Improvement of aerosol time-of-flight mass spectrometer for on-line measurement of tiny particles containing alpha emitters (Contract research); FY2023 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; Osaka University*

JAEA-Review 2025-019, 95 Pages, 2025/09

JAEA-Review-2025-019.pdf:9.49MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2023. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station (1F), Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2021, this report summarizes the research results of the "Improvement of aerosol time-of-flight mass spectrometer for on-line measurement of tiny particles containing alpha emitters" conducted from FY2021 to FY2023. The present study aims to improve Aerosol Time-Of-Flight Mass Spectrometer (ATOFMS) in order to monitor tiny particles containing alpha emitters such as U and Pu which were generated in removing debris from the reactors of 1F. We newly fabricated the improved ATOFMS quipped with a reflectron and carried out measurements for modeled tiny particles containing U. In obtained TOF spectra, ion peaks were observed for Zr, U, and their oxides as well as Zr and U. Mass resolution of the ion peak of U+ was 1,700, which demonstrates that the improved ATOFMS has sufficient mass resolution to distinguish Pu from U. In the development of the apparatus for preparing enriched and enlarged particles, we fabricated the apparatus consisting of PILS, a volume reduction tube, a supersonic atomizer, and an online dryer, and optimized apparatus conditions. In the optimized conditions, enlarged particles with size between 0.4 m and 0.8 m which are detectable with ATOFMS were dominantly produced. By analyzing the enlarged particles, these were produced by taking component elements of the apparatuses used in the enlarged process. The efficiency was evaluated to be 4.5 times. From these developments, the detection concentration limits of the apparatus were evaluated to be 7.010, 4.210, and 1.310 Bq/cm for U, U, and Pu, respectively. These values are below the air concentration limit.

Particle arrangements and optical changes induced by the water swelling of melanin-like polydopamine layers

Watanabe, Taku*; Maejima, Yui*; Ueda, Yuki; Motokawa, Ryuhei; Takabatake, Ai*; Takeda, Shinichi*; Fudoji, Hiroshi*; Kishikawa, Keiki*; Koori, Michinari*

Langmuir, 41(34), p.22762 - 22773, 2025/09

https://doi.org/10.1021/acs.langmuir.5c01855

The assembled structures of melanin particles, i.e., colloidal particles coated with a melanin-like polydopamine (PDA) layer, create vivid structural colors. While the thickness of the PDA layer influences the particle arrangement and optical properties, the underlying mechanism has remained controversial. We demonstrate that the water swelling characteristics of PDA are crucial factors governing the dispersion and aggregation of these particles in solution. Detailed comparisons between dry and wet conditions revealed that the PDA layer readily absorbs water molecules, which leads to significant swelling in the thicker layers. The swelling of the PDA layers determined whether the particles remained dispersed or partially aggregated in the water, ultimately controlling the particle arrangement in the dry state once the water evaporated. These findings provide insights into the self-assembly of colloidal particles and offer a strategy for tuning the periodic particle order. This feature is pivotal for various applications in optical and sensing technologies.

Characteristics of droplet evaporation on high-temperature porous surfaces for estimating cooling time of fuel debris

Yuki, Kohei*; Horiguchi, Naoki; Yoshida, Hiroyuki; Yuki, Kazuhisa*

Mechanical Engineering Journal (Internet), 12(4), p.24-00451_1 - 24-00451_8, 2025/08

https://doi.org/10.1299/mej.24-00451

Fuel debris at the Fukushima Daiichi nuclear power station is typically cooled under immersion. However, an unexpected significant drop in water level results in coolant contact with high-temperature fuel debris having porous structure. In such scenarios, rapid cooling is essential, yet the thermal behavior at the liquid-solid interface, including capillary phenomena, is not well understood. This paper presents basic research evaluating the evaporation characteristics of droplets upon contact with metallic porous media featuring small pores under 1 mm. We conducted experiments using bronze or stainless steel porous media with pore diameters of 1, 40, or 100 m to derive lifetime curves for droplets. Our findings indicate that Leidenfrost effect is mitigated on porous surfaces as the vapor can escape through the pores. Moreover, in bronze porous media, as the temperature increases, oxide film with a fine structure facilitates capillary action. In contrast, the low wettability of stainless steel porous media prevents capillary action, inhibiting droplet absorption and dispersion into the pores. Consequently, rapid cooling via the capillary action is unlikely if the fuel debris shares similar characteristics with steel porous media. Therefore, for risk management, the cooling system should be established assuming that capillary force does not act in the fuel debris.

Grain refinement of dual phase steel maximizes deformation ability of martensite, leading to simultaneous enhancement of strength and ductility

Park, M.-H.*; Shibata, Akinobu*; Harjo, S.; Tsuji, Nobuhiro*

Acta Materialia, 292, p.121061_1 - 121061_13, 2025/06

https://doi.org/10.1016/j.actamat.2025.121061

Application study of adaptive mesh refinement method on unsteady wake vortex analysis

Alzahrani, H.*; Matsushita, Kentaro; Sakai, Takaaki*; Ezure, Toshiki; Tanaka, Masaaki

Nuclear Technology, 13 Pages, 2025/06

https://doi.org/10.1080/00295450.2025.2472582

Development of evaluation method for cover gas entrainment by vortices generated at free surface in upper plenum of sodium-cooled fast reactor is required, and an evaluation method by predicting vortices from flow velocity distribution obtained by CFD analysis is developed. In this study, Adaptive Mesh Refinement (AMR) method is examined to improve efficiency of CFD analysis. Initial mesh was refined with two indexes: the first index (Index-1) is when the second invariant of velocity gradient tensor, Q, is negative and the second one (Index-2) is pressure gradient index added to Index-1. As a result of applying AMR method to unsteady vortices system with a flat plate and performing transient analyses with refined meshes, the result of pressure distribution and velocity around the flat plate in mesh using Index-2 was similar to the result of all refined mesh. It was also confirmed that vortices generation and growth was better simulated by refining meshes around separation area.

Experimental investigation of phase transformations in steel using X-ray and neutron diffraction

Tomota, Yo*; Harjo, S.; Xu, P. G.; Morooka, Satoshi; Gong, W.; Wang, Y.*

Metals, 15(6), p.610_1 - 610_19, 2025/05

https://doi.org/10.3390/met15060610

Ordered graphane nanoribbons synthesized via high-pressure diels-alder polymerization of 2,2'-bipyrazine

Li, F.*; Tang, X.*; Fei, Y.*; Zhang, J.*; Liu, J.*; Lang, P.*; Che, G.*; Zhao, Z.*; Zheng, Y.*; Fang, Y.*; et al.

Journal of the American Chemical Society, 147(17), p.14054 - 14059, 2025/04

https://doi.org/10.1021/jacs.5c03116

We synthesized a crystalline graphane nanoribbon (GANR) via pressure-induced polymerization of 2,2'-bipyrazine (BPZ). By performing Rietveld refinement of in situ neutron diffraction data, nuclear magnetic resonance spectroscopy, infrared spectra, and theoretical calculation, we found that BPZ experienced Diels-Alder polymerization between the stacked aromatic rings, and formed extended boat-GANR structures with exceptional long-range order. The unreacted -C=N- groups bridge the two ends of the boat, and ready for further functionalization. The GANR has a bandgap of 2.25 eV, with booming photoelectric response (/ =18.8). Our work highlights that the high-pressure topochemical polymerization is a promising method for the precise synthesis of graphane with specific structure and desired properties.

Reduction and phase transformation of Ce-doped zirconolites

Hayashizaki, Kohei; Hirooka, Shun; Yamada, Tadahisa*; Sunaoshi, Takeo*; Murakami, Tatsutoshi; Saito, Kosuke

Ceramics (Internet), 8(1), p.24_1 - 24_12, 2025/03

https://doi.org/10.3390/ceramics8010024

Measurements of neutron capture cross-section for nuclides of interest in decommissioning (II); Fe(n,)Fe

Nakamura, Shoji; Shibahara, Yuji*; Endo, Shunsuke; Rovira Leveroni, G.; Kimura, Atsushi

Journal of Nuclear Science and Technology, 62(3), p.300 - 307, 2025/03

https://doi.org/10.1080/00223131.2024.2427244

Directional vector-based quick evaluation method for protective plate effects in X-ray fluoroscopy (DQPEX)

Hizukuri, Kyoko*; Fujibuchi, Toshio*; Han, D.*; Arakawa, Hiroyuki*; Furuta, Takuya

Radiological Physics and Technology, 18(1), p.196 - 208, 2025/03

https://doi.org/10.1007/s12194-024-00873-z

One of the radiation protection measures for medical personnel engaged in X-ray fluoroscopy is the use of radiation-protective plates and a simulation tool to evaluate effect of the plates is desired. Monte Carlo simulation has an advantage of being able to accurately calculate the interaction between radiations and various objects present in the X-ray room. However, Monte Carlo simulation has a disadvantage of being computationally time-consuming. Therefore, we developed a new simplified method to calculate the dose distribution in a short time with the presence of protective plates using pre-computed directional vectors (SCV). Using the Monte Carlo code PHITS, we simulated the ambient dose equivalent distribution the X-ray fluoroscopy room without the presence of protective plates. Assuming the dose at each voxel was all contributed from radiations in the direction indicated by the directional vector, the shielding effect of the protective plates for the dose at the voxel was determined whether the line toward backtrace of the directional vector has a intersect with the protective plate or not. With SCV, the computational time for the whole dose distribution with the presence of a protective plate was reduced approximately 1/6000 of the full PHITS simulation keeping the good accuracy to evaluate the effect of the plate.