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Local electronic states of Fe$$_{4}$$N films revealed by X-ray absorption spectroscopy and X-ray magnetic circular dichroism

内殻吸収および磁気円二色性によるFe$$_{4}$$N薄膜の局所電子状態の研究

伊藤 啓太*; 都甲 薫*; 竹田 幸治; 斎藤 祐児; 小口 多美夫*; 末益 崇*; 木村 昭夫*

Ito, Keita*; Toko, Kaoru*; Takeda, Yukiharu; Saito, Yuji; Oguchi, Tamio*; Suemasu, Takashi*; Kimura, Akio*

We performed XAS and XMCD measurements at Fe L$$_{2,3}$$ and N K-edges for Fe$$_{4}$$N epitaxial films grown by MBE. We compared experimental XAS and XMCD spectra with those simulated by a combination of a first-principles calculation and Fermi's golden rule. We revealed that the shoulders observed at Fe L$$_{2,3}$$-edges in the XAS and XMCD spectra were due to the electric dipole transition from the Fe 2p core-level to the hybridization state generated by $$sigma$$$$^{ast}$$ anti-bonding between the orbitals of N 2p at the body-centered site and Fe 3d on the face-centered (II) sites. Thus, the observed shoulders were attributed to the local electronic structure of Fe atoms at II sites. As to the N K-edge, the line shape of the obtained spectra was explained by the dipole transition from the N 1s core-level to the hybridization state formed by $$pi$$$$^{ast}$$ and $$sigma$$$$^{ast}$$ anti-bondings between the Fe 3d and N 2p orbitals.

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パーセンタイル:67.17

分野:Physics, Applied

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