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The Redox potential of mendelevium (Md) determined atom-at-a-time with a flow electrolytic column

フロー電解カラムを用いたシングルアトムレベルでのメンデレビウムの酸化還元電位

Sch$"a$del, M.; 豊嶋 厚史; Li, Z.*; 浅井 雅人 ; 佐藤 望; 菊池 貴宏; 金谷 佑亮; 北辻 章浩 ; 塚田 和明 ; 永目 諭一郎 ; 大江 一弘*; 笠松 良崇*; こがま 優香*; 篠原 厚*; 羽場 宏光*; Even, J.*

Sch$"a$del, M.; Toyoshima, Atsushi; Li, Z.*; Asai, Masato; Sato, Nozomi; Kikuchi, Takahiro; Kaneya, Yusuke; Kitatsuji, Yoshihiro; Tsukada, Kazuaki; Nagame, Yuichiro; Oe, Kazuhiro*; Kasamatsu, Yoshitaka*; Kogama, Yuka*; Shinohara, Atsushi*; Haba, Hiromitsu*; Even, J.*

The redox behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. It was clearly observed that, applying appropriate potentials on the chromatography column, the most stable Md$$^{3+}$$ is reduced to Md$$^{2+}$$. The redox potential of the Md$$^{2+}$$ = Md$$^{3+}$$ + e$$^{-}$$ couple was determined to be -0.16 $$pm$$ 0.05 V vs. a normal hydrogen electrode.

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