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The Behavior of Cr-coated Zry cladding under high-temperature steam oxidation

Crコートジルカロイ被覆管の高温水蒸気酸化挙動

Mohamad, A. B. ; 古本 健一郎; 根本 義之  ; 井岡 郁夫  ; 佐藤 大樹*; 岡田 裕史*; 山下 真一郎   ; 逢坂 正彦  

Mohamad, A. B.; Furumoto, Kenichiro; Nemoto, Yoshiyuki; Ioka, Ikuo; Sato, Daiki*; Okada, Yuji*; Yamashita, Shinichiro; Osaka, Masahiko

Chromium (Cr) coated zirconium (Zr) based alloy cladding is the promising material for a near term accident tolerant fuel (ATF). Cr-coated Zr based cladding was fabricated by sputtering technique and HT oxidation tests were conducted up to different high temperatures (1100$$^{circ}$$C to 1400$$^{circ}$$C). The present work aims to investigate the metallography of Cr-coated Zr cladding after HT steam test. The result showed Cr$$_{2}$$O$$_{3}$$ layers were formed as a protective oxide layer at the outmost layer for all samples. However, Cr-Zr-Fe phases were observed In particular, the main phases observed in the cross-sectional area were Cr$$_{2}$$O$$_{3}$$, Cr, ZrO$$_{2}$$, Cr-Zr, and Zr situated from outer to inner of the sample after HT test. The details of the microstructure and mechanism of these samples will be discussed in the presentation.

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