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Temperature dependence of Cu$$_{2}$$O formation on Cu$$_{3}$$Au(110) surface with energetic O$$_{2}$$ molecular beams

エネルギーを持った酸素分子線によるCu$$_{3}$$Au(110)表面におけるCu$$_{2}$$O形成の温度依存性

橋之口 道宏*; 吉越 章隆 ; 寺岡 有殿; 岡田 美智雄*

Hashinokuchi, Michihiro*; Yoshigoe, Akitaka; Teraoka, Yuden; Okada, Michio*

We study the surface temperature ($$T$$$$_{rm s}$$) dependence of oxidation on Cu$$_{3}$$Au(110) induced by a hyperthermal O$$_{2}$$ molecular beam (HOMB). The dissociative adsorption of O$$_{2}$$ proceeds accompanying with Cu segregation. From the Ts dependence of the O uptake curve, the direct dissociative adsorption process is a dominant process at less than O coverage ($$Theta$$) of 0.2 ML for the 2.2 eV HOMB incidence. At high $$Theta$$, the oxidation, in particular, the Cu$$_{2}$$O formation, depends on $$T$$$$_{rm s}$$. The high $$T$$$$_{rm s}$$ causes the efficient Cu segregation on the surface during the oxidation, suggesting the dominant role of Cu migration in the Cu$$_{2}$$O formation.

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パーセンタイル:29.39

分野:Chemistry, Physical

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