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モンモリロナイトに吸着した水和Csの構造

Structure of hydrated Cs on montmorillonite

岡本 拓也*; 大窪 貴洋*; 岩舘 泰彦*; 出口 健三*; 清水 禎*; 大木 忍*; 舘 幸男  

Okamoto, Takuya*; Okubo, Takahiro*; Iwadate, Yasuhiko*; Deguchi, Kenzo*; Shimizu, Tadashi*; Oki, Shinobu*; Tachi, Yukio

モンモリロナイトに吸着した$$^{133}$$Csの吸着構造を明らかにすることを目的に、Cs吸着モンモリロナイトを調製し、$$^{133}$$Cs Magic angle spinning (MAS) NMR測定を行った。含水率の異なるCs型モンモリロナイトの測定結果から、水和に伴うCsの吸着構造の変化を解析した。

The structures of Cs adsorbed on montmorillonite were investigated by $$^{133}$$Cs Magic Angle Spinning (MAS) NMR spectroscopy. The NMR spectra of Cs adsorbed on montmorillonite samples were measured under different relative humidity levels and were analyzed to evaluate the change in the structure of hydrated Cs sorbed on montmorillonite.

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