or remove the contents of the drum and refill new drums if necessary. In this report, we will introduce the planning, the review of the plan, and the trial operation of this project.
Cho, S.*; Suh, H.*; Im, S.*; Kim, G.*; Kanematsu, Manabu*; Morooka, Satoshi; Machida, Akihiko*; Shobu, Takahisa; Bae, S.*
Construction and Building Materials, 409, p.133866_1 - 133866_20, 2023/12
Times Cited Count：13 Percentile：85.36(Construction & Building Technology) inferred from muon studyKadono, Ryosuke*; Hiraishi, Masatoshi*; Okabe, Hirotaka*; Koda, Akihiro*; Ito, Takashi
Journal of Physics; Condensed Matter, 35(28), p.285503_1 - 285503_13, 2023/07
Times Cited Count：1 Percentile：11.20(Physics, Condensed Matter)Hirooka, Shun; Nakamichi, Shinya; Matsumoto, Taku; Tsuchimochi, Ryota; Murakami, Tatsutoshi
Frontiers in Nuclear Engineering (Internet), 2, p.1119567_1 - 1119567_7, 2023/03
Storage of plutonium (Pu)-containing materials requires extremely strict attention in terms of physical safety and material accounting. Despite the emphasized importance of storage management, only a few reports are available in the public, e.g., experience in PuO
storage in the UK and safety standards in the storage of Pu-containing materials in the US. Japan also stores more U-Pu mixed oxide (MOX) mostly in powder form. Adopting an appropriate storage management is necessary depending on the characteristics of MOX items such as raw powder obtained by reprocessing of spent Light Water Reactor fuels, research and development on the remains of fuel fabrication, which can contain organic materials, and dry-recycled powder during fuel fabrication. Stagnation in fuel fabrications and experience in degradation of MOX containers during extended period of storage have led to the review of the storage method in the Plutonium Fuel Development Center in Japan Atomic Energy Agency. The present work discusses the various nuclear materials, storage methods, experience in degradation of containers that occur during storage, and strategies for future long-term storage.
Kawaguchi, Munemichi
Journal of Physical Chemistry C, 125(22), p.11813 - 11819, 2021/06
Times Cited Count：5 Percentile：24.25(Chemistry, Physical)Isothermal and constant heating thermogravimetry-differential thermal analysis (TG-DTA) and Fourier transform infrared spectrometer (FTIR) measurements have been performed for pre- and post-fired sodium hydride (NaH) in the temperature range of 500-700 K, respectively. Temperature dependence of NaH thermal decomposition rates obtained by the isothermal TGs showed an inflection point at around 620 K, which was caused by two kinds of hydrogen states (rapid diffusing and immobile hydrogen). In the FTIR spectra for the NaH and sodium (Na), the specific signals were observed at around 873.4, 1010.4, 1049.5 and 1125.7 cm, and the integrated values of FTIR signals for post-fired NaH at below 550K and at above 698 K were comparable to those for pre-fired NaH and Na, respectively. Those for post-fired NaH at 602-667 K were the intermediate values of the pre-fired NaH and Na, which denoted that the Na-Na bonds haven't grown sufficiently and the hydrogen coexisted in metallic Na. In order to predict the practical kinetics of NaH thermal decomposition reaction, we suggested the simple kinetics model which assumed two kinds of rapidly diffusing and immobile hydrogen states. The simulation results revealed the inflection point in temperature dependence of the thermal decomposition rates accordingly because the transition from immobile hydrogen to rapid diffusing hydrogen crosses over at around 620 K.
Task Force on Research Strategy for Debris of Fukushima Daiichi Nuclear Power Station
JAEA-Review 2020-055, 171 Pages, 2020/12
JAEA-Review-2020-055.pdf:5.66MB
Design, planning and control of debris-related processes, namely retrieval, storage management, processing and disposal of the debris, are required for the safe and steady decommissioning of Fukushima Daiichi Nuclear Power Station (1F). Status inside primary containment vessel of 1F must be known by the PCV investigation and fuel debris sample analysis. Continuous updating and improvement of the process design are important through ascertainment of the cause of the accident. The roadmap for the 1F decommissioning have shown the milestone of commencement of trial retrieval of fuels debris within 2021, which indicates the analysis of fuel debris sample begin in earnest. This report recommends required debris analysis in relation with issues for the retrieval, storage management, processing and disposal, and ascertainment of the cause of the 1F accident. Practical analysis plan is expected to be prepared based on this report.
Sakai, Kenji; Oi, Motoki; Teshigawara, Makoto; Naoe, Takashi; Haga, Katsuhiro; Watanabe, Akihiko*
Journal of Neutron Research, 22(2-3), p.337 - 343, 2020/10
For operating a spallation neutron source and a muon target safely and efficiently, a general control system (GCS) operates within Materials and Life Science Experimental Facility (MLF). GCS administers operation and interlock processes of many instruments under various operation status. Since the first beam injection in 2008, it has operated stably without any serious troubles for more than ten years. GCS has a data storage server storing operational data on status around target stations. It has functioned well to detect and investigate unusual situations by checking data in this server. For continuing stable operation of MLF in future, however, introduction of abnormality sign determination system (ASDS) will be necessary for picking up potential abnormalities of target stations caused by radiation damages, time-related deterioration and so on. It will judge abnormalities from slight state transitions of target stations based on analysis with various operational data throughout proton beams, target stations, and secondary beams during long-term operations. This report mentions present status of GCS, conceptual design of ASDS, and installation of an integral data storage server which can deal with various data for ASDS integrally.
Task Force on Writing Textbook of Nuclear Fuel Materials
JAEA-Review 2020-007, 165 Pages, 2020/07
JAEA-Review-2020-007.pdf:6.63MB
The present textbook was written by Task Force on Writing Textbook of Nuclear Fuel Materials at the Nuclear Science Research Institute in order to improve technological abilities of engineers and researchers who handle nuclear fuel materials. The taskforce consists of young and middle class engineers each having certification for chief engineer of nuclear fuel. The present textbook mainly deals with uranium and plutonium, and shows their nuclear properties, physical and chemical properties, and radiation effects on materials and human body. It also presents basic matters for safety handling of nuclear fuel materials, such as handling of nuclear fuel materials with hood and glovebox, important points in storage and transportation of nuclear fuel materials, radioactive waste management, radiation safety management, and emergency management. Furthermore, incident cases at domestic and foreign nuclear fuel materials facilities are compiled to learn from the past.
Task Force on Research Strategy for Debris of Fukushima Daiichi Nuclear Power Station
JAEA-Review 2020-004, 140 Pages, 2020/05
JAEA-Review-2020-004.pdf:4.22MB
Design, planning and control of debris-related processes, namely retrieval, storage management, processing and disposal of the debris, are required for the safe and steady decommissioning of Fukushima Daiichi Nuclear Power Station (1F). Status inside primary containment vessel of 1F must be known by the PCV investigation and fuel debris sample analysis. Continuous updating and improvement of the process design are important through ascertainment of the cause of the accident. The roadmap for the 1F decommissioning have shown the milestone of commencement of trial retrieval of fuels debris within 2021, which indicates the analysis of fuel debris sample begin in earnest. This report recommends required debris analysis in relation with issues for the retrieval, storage management, processing and disposal, and ascertainment of the cause of the 1F accident. Practical analysis plan is expected to be prepared based on this report.
Marufuji, Takato; Sato, Takumi; Ito, Hideaki; Suzuki, Hisashi; Fujishima, Tadatsune; Nakano, Tomoyuki
JAEA-Technology 2019-006, 22 Pages, 2019/05
JAEA-Technology-2019-006.pdf:2.84MB
Radioactive contamination incident occurred at Plutonium Fuel Research Facility (PFRF) in Oarai Research and Development Institute, Japan Atomic Energy Agency on June 6, 2017. During inspection work of storage container containing nuclear fuel materials, the PVC bag packaging in the storage container ruptured when a worker opened the lid in the hood, and a part of contents was spattered over the room. The cause of the increase of internal pressure of the storage container was gas generation by alpha radiolysis of the epoxy resin mixed with nuclear fuel materials. Opening inspection of about 70 similar containers stored in PFRF has been planned to confirm the condition of the contents and to stabilize the stored materials containing organic compounds. For safe and reliable open inspection of the storage containers with high internal pressure in the glove box, it is necessary to develop a pressure-resistant chamber in which the storage containers are opened and the contents are inspected under gastight condition. This report summarizes the concerns and countermeasures of the chamber design and the design results of the chamber.
Restoration Activity Team for the PFRF Contamination Incident
JAEA-Review 2019-001, 58 Pages, 2019/03
JAEA-Review-2019-001.pdf:10.74MB
The contamination accident occurred in a laboratory room (Room No.108) of Plutonium Fuel Research Facility (PFRF) in Japan Atomic Energy Agency (JAEA), Oarai Research and Development Institute on June 6, 2017. The polyvinyl chloride (PVC) bags burst just after the lid of one storage container was opened during the inspection of storage containers for U and Pu in the ventilation hood. At that time, part of nuclear materials in the storage container were scattered all over the room. Five workers in the room were subjected to plutonium contamination, which resulted in internal exposure. In order to restore the Room No.108 of PFRF, the Restoration Activity Team organized in JAEA carried out the decontamination work after the investigation of the contamination level in the room. The team decontaminated the surface of walls, ceiling, gloveboxes and other experimental instruments. Depending on the contamination distribution and installation state of the instruments, suitable decontamination methods were selected. In addition to the manual wiping using wet clothes, the exfoliation method using a strippable paint was applied for constricted areas. As a result, the loose alpha-contamination level fell below the detection limit throughout the room. On the other hand, the fixed contamination was covered with plastic sheets after the decontamination by a strippable paint. We hope that the restoration activity described in this report will provide useful information for the management of decommissioning facilities, especially for facilities treating alpha-radioactive materials such as plutonium.
Yamano, Hidemasa; Kurisaka, Kenichi; Nishino, Hiroyuki; Okano, Yasushi; Naruto, Kenichi*
Proceedings of 12th International Topical Meeting on Nuclear Reactor Thermal-Hydraulics, Operation and Safety (NUTHOS-12) (USB Flash Drive), 15 Pages, 2018/10
Spent fuels are transferred from a reactor core to a spent fuel pool through an external vessel storage tank (EVST) filled with sodium in sodium-cooled fast reactors in Japan. This paper describes identification of dominant accident sequences leading to fuel failure, which was achieved through probabilistic risk assessment for the EVST designed for a next sodium-cooled fast reactor plant system in Japan to improve the EVST design. The safety strategy for the EVST involves whole core refueling (early transfer of all core fuel assemblies into the EVST) assuming a severe situation that results in sodium level reduction leading finally to the top of the reactor core fuel assemblies in a long time. This study introduces the success criteria mitigation along the decay heat decrease over time. Based on the design information, this study has carried out identification of initiating events, event and fault tree analyses, a probability analysis for human error, and quantification of accident sequences. The fuel damage frequency of the EVST was evaluated to be approx. 10
/year. The dominant accident sequence resulted from the static failure and human error for the switching from the stand-by to operation mode in the three stand-by cooling circuits after loss of one circuit for refueling heat removal operation as an initiating phase.
Yamano, Hidemasa; Naruto, Kenichi*; Kurisaka, Kenichi; Nishino, Hiroyuki; Okano, Yasushi
Proceedings of 26th International Conference on Nuclear Engineering (ICONE-26) (Internet), 9 Pages, 2018/07
Spent fuels are transferred from a reactor core to a spent fuel pool through an external vessel storage tank (EVST) filled with sodium in sodium-cooled fast reactors in Japan. This paper describes identification of dominant accident sequences leading to fuel failure by conducting probabilistic risk assessment for EVST designed for a next sodium-cooled fast reactor plant system in Japan to improve the EVST design. Based on the design information, this study has carried out identification of initiating events, event and fault tree analyses, human error probability analysis, and quantification of accident sequences. Fuel damage frequency of the EVST was evaluated approx. 10
/year in this paper. By considering the secondary sodium freezing, the fuel damage frequency was twice increased. The dominant accident sequence resulted from the common cause failure of the damper opening and/or the human error for the switching from the stand-by to the operation mode in the three stand-by cooling circuits. The importance analyses have indicated high risk contributions.
Sano, Yuichi; Ashida, Takashi
JAEA-Review 2017-021, 180 Pages, 2017/11
JAEA-Review-2017-021.pdf:86.98MB
Collaborative Laboratories for Advanced Decommissioning Science (CLADS) is responsible to promote international cooperation in the R&D activities on the decommissioning of Fukushima Daiichi Nuclear Power Station and to develop the necessary human resources. CLADS held the Research Conference on Cementitious Composites in Decommissioning and Waste Management (RCWM2017) on 20th and 21st June, 2017. This report compiles the abstracts and the presentation materials in the above conference.
Yamano, Hidemasa; Naruto, Kenichi*; Kurisaka, Kenichi; Nishino, Hiroyuki; Okano, Yasushi
Proceedings of Asian Symposium on Risk Assessment and Management 2017 (ASRAM 2017) (USB Flash Drive), 3 Pages, 2017/11
Spent fuels are transferred from a reactor core to a spent fuel pool through an external vessel storage tank (EVST) filled with sodium in sodium-cooled fast reactors in Japan (JSFR). The objective of this study is to identify dominant accident sequences leading to fuel failure by conducting PRA for EVST. The EVST heat removal system in JSFR consists of four independent loops with for primary and secondary ones. Based on the JSFR design information, this study has identified initiating events, event and /fault tree analyses, human reliability analysis, and quantification of accident sequences. Fuel damage frequency of the EVST was evaluated approx. 10 /year in this paper. The main contributor of the fuel damage frequency is the loss of heat removal function of the cooling system. The dominant initiating event was the loss of one circuit of normal heat removal operation.
Motooka, Takafumi; Yamagishi, Isao
JAEA-Review 2017-004, 157 Pages, 2017/03
JAEA-Review-2017-004.pdf:48.18MB
Collaborative Laboratories for Advanced Decommissioning Science (CLADS) is responsible to promote international cooperation in the R&D activities on the decommissioning of Fukushima Daiichi Nuclear Power Station and to develop the necessary human resources. CLADS held the Research Conference on Post-accident Waste Management Safety (RCWM2016) was held on November 7th, 2016 and the Technical Seminar on Safety Research for Radioactive Waste Storage was held on November 8th, 2016. This report compiles the abstracts and the presentation materials in the above conference and seminar.
Abe, Hiroshi; Tokuhira, Shinnosuke*; Uchida, Hirohisa*; Oshima, Takeshi
Nuclear Instruments and Methods in Physics Research B, 365(Part A), p.214 - 217, 2015/12
no abstracts in English
