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Development of an Fe$$^{rm II}$$ complex exhibiting intermolecular proton shifting coupled spin transition

分子内プロトンシフトと協調したスピン転移を示す鉄(II)錯体の開発

Ji, T.*; Su, S.*; Wu, S.*; 堀 優太*; 重田 育照*; Huang, Y.*; Zheng, W.*; Xu, W.*; Zhang, X.*; 鬼柳 亮嗣  ; 宗像 孝司*; 大原 高志   ; 中西 匠*; 佐藤 治*

Ji, T.*; Su, S.*; Wu, S.*; Hori, Yuta*; Shigeta, Yasuteru*; Huang, Y.*; Zheng, W.*; Xu, W.*; Zhang, X.*; Kiyanagi, Ryoji; Munakata, Koji*; Ohara, Takashi; Nakanishi, Takumi*; Sato, Osamu*

In this study, we investigated reversible intermolecular proton shifting (IPS) coupled with spin transition (ST) in a novel Fe$$^{rm II}$$ complex. The host Fe$$^{rm II}$$ complex and the guest carboxylic acid anion were connected by intermolecular hydrogen bonds (IHBs). We extended the intramolecular proton transfer coupled ST phenomenon to the intermolecular system. The dynamic phenomenon was confirmed by variable-temperature single-crystal X-ray diffraction, neutron crystallography, and infrared spectroscopy.

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分野:Chemistry, Multidisciplinary

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