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Development of MA separation process with TEHDGA/SiO$$_{2}$$-P for an advanced reprocessing

高度再処理技術を指向したTEHDGA吸着材を用いたMA分離プロセスの開発

堀内 勇輔; 渡部 創  ; 佐野 雄一   ; 竹内 正行 ; 木田 福香*; 新井 剛*

Horiuchi, Yusuke; Watanabe, So; Sano, Yuichi; Takeuchi, Masayuki; Kida, Fukuka*; Arai, Tsuyoshi*

抽出クロマトグラフィ法を採用した高レベル放射性廃液からのMA分離技術の構築のためにTEHDGA吸着材の適用性をバッチ式吸着およびカラム試験により評価した。バッチ式吸着試験の結果より、TEHDGA吸着材はTODGA吸着材と比較すると核分裂生成物の除染性能が優れていることが確認された。さらにカラム試験の結果より、TEHDGA吸着材から希土類元素の全量溶離が確認されたためTEHDGAは吸着材としても性能は十分に発揮され、プロセスへの適用が期待できる。

Applicability of tetra2-ehylhexyl diglycolamide (TEHDGA) impregnated adsorbent for minor actinide (MA) recovery from high level liquid waste (HLLW) in extraction chromatography technology was investigated through batch-wise adsorption and column separation experiments. Distribution ratio of representative fission product elements were obtained by the batch-wise experiments, and TEHDGA adsorbent was shown to be preferable to TODGA adsorbent for decontamination of several species. All Ln(III) supplied into the TEHDGA adsorbent packed column was properly eluted from the column, and the applicability of the adsorbent was successfully showed by this study.

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パーセンタイル:69.06

分野:Chemistry, Analytical

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