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Sorption behavior of Np(V) on microbe pure culture and consortia

単離された微生物及び微生物共同体へのNp(V)の収着

大貫 敏彦; 香西 直文   ; 坂本 文徳  ; 宇都宮 聡*; 加藤 憲二*

Onuki, Toshihiko; Kozai, Naofumi; Sakamoto, Fuminori; Utsunomiya, Satoshi*; Kato, Kenji*

微生物共同体及び単離された鉄還元バクテリアへのNp(V)の吸着挙動を、休眠状態の細胞を用いてpH3$$sim$$7において調べた。不活性雰囲気における鉄還元菌へのNp(V)の吸着量及び大気状態での微生物共同体への吸着量は、pH5以下で大気条件下における鉄還元菌への吸着量より多かった。この結果は、微生物細胞表面への吸着以外のメカニズム、すなわちNp(IV)への還元反応が関わっている可能性を示唆する。

The sorption behavior of Np(V) by the microbe consortia and by a single pure culture of Fe reducing bacterium was studied at pH between 3 and 7 in resting cell conditions. The sorption of Np(V) by the Fe reducing bacterium obtained in the inert condition and by the consortia in aerated condition were higher than by the Fe reducing bacterium in aerobic condition at pH below 5, strongly suggesting presence of other mechanism than the adsorption on microbial cell surface, i.e. reduction to Np(IV).

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分野:Chemistry, Multidisciplinary

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