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Structural study on complex between MO$$_{4}$$$$^{-}$$ (M=$$^{99}$$Tc and Re) and MIDOA by ATR FT-IR and EXAFS spectroscopy and DFT calculation

ATR FT-IR, EXAFS分光法及びDFT計算によるMO$$_{4}$$$$^{-}$$ (M=$$^{99}$$Tc and Re) - MIDOA錯体の構造研究

佐伯 盛久; 佐々木 祐二 ; Banerjee, D.*; Scheinost, A.*; Foerstendorf, H.*

Saeki, Morihisa; Sasaki, Yuji; Banerjee, D.*; Scheinost, A.*; Foerstendorf, H.*

Structures of complexes of MO$$_{4}$$$$^{-}$$ (M=$$^{99}$$Tc and Re) with MIDOA were investigated by IR and EXAFS spectroscopy. Analysis of observed spectra based on results of DFT calculation suggests that the complexes are stabilized by multiple hydrogen bonds.

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