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コンクリート中のCsの局所構造解析

Local structure analysis of Cs in concrete of reactor building

腰越 広輝*; 佐藤 勇*; 宮原 直哉*; 鈴木 恵理子   ; 逢坂 正彦  ; 松浦 治明*

Koshigoe, Koki*; Sato, Isamu*; Miyahara, Naoya*; Suzuki, Eriko; Osaka, Masahiko; Matsuura, Haruaki*

福島第一原子力発電所等の廃炉に必要となるコンクリートへの骨材の影響に着目したCs浸透挙動を解明するため、CsCl及びCsI水溶液への骨材含有量の異なるコンクリートの浸漬試験を行った。XRF分析によりCs浸透の深さ分布を、EXAFS測定によりコンクリート中のCsの化学状態を調べた結果、骨材含有量によってCs濃度の深さ分布やCs近傍のOの配位数が異なることが分かり、骨材含有量の重要性を明らかにした。

For the waste management of radioactive concrete in the Fukushima Daiichi Nuclear Power Station, the Cs penetration behavior into concrete focused on the effects of aggregates was investigated by small-scale leaching tests of concrete with various contents of aggregates into CsI or CsCl dissolved water solution. The distribution in depth direction and chemical state of Cs were measured by using XRF and EXAFS, respectively. It was found that the Cs concentration and coordination number of O with Cs changed according to the content of aggregates. These results suggested importance of the effect of content of aggregates.

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