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Thermochromic properties of low-melting ionic uranyl isothiocyanate complexes

低融点を持つウランチオシアン錯体のサーモクロミズム特性

青柳 登   ; 下条 晃司郎   ; Brooks, N. R.*; 永石 隆二 ; 長縄 弘親  ; Van Hecke, K.*; Van Meervelt, L.*; Binnemans, K.*; 木村 貴海 

Aoyagi, Noboru; Shimojo, Kojiro; Brooks, N. R.*; Nagaishi, Ryuji; Naganawa, Hirochika; Van Hecke, K.*; Van Meervelt, L.*; Binnemans, K.*; Kimura, Takaumi

Temperature-dependent yellow-to-red colour changes of uranylthiocyanate complexes with 1-alkyl-3-methylimidazolium cations have been studied by different spectroscopic methods and this phenomenon is attributed to changes in the local environment of the uranyl ion, including the coordination number, as well as to cation - anion interactions.

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パーセンタイル:70.65

分野:Chemistry, Multidisciplinary

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