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スピントラップ剤CYPMPOによる水分解ラジカル捕捉,2

Trapping of the water decomposed radicals by spin-trap CYPMPO, 2

岡 壽崇; 山下 真一; 佐伯 誠一; 翠川 匡道*; Delamea, N.*; 勝村 庸介; 上林 將人*; 安西 和紀*

Oka, Toshitaka; Yamashita, Shinichi; Saiki, Seiichi; Midorikawa, Masamichi*; Delamea, N.*; Katsumura, Yosuke; Kamibayashi, Masato*; Anzai, Kazunori*

水への$$gamma$$線照射によって生成した活性酸素ラジカルをスピントラップ剤CYPMPO(5-(2,2-dimethyl-1,3-propoxy cyclophos-phoryl)-5-methyl-1-pyrroline N-oxide)で捕捉し、ESR測定によって活性酸素スピンアダクト($${}^{bullet}$$OHとHO$$_{2}^{bullet}$$)の減衰挙動について検討した。

A novel spin-trap CYPMPO (5-(2,2-dimethyl-1,3-propoxy cyclophos-phoryl)-5-methyl-1-pyrroline N-oxide) was applied to detect the water decomposed radicals using by ESR (Electron Spin Resonance) spectroscopy, and their lifetimes were estimated.

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