検索対象:     
報告書番号:
※ 半角英数字
 年 ~ 
 年
検索結果: 110 件中 1件目~20件目を表示

発表形式

Initialising ...

選択項目を絞り込む

掲載資料名

Initialising ...

発表会議名

Initialising ...

筆頭著者名

Initialising ...

キーワード

Initialising ...

発表言語

Initialising ...

発行年

Initialising ...

開催年

Initialising ...

選択した検索結果をダウンロード

論文

Fused-ring nanothread synthesized via high-pressure polymerization of naphthalene

Fei, Y.*; Wang, Y.*; Zhang, J.*; Liu, J.*; Zhao, Z.*; 服部 高典; 阿部 淳*; Dong, X.*; Mao, H.-K.*; Zheng, H.*; et al.

Chemistry; A European Journal, 32(31), p.e71096_1 - e71096_11, 2026/08

 被引用回数:0 パーセンタイル:0.00(Chemistry, Multidisciplinary)

カーボンナノスレッド(CNThs)は、卓越した機械的特性を備えた一次元飽和炭素ナノ材料である。多環芳香族炭化水素(PAHs)は、高圧下において、機械的性能が向上した、より太い多環状CNThsを形成すると期待されている。本研究では、最も単純なPAHであるナフタレンの高圧重合について、複数の最先端手法を用いて体系的に調査した。ナフタレン分子はヘリンボーン状に積層し、20GPa以上ではa-b方向に沿って[4+2]環化付加反応を起こし、一次元CNThを生成した。多くのCNThの形成とは対照的に、CNThの核生成は加圧中に起こりその成長は減圧中に進行するが、これはヘリンボーン状に積層した芳香族化合物に普遍的に見られる現象であると考えられる。得られたCNTh結晶の単位格子が決定され、生成物であるCNThの可能な構造も提案された。本研究は、高圧下におけるナフタレンの重合特性を明らかにし、滑り角が重合経路を決定する上で重要な役割を果たすことを示している。

論文

Ductile-to-brittle transition in aluminum alloys

Zhou, D.*; Zhang, X.*; Pang, X.*; Zhao, Z.*; Chen, X.*; Wei, S.*; Yang, C.*; Gong, W.; Harjo, S.; Li, R.*; et al.

Materials Research Letters (Internet), 14(6), p.689 - 698, 2026/06

 被引用回数:1 パーセンタイル:76.28(Materials Science, Multidisciplinary)

Here, we investigated the room-temperature (298 K) and cryogenic-temperature (77 K) mechanical behaviors of binary Al-Mg alloys over a wide range of Mg concentrations (2.8-13.1 at.%). A ductile-to-brittle transition was observed at 77 K as the Mg content increased from 7.5 to 13.1 at.%, accompanied by a significant decrease in impact energy from 161 J to 14 J. Through detailed theoretical calculations and experimental observations, this composition-dependent transition was found to be primarily associated with Mg segregation-induced grain boundary (GB) expansion and charge density depletion at the GB. These findings not only address the growing demand for durable lightweight materials for low-temperature applications, but also provide insights into the design of ultralight aerospace structural materials capable of withstanding the harsh environments encountered in space exploration.

論文

Interplay of dynamic strain aging and dynamic precipitation in the Portevin-Le Ch$^{a}$telier effect in an Al-Mg-Zn-based crossover aluminum alloy

Zhang, X.*; Li, Y.*; Wei, S.*; Guo, H.*; He, Z.*; Yang, C.*; Gong, W.; Harjo, S.; Zhou, D.*; Li, Z.*; et al.

Acta Materialia, 308, p.121990_1 - 121990_18, 2026/04

 被引用回数:8 パーセンタイル:99.16(Materials Science, Multidisciplinary)

Dynamic strain aging (DSA) causes serrated flow, known as the Portevin-Le Ch$^{a}$telier (PLC) effect, through interactions between solute atoms and dislocations. In this study, tensile tests on an Al-Mg-Zn crossover solid-solution alloy revealed that DSA and strain-induced dynamic precipitation jointly control serration behavior. At low strain rates, DSA-assisted precipitation produced Type C serrations, whereas high strain rates suppressed precipitation and promoted Type A serrations. High-energy X-ray diffraction and TEM analyses showed that screw dislocations dominated early deformation and governed plastic flow localization through cross-slip. Frequent cross-slip at high strain rates generated dislocation microbands responsible for Type A serrations, highlighting the primary role of screw dislocations rather than edge dislocations. A constitutive model incorporating DSA-assisted strengthening successfully predicted flow behavior over a wide strain-rate range.

論文

Decay properties of new isotopes $$^{235}$$Bk and $$^{231}$$Am

Wang, J. G.*; Zhang, Z. Y.*; Andreyev, A. N.; 他33名*

Physics Letters B, 875, p.140365_1 - 140365_6, 2026/04

 被引用回数:2 パーセンタイル:81.50(Astronomy & Astrophysics)

ガス充填反跳分離器SHANS2を用いて、新同位体$$^{235}$$Bkと$$^{231}$$Amを調査した。これらの同位体は、$$^{197}$$Au($$^{40}$$Ar,2n)$$^{235}$$Bk反応によって合成された$$^{235}$$Bkの放射性崩壊系列の測定により同定された。またこれらの同位体の$$alpha$$線エネルギーと半減期が決定された。系統的な解析により、BkとAmの同位体に関する実験データと理論予測との間に大きな不一致があることが明らかになり、更なる調査の必要性が示唆された。

論文

Magnetic signature of chiral phonons revealed by neutron spectroscopy in ferrimagnetic Fe$$_{1.75}$$Zn$$_{0.25}$$Mo$$_{3}$$O$$_{8}$$

Bao, S.*; Liao, J.*; Huang, Z.*; Shangguan, Y.*; Ma, Z.*; Zhang, B.*; Cheng, S.*; Xu, H.*; Song, Z.*; Dong, S.*; et al.

Physical Review Letters, 136(9), p.096502_1 - 096502_8, 2026/03

 被引用回数:3 パーセンタイル:96.14(Physics, Multidisciplinary)

Lattice vibrations can carry angular momentum and magnetic moments under broken inversion or time-reversal symmetry, forming so-called chiral phonons. While such excitations have been explored in nonmagnetic systems via optical probes, their direct detection in magnetic materials and coupling to spin excitations remain largely unexplored. Here, using neutron spectroscopy, sensitive to both nuclear and magnetic scattering, we reveal the magnetic signature of chiral phonons in ferrimagnetic Fe$$_{1.75}$$Zn$$_{0.25}$$Mo$$_{3}$$O$$_{8}$$ with Curie temperature $$T_C sim 49$$ K. Below $$T_C$$, we observe enhanced magnetic scattering of phonons at small momenta, arising from strong magnon-phonon coupling. In addition, out-of-plane intensity modulation, phonon mode splitting, and field-induced Zeeman shifts are observed, all closely associated with the ferrimagnetic order. These features vanish above $$T_C$$, where phonon spectra are dominated by nuclear scattering. These observations demonstrate the existence of chiral phonons carrying substantial magnetic moments that directly contribute to magnetic scattering, and establish neutron spectroscopy as a powerful, momentum-resolved probe of their magnetic character.

論文

Spin excitation continuum from degenerate states in the mixed ferro-antiferromagnetic exchange system CeMgAl$$_{11}$$O$$_{19}$$

Gao, B.*; Chen, T.*; Liu, C.*; Klemm, M. L.*; Zhang, S.*; Ma, Z.*; Xu, X.*; Won, C.*; McCandless, G. T.*; Rao, K.*; et al.

Science Advances (Internet), 12(10), p.eaed7778_1 - eaed7778_7, 2026/03

 被引用回数:2 パーセンタイル:76.89(Multidisciplinary Sciences)

In the search for unconventional magnetism, exotic quantum states are characterized by a lack of order and a broad spin excitation continuum approaching zero temperature. We study the two-dimensional triangular-lattice effective spin-system CeMgAl$$_{11}$$O$$_{19}$$, which shows slight disorder but no magnetic ordering down to 100 millikelvin. Spin-wave analysis in the magnetic-field-polarized state determines the spin Hamiltonian featuring a mixed ferromagnetic-antiferromagnetic nearest-neighbor exchange interaction. This places the system near an exactly solvable point of the spin-triangular-lattice XXZ model with extensive ground-state degeneracy. In zero field, neutron spectroscopy reveals a prominent continuum; we show that this arises from an ensemble average of spin-wave spectra across the degenerate ground-state manifold. This demonstrates that the role of weak quenched disorder can be quantitatively constrained: It inhibits unique ground-state selection and stabilizes a local distribution within the degenerate manifold, yielding continuum-like spectra that necessitate a critical reevaluation of the experimental signatures of exotic quantum states.

論文

Shape evolution in neutron-rich Rh isotopes; First measurement of negative-parity isomers in $$^{117,119}$$Rh

Zhang, J. Z.*; Chen, Z. Q.*; Qu, T.*; Wang, Y. K.*; Li, Z. H.*; Orlandi, R.; 他62名*

Physics Letters B, 873, p.140144_1 - 140144_9, 2026/02

 被引用回数:0 パーセンタイル:0.00(Astronomy & Astrophysics)

At the RIKEN, $$beta$$-delayed $$gamma$$-ray spectroscopy studies were conducted on $$^{117}$$Rh and $$^{119}$$Rh, resulting in the world's first successful identification of a 1/2$$^-$$ isomer in these isotope, extending the energy difference between the 9/2$$^+$$ and 1/2$$^-$$ states up to neutron number $$N$$=74. Comparison of the new results with state-of-the-art calculations suggests that triaxial deformation plays a significant role in the evolution of the energy difference, indicating a shape transition from axially symmetric to triaxial deformation within the Rh isotopic series. These findings provide new insights into the structure of neutron-rich nuclei in the atomic number $$A sim 110$$ region, elucidating the interplay between triaxial deformation and shell evolution.

論文

Residual stress relief effect in gradient structural steel and remaining life evaluation under stochastic fatigue loads

Qin, T. Y.*; Hu, F. F.*; 徐 平光; Zhang, R.*; Su, Y. H.; Ao, N.*; Li, Z. W.*; 篠原 武尚; 菖蒲 敬久; Wu, S. C.*

International Journal of Fatigue, 202, p.109233_1 - 109233_16, 2026/01

 被引用回数:7 パーセンタイル:69.50(Engineering, Mechanical)

The surface induction-hardened S38C medium carbon steel shows a good balance of strength and toughness, but complicates the evaluation of fatigue resistance, mainly because of gradient residual stress (RS) and grains. An integrated fatigue resistance assessment (AIFA) framework was proposed to consider the residual stress relief under stochastic loads. To this end, quasi-in situ neutron diffraction and Bragg-edge imaging were combined to probe the evolution of residual stress during crack propagation. Firstly, a rigid-flexible coupled vehicle dynamics model was adopted to obtain the time-domain variable amplitude loading spectrum. Then, Fortran subroutines were developed to assign these data into full-scale S38C axle model, and the remaining life was predicted using the damage tolerance approach. The results demonstrate that crack propagation would accelerate when residual stress is considered in the case of the crack depth exceeding 3.0 mm. It is, for the first time, found that 15 mm- and 5 mm-thickness fan-shaped specimens can retain the axial and hoop residual strain in terms of diffraction angle variation, respectively, for full-scale structural S38C steel axles. In the absence of RS, the remaining life of the axle decreases sharply from 624,800 to 51,300 km as the crack depth increases from 3.0 to 16 mm. Compared with the standard method under constant amplitude loading without residual stress relief, the present AIFA method provides the more accurate but conservative fatigue life prediction.

論文

Isotopic ratios of plutonium in radioactive particles released by the accident of Fukushima Daiichi Nuclear Power Plant

五十嵐 淳哉*; 二宮 和彦*; Zheng, J.*; Zhang, Z.*; 福田 美保*; 青野 辰雄*; 箕輪 はるか*; 吉川 英樹*; 末木 啓介*; 佐藤 志彦; et al.

Journal of Environmental Radioactivity, 291, p.107856_1 - 107856_8, 2026/01

 被引用回数:2 パーセンタイル:43.74(Environmental Sciences)

福島第一原子力発電所(FDNPP)事故に由来する放射性粒子中のプルトニウム同位体比を、サンプル数を増やして高精度に測定し、FDNPP由来Puの指紋として利用可能な代表値を提示した。Pu同位体の原子比は放出源ごとに固有であり、Pu起源推定に有用である。FDNPP事故由来Puについては、事故時に炉内で形成された放射性粒子を対象とすることで全球的フォールアウトの影響を受けにくい評価が可能だが、既報は解析粒子数が少なく原子比推定の不確かさが大きかった。SF-ICP-MSにより7粒子を分析した結果、$$^{240}$$Pu/$$^{239}$$Pu=0.369$$pm$$0.008、$$^{241}$$Pu/$$^{239}$$Pu=0.150$$pm$$0.007(原子比)を得た。これらの値は炉心インベントリ計算や周辺環境試料で報告される比と概ね整合し、今後のPu起源推定や環境影響評価の参照指標として有用である。

論文

Critical role of L2$$_1$$ and L1$$_2$$ phase in deformation behaviors of additively manufactured FeCrNiAlTi alloy

Wang, X.*; Wang, Y.*; Gong, W.; Wu, W.*; Zhang, Y.*; Harjo, S.; Yang, Z.*; Chen, H.*

International Journal of Plasticity, 195, p.104502_1 - 104502_16, 2025/12

 被引用回数:12 パーセンタイル:92.14(Engineering, Mechanical)

Precipitation hardening strengthens FCC alloys but often reduces ductility. This study shows that precipitates can also modify deformation behavior to mitigate this trade-off. An FeCrNiAlTi FCC alloy fabricated by laser additive manufacturing contains incoherent L2$$_1$$ precipitates at cell walls and coherent L1$$_2$$ precipitates within cells. By controlling precipitation, an excellent strength-ductility balance was achieved at both ambient and cryogenic temperatures. High-density precipitates provide strengthening while promoting deformation-induced stacking faults and twinning, thereby enhancing work hardening via strain heterogeneity. In situ neutron diffraction indicates that post-yield lattice strain governs stacking fault and twin formation. Simulations show that interfacial misfit of the L2$$_1$$ phase and the size and spacing of the L1$$_2$$ phase amplify local strain.

論文

All-temperature barocaloric effects at pressure-induced phase transitions

Zhao, X.*; Zhang, Z.*; 服部 高典; Wang, J.*; Li, L.*; Jia, Y.*; Li, W.*; Xue, J.*; Fan, X.*; Song, R.*; et al.

Nature Communications (Internet), 16, p.7713_1 - 7713_8, 2025/08

 被引用回数:10 パーセンタイル:85.19(Multidisciplinary Sciences)

熱効果は、固体状態の冷凍技術の一つの解決策の基盤を成すもので、通常は固体状態の相転移付近で発生し、冷凍温度範囲が限定されている。ここでは、前例のない概念である「全温度帯バロカロリック効果」を導入し実現する。すなわち、KPF$$_6$$において77.5Kから300Kの極めて広い温度範囲(潜在的に4Kまで)で観測される顕著なバカカロリック効果である。この温度範囲は、一般的な室温、液体窒素、液体水素、液体ヘリウムの冷却領域をカバーしている。直接測定されたバーカロリック断熱温度変化は、250MPaの圧力を解放した際に、室温で12K、77.5Kで2.5Kに達する。この効果は、圧力依存性の中性子粉末回折、ラマン散乱解析、第一原理計算により示されるように、菱面体高圧相への持続的な相転移に起因する。構造的不安定性を考慮した熱力学的エネルギーランドスケープを記述する。この独自の全温度帯バロカロリック効果は、従来の多段式シナリオを超えた、高度に適用可能な固体状態冷凍技術への新たなアプローチを提供する。

論文

Seniority structure in neutron-rich nucleus $$^{128}$$Ag; Evidence for robustness of $$N$$=82 shell closure in silver isotopes

Luo, D. W.*; Zhang, J. Z.*; Li, Z. H.*; Orlandi, R.; 他64名*

Physical Review Letters, 134(23), p.232502_1 - 232502_7, 2025/06

 被引用回数:4 パーセンタイル:76.34(Physics, Multidisciplinary)

The first spectroscopic study of the neutron-rich $$^{128}$$Ag isotope at RIBF-RIKEN revealed a new 1.60(7) $$mu$$s seniority isomer with a proposed 16$$^{-}$$ spin-parity. Shell model calculations accurately describe its level structure, consistent with seniority schemes in nearby odd-odd nuclei. Level inversions between $$^{128}$$Ag and $$^{130}$$In's lowest states are linked to seniority-nonconserving interactions. The structure above 10$$^{-}$$ shows similarities to seniority structures in $$^{128}$$Pd and $$^{130}$$Cd, confirming the robustness of the $$N$$=82 shell closure in silver isotopes.

論文

Ordered graphane nanoribbons synthesized via high-pressure diels-alder polymerization of 2,2'-bipyrazine

Li, F.*; Tang, X.*; Fei, Y.*; Zhang, J.*; Liu, J.*; Lang, P.*; Che, G.*; Zhao, Z.*; Zheng, Y.*; Fang, Y.*; et al.

Journal of the American Chemical Society, 147(17), p.14054 - 14059, 2025/04

 被引用回数:2 パーセンタイル:21.18(Chemistry, Multidisciplinary)

2,2'-ビピラジン(BPZ)の圧力誘起重合により結晶性グラファンナノリボン(GANR)を合成した。中性子回折データのリートベルト精密化,核磁気共鳴スペクトル,赤外スペクトル,理論計算を行った結果、BPZは$$pi$$ $$cdots$$ $$pi$$積層した芳香環の間でディールス・アルダー重合し、並外れた長距離秩序を持つ伸びたボート型GANR構造を形成することがわかった。未反応の-C=N-基がボートの両端を橋渡ししており、さらなる機能化の余地がある。このGANRのバンドギャップは2.25eVであり、光電応答は良好である(I$$_{on}$$/I$$_{off}$$ =18.8)。われわれの研究は、高圧トポケミカル重合法が、特定の構造と望んだ特性を持つグラファンの精密な合成に有望な方法であることを強調している。

論文

The Influence of structural dynamics in two-dimensional hybrid organic-inorganic perovskites on their photoluminescence efficiency; Neutron scattering analysis

Rajeev, H. S.*; Hu, X.*; Chen, W.-L.*; Zhang, D.*; Chen, T.*; 古府 麻衣子*; 梶本 亮一; 中村 充孝; Chen, A. Z.*; Johnson, G. C.*; et al.

Journal of the Physical Society of Japan, 94(3), p.034602_1 - 034602_14, 2025/03

 被引用回数:2 パーセンタイル:55.25(Physics, Multidisciplinary)

Two-dimensional hybrid organic-inorganic perovskites (HOIPs) have emerged as promising materials for light-emitting diode applications. In this study, by using time-of-flight neutron spectroscopy we identified and quantitatively separated the lattice vibrational and molecular rotational dynamics of two perovskites, butylammonium lead iodide (BA)$$_{2}$$PbI$$_{4}$$ and phenethyl-ammonium lead iodide (PEA)$$_{2}$$PbI$$_{4}$$. By examining the corresponding temperature dependence, we found that the lattice vibrations, as evidenced by neutron spectra, are consistent with the lattice dynamics obtained from Raman scattering. We revealed that the rotational dynamics of organic molecules in these materials tend to suppress their photoluminescence quantum yield (PLQY) while the vibrational dynamics did not show predominant correlations with the same. Additionally, we observed photoluminescence emission peak splitting for both systems, which becomes prominent above certain critical temperatures where the suppression of PLQY begins. This study suggests that the rotational motions of polarized molecules may lead to a reduction in exciton binding energy or the breaking of degeneracy in exciton binding energy levels, enhancing non-radiative recombination rates, and consequently reducing photoluminescence yield. These findings offer a deeper understanding of fundamental interactions in 2D HOIPs and could guide the design of more efficient light-emitting materials for advanced technological applications.

論文

Strong low-energy rattling modes enabled liquid-like ultralow thermal conductivity in a well-ordered solid

Liu, P.-F.*; Li, X.*; Li, J.*; Zhu, J.*; Tong, Z.*; 古府 麻衣子*; 楡井 真実; Xu, J.*; Yin, W.*; Wang, F.*; et al.

National Science Review, 11(12), p.nwae216_1 - nwae216_10, 2024/12

 被引用回数:31 パーセンタイル:91.47(Multidisciplinary Sciences)

Crystalline solids exhibiting inherently low lattice thermal conductivity ($$kappa_{rm L}$$) are of great importance in applications such as thermoelectrics and thermal barrier coatings. However, $$kappa_{rm L}$$ cannot be arbitrarily low and is limited by the minimum thermal conductivity related to phonon dispersions. In this work, we report the liquid-like thermal transport in a well-ordered crystalline CsAg$$_5$$Te$$_3$$, which exhibits an extremely low $$kappa_{rm L}$$ value of $$sim$$ 0.18 Wm$$^{-1}$$K$$^{-1}$$. On the basis of first-principles calculations and inelastic neutron scattering measurements, we find that there are lots of low-lying optical phonon modes at $$sim$$ 3.1 meV hosting the avoided-crossing behavior with acoustic phonons. These strongly localized modes are accompanied by weakly bound rattling Ag atoms with thermally induced large amplitudes of vibrations. Using the two-channel model, we demonstrate that coupling of the particle-like phonon modes and the heat-carrying wave-like phonons is essential for understanding the low $$kappa_{rm L}$$, which is heavily deviated from the $$1/T$$ temperature dependence of the standard Peierls theory. In addition, our analysis indicates that the soft structural framework with liquid-like motions of the fluctuating Ag atoms is the underlying cause that leads to the suppression of the heat conduction in CsAg$$_5$$Te$$_3$$. These factors synergistically account for the ultralow $$kappa_{rm L}$$ value. Our results demonstrate that the liquid-like heat transfer could indeed exist in a well-ordered crystal.

論文

Emergent magneto-inductance effect in NiFe thin films on glass substrates at room temperature

Zhang, Z.*; 船戸 匠*; 松尾 衛; 他5名*

Journal of Magnetism and Magnetic Materials, 610, p.172500_1 - 172500_7, 2024/11

 被引用回数:3 パーセンタイル:23.65(Materials Science, Multidisciplinary)

We investigate an emergent magneto-inductance (EML) effect using stepwise magnetic field with AC current in Ni$$_{80}$$Fe$$_{20}$$ and Ni$$_{36}$$Fe$$_{64}$$ thin films on glass substrates. The properties of the EML effect were evaluated in terms of frequency, stepwise magnetic field, cross-sectional area, and the proportion of Ni and Fe. As a result, a large EML ($$>$$1.5 $$mu$$H) is observed under a low magnetic field of 10 Oe in Ni$$_{80}$$Fe$$_{20}$$ thin films at room temperature. The EML effect can be enhanced by increasing the stepwise magnetic field increment or decreasing the cross-sectional area of Ni$$_{80}$$Fe$$_{20}$$ thin films. Ni$$_{80}$$Fe$$_{20}$$/glass exhibits a larger EML effect compared to that of Ni$$_{36}$$Fe$$_{64}$$/glass, indicating that the EML depends on the strength of induced magnetic anisotropy. The observed EML effect can be explained by theoretical calculation based on the spin motive force owing to the transient current-driven domain-wall motion. These experimental and theoretical findings provide a deeper understanding on the mechanism of EML effect, and pave the way for potential applications, such as miniaturized inductors and magnetic sensors

論文

Anomalous dislocation response to deformation strain in CrFeCoNiPd high-entropy alloys with nanoscale chemical fluctuations

Ying, H.*; Yang, X.*; He, H.*; Yan, A.*; An, K.*; Ke, Y.*; Wu, Z.*; Tang, S.*; Zhang, Z.*; Dong, H.*; et al.

Scripta Materialia, 250, p.116181_1 - 116181_7, 2024/09

 被引用回数:14 パーセンタイル:79.41(Nanoscience & Nanotechnology)

Nanoscale chemical fluctuations and their effect on the deformation behavior of CrFeCoNi-based high-entropy alloys (HEAs) were investigated using small-angle scattering and in situ neutron diffraction measurements. Small-angle scattering results demonstrated the presence of nano ($$>$$10 nm) chemical fluctuations in the as-prepared CrFeCoNiPd HEAs, which was attributed to the negative mixing of enthalpy and the significant atomic radius difference between Pd and the constituent elements in the CrFeCoNi-based alloys. Subsequent tensile tests demonstrated that the yield and tensile strengths of the as-prepared CrFeCoNiPd HEA surpass those of the as-prepared CrMnFeCoNi HEA. Neutron diffraction data analysis revealed an anomalous response of dislocation evolution with the strain.

論文

Fukushima Daiichi Nuclear Power Plant Accident; Understanding Formation Mechanism of Radioactive Particles through Sr and Pu Quantities

五十嵐 淳哉*; 二宮 和彦*; Zheng, J.*; Zhang, Z. J.*; 福田 美保*; 青野 辰雄*; 箕輪 はるか*; 吉川 英樹*; 末木 啓介*; 佐藤 志彦; et al.

Environmental Science & Technology, 58(33), p.14823 - 14830, 2024/08

 被引用回数:7 パーセンタイル:47.81(Engineering, Environmental)

The Fukushima Daiichi Nuclear Power Plant accident released considerable radionuclides into the environment. Radioactive particles, composed mainly of SiO$$_2$$, emerged as distinctive features, revealing insights into accident's dynamics. While studies extensively focused on high-volatile radionuclides like Cs, investigations into low-volatile nuclides such as $$^{90}$$Sr and Pu remain limited. Understanding their abundance in radioactive particles is crucial for deciphering the accident's details, including reactor temperatures and injection processes. Here we aimed to determine $$^{90}$$Sr and Pu amounts in radioactive particles and provide essential data for understanding the formation processes and conditions within the reactor during the accident. We employed radiochemical analysis on nine radioactive particles and determined the amounts of $$^{90}$$Sr and Pu in these particles. $$^{90}$$Sr and Pu quantification in radioactive particles showed $$^{90}$$Sr/$$^{137}$$Cs radioactivity ratio (corrected to March 11, 2011) aligned with core temperature expectations. However, $$^{239+240}$$Pu/$$^{137}$$Cs activity ratio indicated non-volatile Pu introduction, possibly through fuel fragments. Analyzing $$^{90}$$Sr and Pu enhances our understanding of the Fukushima Daiichi accident. Deviations in $$^{239+240}$$Pu/$$^{137}$$Cs activity ratios underscore non-volatile processes, emphasizing the accident's complexity. Future research should expand this dataset for a more comprehensive understanding of the accident's nuances.

論文

Giant barocaloric effects in sodium hexafluorophosphate and hexafluoroarsenate

Zhang, Z.*; 服部 高典; Song, R.*; Yu, D.*; Mole, R.*; Chen, J.*; He, L.*; Zhang, Z.*; Li, B.*

Journal of Applied Physics, 136(3), p.035105_1 - 035105_8, 2024/07

 被引用回数:6 パーセンタイル:47.53(Physics, Applied)

バロカロリック材料を用いた固体冷凍は、環境に優しく高効率であるため、過去10年間にわたり世界的に注目されてきた。ここでは、室温付近で立方晶から菱面体晶への相転移を起こすヘキサフルオロ燐酸ナトリウム(NaPF$$_6$$)とヘキサフルオロ砒酸ナトリウム(NaAsF$$_6$$)における巨大バロカロリック効果を報告する。われわれは中性子粉末回折により、NaPF$$_6$$の低温相の構造が空間群R$=3$の菱面体構造であることを明らかにした。NaPF$$_6$$とNaAsF$$_6$$には3つのラマン振動モード(F$$_{2g}$$, E$$_g$$, A$$_{1g}$$)が存在する。相転移温度はNaPF$$_6$$及びNaAsF$$_6$$においてそれぞれdT$$_t$$/dP=250K/GPa及び310K/GPaの割合で圧力とともに変化する。NaPF$$_6$$とNaAsF$$_6$$の圧力誘起エントロピー変化は、それぞれ約45.2Jkg$$^{-1}$$K$$^{-1}$$と35.6Jkg$$^{-1}$$K$$^{-1}$$と決定された。飽和駆動圧力は約40MPaであった。高圧下の中性子粉末回折から、バロカロリック効果は立方晶から菱面体晶への圧力誘起相転移に関係していることが示唆された。

論文

Spectral evidence for Dirac spinons in a kagome lattice antiferromagnet

Zeng, Z.*; Zhou, C.*; Zhou, H.*; Han, L.*; Chi, R.*; Li, K.*; 古府 麻衣子; 中島 健次; Wei, Y.*; Zhang, W.*; et al.

Nature Physics, 20(7), p.1097 - 1102, 2024/07

 被引用回数:33 パーセンタイル:96.08(Physics, Multidisciplinary)

Emergent quasiparticles with a Dirac dispersion in condensed matter systems can be described by the Dirac equation for relativistic electrons, in analogy with Dirac particles in high-energy physics. For example, electrons with a Dirac dispersion have been intensively studied in electronic systems such as graphene and topological insulators. However, charge is not a prerequisite for Dirac fermions, and the emergence of Dirac fermions without a charge degree of freedom has been theoretically predicted to be realized in Dirac quantum spin liquids. These quasiparticles carry a spin of 1/2 but are charge-neutral and so are called spinons. Here we show that the spin excitations of a kagome antiferromagnet, YCu$$_3$$(OD)$$_6$$Br$$_2$$[Br$$_{0.33}$$(OD)$$_{0.67}$$], are conical with a spin continuum inside, which is consistent with the convolution of two Dirac spinons. The predictions of a Dirac spin liquid model with a spinon velocity obtained from spectral measurements are in agreement with the low-temperature specific heat of the sample. Our results, thus, provide spectral evidence for a Dirac quantum spin liquid state emerging in this kagome lattice antiferromagnet. However, the locations of the conical spin excitations differ from those calculated by the nearest-neighbor Heisenberg model, suggesting the Dirac spinons have an unexpected origin.

110 件中 1件目~20件目を表示