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Photoemission study on natural oxidation of Cu$$_{3}$$Au with synchrotron radiation

シンクロトロン放射光を用いたCu$$_{3}$$Auの自然酸化に関する光電子分光研究

宗和 誠*; 山崎 大地*; 岡田 美智雄*; 吉越 章隆 ; 寺岡 有殿; 笠井 俊夫*

Sowa, Makoto*; Yamazaki, Daichi*; Okada, Michio*; Yoshigoe, Akitaka; Teraoka, Yuden; Kasai, Toshio*

We report the results of a study of the natural oxidation of Cu$$_{3}$$Au(110) with high-resolution X-ray photoemission spectroscopy in conjunction with synchrotron radiation. The clean surface of Cu$$_{3}$$Au(110) is terminated with 50% Au and 50% Cu atoms. After natural oxidation in the air, Cu atoms segregate on the surface and produce Cu-oxide. As a result, Au atoms move into the bulk. Au atoms below the oxide reduce the diffusion of O atoms farther into bulk and limit the oxide thickness. The face dependence of natural oxidation indicates that the diffusion of Cu atoms also contributes to oxide formation.

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パーセンタイル:18.52

分野:Engineering, Electrical & Electronic

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