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In
Ge studied by single crystal neutron diffraction田端 千紘; 金子 耕士; 中尾 朗子*; 大原 高志; 松田 達磨*; 大貫 惇睦*
Journal of the Physical Society of Japan, 95(5), p.053702_1 - 053702_4, 2026/04
The magnetic order of EuIrInGe, which crystallizes in a Dresselhaus-type noncentrosymmetric tetragonal structure, was investigated using two complementary single-crystal neutron diffraction approaches. Time-of-flight single-crystal diffraction reveals antiferromagnetic Bragg reflections with propagation vector q = (0, 0, 0) below the Neel temperature TN = 2.5 K, indicating a breaking of body-centered translational symmetry. Polarized neutron diffraction on a triple-axis spectrometer demonstrates that the ordered Eu2+ 4f moments lie within the basal plane and form a collinear antiferromagnetic structure with antiparallel alignment between corner and body-center sites. Despite the Dresselhaus-type spin splitting in the conduction bands, the magnetic order remains simple, implying weak coupling between localized moments and itinerant electrons.
中村 龍也; 藤 健太郎; 鬼柳 亮嗣; 大原 高志; 細谷 孝明; 戸邊 雅弘; 菱沼 行男*; 海老根 守澄; 坂佐井 馨
Journal of Physics; Conference Series, 3130(1), p.012002_1 - 012002_6, 2025/11
J-PARC物質・生命科学実験施設に設置されたSENJU中性子回折計用の2次元シンチレータ中性子検出器の高度化を進めている。高度化計画には、薄型、高効率型、真空槽下およびバンク設置用の大面積検出器が含まれる。これはすべて
Li:ZnSと波長シフトファイバーを用いた検出器である。大面積検出器についてはこれまでにオリジナル検出器の2
2倍の有感面積(512512mm)をもつ検出器を開発してきたが、近年ではさらに大面積で長方形の有感面積である検出器を開発している(13倍(256768mm)、23倍(512768mm))。発表ではこれらの検出器の設計やプロトタイプ検出器の実験結果を報告する。
He neutron spin filter at J-PARC高橋 慎吾; 鬼柳 亮嗣; 奥平 琢也*; 高田 秀佐*; 小林 龍珠; 奥泉 舞桜; 猪野 隆*; 浅井 寛太*; 土川 雄介; 及川 健一; et al.
Nuclear Instruments and Methods in Physics Research A, 1075, p.170410_1 - 170410_8, 2025/06
被引用回数：1 パーセンタイル：0.00(Instruments & Instrumentation)This study developed a compact and portable in-situ He neutron spin filter ( He NSF) utilizing spin-exchange optical pumping at MLF of J-PARC. Its performance as an incident neutron polarizer was evaluated at MLF, where it achieved a He polarization exceeding 0.6, corresponding to a neutron polarization greater than 0.8 at 1.8 
. Notably, the He NSF demonstrated stable operation for 110 h. These outcomes signify that the developed in-situ He NSF facilitates and promotes polarized pulsed neutron experiments at MLF.
軽部 皓介*; 大貫 惇睦*; 中島 多朗*; Chen, H.-Y.*; 石塚 大晃*; 木俣 基*; 大原 高志; 宗像 孝司*; 野本 拓也*; 有田 亮太郎*; et al.
npj Quantum Materials (Internet), 10, p.55_1 - 55_9, 2025/06
被引用回数：6 パーセンタイル：87.77(Materials Science, Multidisciplinary)The Hall effect is one of the most fundamental but elusive phenomena in condensed matter physics due to the rich variety of underlying mechanisms. Here we report an exceptionally large Hall effect in a frustrated magnet, GdCu, with high conductivity. The Hall conductivity at the base temperature shows abrupt sign changes under magnetic fields. Our systematic measurements indicate that the unusual Hall effect can be understood in terms of spin-splitting-induced emergence/disappearance of Fermi pockets as well as skew scattering from spin-chiral cluster fluctuations in a field-polarized state. The present study demonstrates a complex interplay among magnetization, spin-dependent electronic structure, and spin fluctuations in producing the giant Hall effect in highly conductive frustrated magnets with a distorted triangular lattice.
Sb
with a honeycomb network足立 匡*; Ogawa, Taiki*; 小宮山 陽太*; 須村 拓也*; Saito-Tsuboi, Yuki*; Takeuchi, Takaaki*; Mano, Kohei*; Manabe, Kaoru*; 川端 幸樹*; 今津 毅士*; et al.
Physical Review B, 111(10), p.L100508_1 - L100508_6, 2025/03
被引用回数：1 パーセンタイル：0.00(Materials Science, Multidisciplinary)Chiral superconductivity exhibits the formation of novel electron pairs that breaks the time-reversal symmetry and has been actively studied in various quantum materials in recent years. However, despite its potential to provide definitive information, effects of disorder in the crystal structure on the chiral superconductivity has not yet been clarified, and therefore the investigation using a solid-solution system is desirable. We report muon-spin-relaxation (
SR) results of layered pnictide BaPtAsSb with a honeycomb network composed of Pt and (As, Sb). We observed an increase of the zero-field SR rate in the superconducting (SC) state at the Sb end of 
, suggesting the occurrence of a spontaneous magnetic field due to the time-reversal symmetry breaking in the SC state. On the other hand, a spontaneous magnetic field was almost and completely suppressed for the As-Sb mixed samples of 
and 0.2, respectively, suggesting that the time-reversal symmetry-breaking SC state in is sensitive to disorder. The magnetic penetration depth estimated from transverse-field SR measurements at and 0.2 behaved like weak-coupling 
-wave superconductivity. These seemingly incompatible zero-field and transverse-field SR results of BaPtAsSb with could be understood in terms of chiral 
-wave superconductivity with point nodes on the three-dimensional Fermi surface.
Jin, H.*; Choi, E. S.*; Wu, H.-C.*; Curro, N. J.*; 那波 和宏*; 佐藤 卓*; 鬼柳 亮嗣; 大原 高志; Klavins, P.*; Taufour, V.*
Physical Review B, 111(3), p.035103_1 - 035103_7, 2025/01
被引用回数：0 パーセンタイル：0.00(Materials Science, Multidisciplinary)We report on neutron diffraction, magnetoresistance, magnetization and magnetic torque measurements under high magnetic field in the helical antiferromagnet CeVGe. This compound exhibits Kondo lattice coherence and helical antiferromagnetic (AFM) ordering at ambient pressure, similar to the well-studied CeRhIn
. Our measurements reveal that CeVGe undergoes a magnetic transition from an incommensurate (ICM) AFM state to an up-up-down-down commensurate (CM) AFM structure, followed by a transition to a novel phase at higher fields. A quantum phase transition occurs around 21.3 T. This rich magnetic field phase diagram closely resembles that of CeRhIn. Furthermore, angle-dependent magnetoresistance measurements reveal that all transitions in CeVGe occur from the field component along the ab plane. These findings highlight the intricate interplay among exchange interactions, crystal field effects, ground state properties, and crystalline symmetries.
山口 瑛子; 栗原 雄一*; 永田 光知郎*; 田中 万也; 桧垣 正吾*; 小林 徹; 谷田 肇; 小原 義之*; 横山 啓一; 矢板 毅; et al.
Journal of Colloid and Interface Science, 661, p.317 - 332, 2024/05
被引用回数：13 パーセンタイル：74.36(Chemistry, Physical)ラジウム(Ra)は放射性元素であり、放射性廃棄物処理やウラン鉱山周辺の環境問題で重要なため、環境中Ra挙動の解明は急務である。しかし、Raは安定同位体が存在しないため分子レベルの実験が難しく、環境中で重要と考えられる粘土鉱物への吸着反応についても詳細なデータは得られていない。本研究では、広域X線吸収微細構造(EXAFS)法によりRaの分子レベルの情報を得る手法を確立し、さらに第一原理計算を利用することでRaの粘土鉱物への吸着構造を明らかにした。また、同族元素との比較を行い、粘土鉱物への吸着反応の系統的な理解に資する結果を得た。
complex exhibiting intermolecular proton shifting coupled spin transitionJi, T.*; Su, S.*; Wu, S.*; 堀 優太*; 重田 育照*; Huang, Y.*; Zheng, W.*; Xu, W.*; Zhang, X.*; 鬼柳 亮嗣; et al.
Angewandte Chemie; International Edition, 63(25), p.e202404843_1 - e202404843_6, 2024/04
被引用回数：3 パーセンタイル：23.38(Chemistry, Multidisciplinary)In this study, we investigated reversible intermolecular proton shifting (IPS) coupled with spin transition (ST) in a novel Fe complex. The host Fe complex and the guest carboxylic acid anion were connected by intermolecular hydrogen bonds (IHBs). We extended the intramolecular proton transfer coupled ST phenomenon to the intermolecular system. The dynamic phenomenon was confirmed by variable-temperature single-crystal X-ray diffraction, neutron crystallography, and infrared spectroscopy.
Rh
Sn
下田 愛海*; 岩佐 和晃*; 桑原 慶太郎*; 佐賀山 基*; 中尾 裕則*; 石角 元志*; 中尾 朗子*; 河村 聖子; 村井 直樹; 大原 高志; et al.
Physical Review B, 109(13), p.134425_1 - 134425_10, 2024/04
被引用回数：4 パーセンタイル：50.66(Materials Science, Multidisciplinary)The detailed electronic superlattice structure of the Remeika phase compound NdRhSn was investigated. The material undergoes a structural phase transition at 
~K between the high temperature phase (
) and the low temperature chiral structure phase (
3), which is the same symmetry change as that of the La- and Ce-based Remeika phase compounds. The inequivalent Nd-ion sites in the chiral phase are occupied by different crystalline electronic field splitting schemes of the 4
electronic configuration with the total angular moment 
, which results in two-sublattice antiferromagnetic ordering below 
= 1.65 K. The one-dimensional Nd-ion chains in which the magnetic moments are alternately arranged are connected via the second-neighbor triangular lattice in the chiral phase, which suggests a magnetic frustration effect.
-odd/
-odd interactions on the 0.75 eV 
-wave resonance in 
+
forward transmission determined using a pulsed neutron beam中部 倫太郎*; Auton, C. J.*; 遠藤 駿典; 藤岡 宏之*; Gudkov, V.*; 広田 克也*; 井出 郁央*; 猪野 隆*; 石角 元志*; 神原 理*; et al.
Physical Review C, 109(4), p.L041602_1 - L041602_4, 2024/04
被引用回数：1 パーセンタイル：8.54(Physics, Nuclear)Neutron transmission experiments can offer a new type of highly sensitive search for time-reversal invariance violating (TRIV) effects in nucleon-nucleon interactions via the same enhancement mechanism observed for large parity violating (PV) effects in neutron-induced compound nuclear processes. In these compound processes, the TRIV cross-section is given as the product of the PV cross-section, a spin-factor 
, and a ratio of TRIV and PV matrix elements. We determined to be 0.59 
0.05 for 
La+n using both (n, 
) spectroscopy and (+) transmission. This result quantifies for the first time the high sensitivity of the La 0.75 eV -wave resonance in a future search for -odd/-odd interactions in (+) forward transmission.
-wave resonance of 
+
奥平 琢也*; 中部 倫太郎*; Auton, C. J.*; 遠藤 駿典; 藤岡 宏之*; Gudkov, V.*; 井出 郁央*; 猪野 隆*; 石角 元志*; 神原 理*; et al.
Physical Review C, 109(4), p.044606_1 - 044606_9, 2024/04
被引用回数：2 パーセンタイル：49.04(Physics, Nuclear)We measured the spin dependence in a neutron-induced p-wave resonance by using a polarized epithermal neutron beam and a polarized nuclear target. Our study focuses on the 0.75 eV -wave resonance state of La+n, where largely enhanced parity violation has been observed. We determined the partial neutron width of the -wave resonance by measuring the spin dependence of the neutron absorption cross section between polarized La and polarized neutrons. Our findings serve as a foundation for the quantitative study of the enhancement effect of the discrete symmetry violations caused by mixing between partial amplitudes in the compound nuclei.
CoSi山内 宏樹; Sari, D. P.*; 安井 幸夫*; 坂倉 輝俊*; 木村 宏之*; 中尾 朗子*; 大原 高志; 本田 孝志*; 樹神 克明; 井川 直樹; et al.
Physical Review Research (Internet), 6(1), p.013144_1 - 013144_9, 2024/02
-Mn-type family alloys Mn
have three-dimensional antiferromagnetic (AFM) corner-shared triangular network. The antiferromagnet MnRhSi shows magnetic short-range order (SRO) over a wide temperature range of approximately 500 K above the N
el temperature = 190 K. MnCoSi has the smallest lattice parameter and the lowest in the family compounds. The quantum critical point (QCP) from AFM to the quantum paramagnetic state is expected near a cubic lattice parameter of 6.15 
of MnCoSi is only 140 K, quantum critical behavior is observed in MnCoSi as the enhancement of the electronic specific heat coefficient . We study how the magnetic SRO appears in MnCoSi by using neutron scattering, SR, and physical property measurements. The experimental results show that the neutron scattering intensity of the magnetic SRO does not change much regardless of the suppressed magnetic moment in the long-range magnetic ordered state compared to those of MnRhSi. The initial asymmetry drop ratio of SR above becomes small, and the magnetic SRO temperature 
is suppressed to 240 K. The results suggest that the MnCoSi is close to the QCP in the Mn system.
Zhang, A.*; Deng, K.*; Sheng, J.*; Liu, P.*; Kumar, S.*; 島田 賢也*; Jiang, Z.*; Liu, Z.*; Shen, D.*; Li, J.*; et al.
Chinese Physics Letters, 40(12), p.126101_1 - 126101_8, 2023/12
被引用回数：15 パーセンタイル：84.76(Physics, Multidisciplinary)In a Dirac semimetal, the massless Dirac fermion has zero chirality, leading to surface states connected adiabatically to a topologically trivial surface state as well as vanishing anomalous Hall effect. Recently, itis predicted that in the nonrelativistic limit of certain collinear antiferromagnets, there exists a type of chiral "Dirac-like" fermion, whose dispersion manifests four-fold degenerate crossing points formed by spin-degenerate linear bands, with topologically protected Fermi arcs. Here, by combining with neutron diffraction and first-principles calculations, we suggest a multidomain collinear antiferromagnetic configuration, rendering the existence of the Fermi-arc surface states induced by chiral Dirac-like fermions.
山下 恵史朗*; 中山 和也*; 小松 一生*; 大原 高志; 宗像 孝司*; 服部 高典; 佐野 亜沙美; 鍵 裕之*
Acta Crystallographica Section B; Structural Science, Crystal Engineering and Materials (Internet), 79(5), p.414 - 426, 2023/10
被引用回数：2 パーセンタイル：30.47(Chemistry, Multidisciplinary)最近発見された塩化ナトリウムの超水和物(NaCl
13H(D)O)の構造を1.7GPa, 298Kでのその場単結晶中性子回折によって決定した。この物質は大きな水素結合ネットワークを持ち、いくつかの水分子は分岐水素結合や5配位水分子のような歪んだ結合の特徴を持つ。水素結合ネットワークは、ネットワークトポロジーと水素結合の無秩序性という点で、氷VIと類似している。擬似対称性によって接続されたネットワークの構成要素を区別しなければ、このハイドレートの全体的なネットワーク構造は、氷VIのネットワーク構造に対応する小さな構造単位に分解することで表現できる。この水素結合ネットワークは、既知の塩水和物とは対照的に、水分子の配向の乱れを含んでいる。ここでは、イオン種を含む水素結合ネットワークに関するさらなる洞察のための例を示す。
千葉 薫*; 松井 拓郎*; 茶竹 俊行*; 大原 高志; 田中 伊知朗*; 油谷 克英*; 新村 信雄*
Protein Science, 32(10), p.e4765_1 - e4765_13, 2023/10
被引用回数：1 パーセンタイル：5.00(Biochemistry & Molecular Biology)In structural biology, peptide bonds, fundamental linkages between hundreds of amino acids, of which a protein molecule is composed, have been commonly treated as a plane structure just as Linus Pauling et al. proposed. In this paper, a site-specific peptide bond relaxation mechanism by deuterons whose localization has been suggested by neutron crystallography is proposed. A comprehensive study using X-ray and neutron diffraction and 
N chemical shifts of individual amide nitrogen atoms within the same peptide bond strongly suggests the relaxation of the electronic resonance structure because of site-specific modulation by protons/deuterons localized on the electron orbital of the carbonyl oxygen.
Su, Y. H.; 及川 健一; 篠原 武尚; 甲斐 哲也; 堀野 孝*; 井戸原 修*; 三阪 佳孝*; 友田 陽*
International Journal of Fatigue, 174, p.107729_1 - 107729_12, 2023/09
被引用回数：24 パーセンタイル：90.74(Engineering, Mechanical)A novel procedure, double induction quenching (DIQ), effective for improving the fatigue strength of gear products, has been used for producing gears with steep gradients of compressive residual stress generated in the tooth surface. We performed a Bragg edge imaging experiment at a pulsed neutron source to determine the spatial distribution of the {110} lattice spacing (d
) and the broadening of the {110} Bragg edge (w) on the DIQ gear product after tooth-bending fatigue tests to which different loading cycles were applied. No significant difference occurred in the d and the wat Hofer 's critical section of the teeth with different loading conditions within the accuracy of data analysis. However, we detected a decrease in the w and changes in the residual lattice strain distribution in the axial direction along the tooth root directions at the opposite side of Hofer 's critical section for both teeth after 310 
and 810 cycles, relieving the compressive residual stresses during the fatigue process. The residual stress close to the gear tooth surface determined by X-ray diffraction using sequential polishing showed a slight relaxation and redistribution from the tensile side in the hoop direction, complementary to the neutron Bragg edge imaging.
中西 匠*; 堀 優太*; 重田 育照*; 佐藤 寛泰*; 鬼柳 亮嗣; 宗像 孝司*; 大原 高志; 岡澤 厚*; 島田 林太郎*; 坂本 章*; et al.
Journal of the American Chemical Society, 145(35), p.19177 - 19181, 2023/08
被引用回数：8 パーセンタイル：41.20(Chemistry, Multidisciplinary)Multiple proton transfer (PT) controllable by external stimuli plays a crucial role in fundamental chemistry, biological activity, and material science. However, in crystalline systems, controlling multiple PT, which results in a distinct protonation state, remains challenging. In this study, we developed a novel tridentate ligand and iron(II) complex with a short hydrogen bond (HB) that exhibits a PT-coupled spin transition (PCST). Single-crystal X-ray and neutron diffraction measurements revealed that the positions of the two protons in the complex can be controlled by temperature and photoirradiation based on the thermal- and photoinduced PCST. The obtained results suggest that designing molecules that form short HBs is a promising approach for developing multiple PT systems in crystals.
Sn ( = Rh and Ir)下田 愛海*; 岩佐 和晃*; 桑原 慶太郎*; 佐賀山 基*; 中尾 裕則*; 石角 元志*; 大原 高志; 中尾 朗子*; 星川 晃範*; 石垣 徹*
JPS Conference Proceedings (Internet), 38, p.011091_1 - 011091_6, 2023/05
Synchrotron X-ray diffraction study revealed that NdSn ( = Rh and Ir) undergo structural phase transitions characterized by the wave vector 
=(1/2,1/2,0). Neutron diffraction study revealed antiferromagnetic ordering below 
= 1.65 and 1.42 K for NdRhSn and NdIrSn, respectively, which is similar to that previously reported for NdCoSn. These compounds show a magnetic susceptibility saturation behavior below approximately 3 K. The results indicate emergence of anomalous electronic correlation in NdSn ( = Co, Rh, and Ir) above .
中西 匠*; 堀 優太*; 重田 育照*; 佐藤 寛泰*; Wu, S.-Q.*; 鬼柳 亮嗣; 宗像 孝司*; 大原 高志; 佐藤 治*
Physical Chemistry Chemical Physics, 25(17), p.12394 - 12400, 2023/05
被引用回数：3 パーセンタイル：26.53(Chemistry, Physical)The application of single-crystal neutron diffraction (SCND) to observe proton-transfer phenomena in crystalline compounds exhibiting unusual protonation states or proton dynamics has garnered significant research interest in recent years. However, proton tautomerism, which results in different protonation states before and after proton transfer, has never been observed using the SCND technique. Thus, to observe the proton tautomerism phenomenon by SCND measurements, we developed an iron(II) complex that forms a large crystal and exhibits a proton-transfer-coupled spin transition (PCST). The presence of the two types of proton tautomers was determined by conventional analysis of the proton position by X-ray crystallography, infrared spectroscopy, and density functional theory calculations. Finally, our results confirmed that proton tautomerism was successfully observed for the first time using variable-temperature SCND measurements.
根尾 陽一郎*; 橋本 凱*; Koike, Rei*; 大原 高志; 松本 貴裕*
Global Challenges, 7(4), p.2200236_1 - 2200236_8, 2023/04
被引用回数：1 パーセンタイル：7.13(Multidisciplinary Sciences)The ongoing global outbreak of coronavirus disease has necessitated the use of ultraviolet (UV) disinfection techniques to reduce viral transmission in public places. The previously used UV wavelength is harmful to the human body, the wavelength range from 200 to 235 nm, often referred to as far-UVC light, has attracted attention as a novel disinfection wavelength range that can be used in a safe manner. Here, an efficient mercury-free far-UVC solid-state light source is presented. This light source demonstrates intense 230 nm emission with a narrow spectral width of 30 nm and a long lifetime of more than 1000 h. These characteristics can be achieved by graphene nanostructure field emitters and wide-bandgap magnesium aluminate phosphors.
